Advanced search
Publication Cover
Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 6, 1987 - Issue 3
Submit an article Journal homepage
148
Views
66
CrossRef citations to date
0
Altmetric
Original Articles

The Versatility of the Pentamethylcyclopentadienyl Ligand in Main-Group Chemistry

Peter Jutzi Faculty of Chemistry, University of Bielefeld, D-4800, Bielefeld, Federal Republic of Germany
Pages 123-144 | Published online: 13 Dec 2006

Citations (66)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (1)

P. Jutzi, N. Brusdeilins, U. Meyer & S. Opiela. (1993) The Pentamethylcyclopentadienyl Ligand at Phosphorus or Arsenic – Effect on Small-Membered Rings and Double–Bond Species. Phosphorus, Sulfur, and Silicon and the Related Elements 76:1-4, pages 53-56.
Read now

Articles from other publishers (65)

Philipp Dabringhaus, Silja Zedlitz, Luisa Giarrana, David Scheschkewitz & Ingo Krossing. (2023) Low‐Valent M x Al 3 Cluster Salts with Tetrahedral [SiAl 3 ] + and Trigonal‐Bipyramidal [M 2 Al 3 ] 2+ Cores (M=Si/Ge) . Angewandte Chemie International Edition 62:8.
Crossref
Philipp Dabringhaus, Silja Zedlitz, Luisa Giarrana, David Scheschkewitz & Ingo Krossing. (2023) Low‐Valent M x Al 3 Cluster Salts with Tetrahedral [SiAl 3 ] + and Trigonal‐Bipyramidal [M 2 Al 3 ] 2+ Cores (M=Si/Ge) . Angewandte Chemie 135:8.
Crossref
Fule Wu, Christophe Deraedt, Yann Cornaton, Laurent Ruhlmann, Lydia Karmazin, Corinne Bailly, Nathalie Kyritsakas, Nolwenn Le Breton, Sylvie Choua & Jean-Pierre Djukic. (2021) Fate of Cobaltacycles in Cp*Co-Mediated C–H Bond Functionalization Catalysis: Cobaltacycles May Collapse upon Oxidation via Co(IV) Species. Organometallics 40:15, pages 2624-2642.
Crossref
William Erb & Thierry Roisnel. (2019) Asymmetric synthesis of hetero-1,2,3,4,5-pentasubstituted ferrocenes. Chemical Communications 55:62, pages 9132-9135.
Crossref
Carsten Müller, Angelika Stahlich, Lisa Wirtz, Claude Gretsch, Volker Huch & André Schäfer. (2018) Carbene Complexes of Stannocenes. Inorganic Chemistry 57:14, pages 8050-8053.
Crossref
Wasim Haider, Volker Huch & André Schäfer. (2018) Lewis base complexes of sila[2]aluminocenophanes. Dalton Transactions 47:31, pages 10425-10428.
Crossref
Alma T. Corona‐Armenta, Mario Ordoñez, Jorge A. López, Jorge Cervantes & Oracio Serrano. (2015) Synthesis and Characterization of m ‐Terphenyl (1,3‐Diphenylbenzene) Compounds Containing Trifluoromethyl Groups . Helvetica Chimica Acta 98:3, pages 359-367.
Crossref
P. Perrotin, Bretni S. Kennon, Brendan Twamley, Joel S. Miller & Pamela J. Shapiro. (2014) Synthesis and characterization of cyclopentadienylgallium amide compounds as potential single source precursors to GaN. Polyhedron 84, pages 216-222.
Crossref
Markus Stubenhofer, Giuliano Lassandro, Gábor Balázs, Alexey Y. Timoshkin & Manfred Scheer. (2012) Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction. Chemical Communications 48:58, pages 7262.
Crossref
Anne Kraft, Jennifer Beck & Ingo Krossing. (2011) Facile Access to the Pnictocenium Ions [Cp*ECl] + (E=P, As) and [(Cp*) 2 P] + : Chloride Ion Affinity of Al(OR F ) 3 . Chemistry – A European Journal 17:46, pages 12975-12980.
Crossref
Anna Maria Raspolli Galletti & Guido Pampaloni. (2010) Niobium complexes as catalytic precursors for the polymerization of olefins. Coordination Chemistry Reviews 254:5-6, pages 525-536.
Crossref
Manfred Scheer, Christian Kuntz, Markus Stubenhofer, Manfred Zabel & Alexey Y. Timoshkin. (2009) Stepwise Expansion of a Cp* Ring at Pentelidene Complexes and Stereoselective Formation of Triphosphines. Angewandte Chemie International Edition 49:1, pages 188-192.
Crossref
Manfred Scheer, Christian Kuntz, Markus Stubenhofer, Manfred Zabel & Alexey Y. Timoshkin. (2009) Schrittweise Erweiterung eines Cp*‐Rings am Pentelidenkomplex und stereoselektive Bildung von Triphosphanen. Angewandte Chemie 122:1, pages 192-196.
Crossref
Zvi RappoportPeter Jutzi. 2010. Patai's Chemistry of Functional Groups. Patai's Chemistry of Functional Groups.
Andrew E. Ashley, Andrew R. Cowley & Dermot O'Hare. (2007) Permethylpentalene Chemistry. European Journal of Organic Chemistry 2007:14, pages 2239-2242.
Crossref
Andrew E. Ashley, Andrew R. Cowley & Dermot O'Hare. (2007) The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry. Chemical Communications:15, pages 1512.
Crossref
Hans Martin Lindemann, Beate Neumann, Hans‐Georg Stammler, Anja Stammler & Peter Jutzi. 2005. Organosilicon Chemistry Set. Organosilicon Chemistry Set 429 434 .
Peter Jutzi & Stefan H. A. Petri. 2005. Organosilicon Chemistry Set. Organosilicon Chemistry Set 275 280 .
Jun-ichi Terasawa, Hideo Kondo, Taisuke Matsumoto, Karl Kirchner, Yukihiro Motoyama & Hideo Nagashima. (2005) “Unsymmetrical” Diruthenium Amidinates in Which the μ 2 -Amidinate Bridge Is Perpendicular to the Ru−Ru Axis:  Synthesis and Reactions of Derivatives of [(η 5 -C 5 Me 5 )Ru(μ-amidinate)Ru(η 5 -C 5 H 5 )] + . Organometallics 24:11, pages 2713-2721.
Crossref
Hans Martin Lindemann, Beate Neumann, Hans‐Georg Stammler, Anja Stammler & Peter Jutzi. 2003. Organosilicon Chemistry V. Organosilicon Chemistry V 429 434 .
Peter Jutzi, Hans Martin Lindemann, Jörn‐oliver Nolte & Manuela Schneider. 2003. Silicon Chemistry. Silicon Chemistry 372 382 .
Isabel Rojo, Francesc Teixidor, Clara Viñas, Raikko Kivekäs & Reijo Sillanpää. (2003) Relevance of the Electronegativity of Boron in η 5 ‐Coordinating Ligands: Regioselective Monoalkylation and Monoarylation in Cobaltabisdicarbollide [3,3′‐Co(1,2‐C 2 B 9 H 11 ) 2 ] − Clusters . Chemistry – A European Journal 9:18, pages 4311-4323.
Crossref
Anthony G. Avent, Michael J. Davies, Peter B. Hitchcock & Michael F. Lappert. (2003) Synthesis and Characterization of a Series of 1, 2‐Phenylenedioxoborylcyclopentadienes. Zeitschrift für anorganische und allgemeine Chemie 629:7-8, pages 1358-1366.
Crossref
Hans Martin Lindemann, Manuela Schneider, Beate Neumann, Hans-Georg Stammler, Anja Stammler & Peter Jutzi. (2002) Synthesis and Reactivity of Core-Functionalized Polyhedral Titanasiloxanes. Organometallics 21:14, pages 3009-3017.
Crossref
E Leiner & M Scheer. (2002) Cp*GaCl2 and Cp*2GaCl (Cp*=η1-C5Me5) as starting materials for novel Group 13 element complexes. Journal of Organometallic Chemistry 646:1-2, pages 247-254.
Crossref
Peter W. Roesky. (2001) Substituted Cyclooctatetraenes as Ligands inf-Metal Chemistry. European Journal of Inorganic Chemistry 2001:7, pages 1653-1660.
Crossref
Andreas Klipp, Stefan H.A Petri, Beate Neumann, Hans-Georg Stammler & Peter Jutzi. (2001) Novel cyclopentadienyl silanes and disilanes: synthesis, structure and gas-phase pyrolysis. Journal of Organometallic Chemistry 620:1-2, pages 20-31.
Crossref
Peter Jutzi, Beate Neumann, Lars Oliver Schebaum, Anja Stammler & Hans-Georg Stammler. (2000) Unexpected Reactivity of Cp*Ga toward Fe−Cl Bonds:  Synthesis and Structure of Cp*(Cp*Ga) 2 FeGaCl 2 ·THF and of Cp*(CO) 2 FeGa(η 2 -Cp*)Cl . Organometallics 19:7, pages 1445-1447.
Crossref
Ulrich Siemeling. (2000) Chelate Complexes of Cyclopentadienyl Ligands Bearing Pendant O -Donors . Chemical Reviews 100:4, pages 1495-1526.
Crossref
Detlef Schröder, Helmut Schwarz, Matthias Wulf, Heinrich Sievers, Peter Jutzi & Markus Reiher. (1999) Experimenteller Nachweis von neutralem P6: ein neues Allotrop des Phosphors. Angewandte Chemie 111:23, pages 3723-3726.
Crossref
Peter Jutzi, Beate Neumann, Guido Reumann & Hans-Georg Stammler. (1999) Novel Ga 2 N 2 Ring Systems by Reaction of Pentamethylcyclopentadienylgallium with Organic Azides . Organometallics 18:10, pages 2037-2039.
Crossref
Peter Jutzi & Neil Burford. (1999) Structurally Diverse π-Cyclopentadienyl Complexes of the Main Group Elements. Chemical Reviews 99:4, pages 969-990.
Crossref
Christine J Cardin, David J Cardin, William Clegg, Simon J Coles, Steven P Constantine, Jeanette R Rowe & Simon J Teat. (1999) The molecular structure and one-pot synthesis of [Li(thf)3?Sn(SiMe3)3]. Journal of Organometallic Chemistry 573:1-2, pages 96-100.
Crossref
Sjoerd Harder. (1998) Recent developments in cyclopentadienyl-alkalimetal chemistry. Coordination Chemistry Reviews 176:1, pages 17-66.
Crossref
Peter Jutzi & Neil Burford. 1998. Metallocenes. Metallocenes 1 54 .
Peter Jutzi, Beate Neumann, Guido Reumann & Hans-Georg Stammler. (1998) Pentamethylcyclopentadienylgallium (Cp*Ga):  Alternative Synthesis and Application as a Terminal and Bridging Ligand in the Chemistry of Chromium, Iron, Cobalt, and Nickel. Organometallics 17:7, pages 1305-1314.
Crossref
Jörg Ebels, Rudolf Pietschnig, Sirpa Kotila, André Dombrowski, Edgar Niecke, Martin Nieger & Hans Michael Schiffner. (1998) Bis(pentamethylcyclopentadienyl)-Substituted Phosphanes: Synthesis and Structure. European Journal of Inorganic Chemistry 1998:3, pages 331-337.
Crossref
Stefan H.A Petri, Beate Neumann, Hans-Georg Stammler & Peter Jutzi. (1998) Silyl-Komplexe des Molybdäns und Wolframs. Synthese, Reaktivität und Struktur. Journal of Organometallic Chemistry 553:1-2, pages 317-329.
Crossref
P. Jutzi, S. Pilotek, B. Neumann & H.-G. Stammler. (1998) Synthese und Charakterisierung neuer Cyclopentadienylarsen-Verbindungen. Journal of Organometallic Chemistry 552:1-2, pages 221-228.
Crossref
Peter Jutzi & Stefan H. A. Petri. 1997. Organosilicon Chemistry III. Organosilicon Chemistry III 275 280 .
Helmut Sitzmann, Yvonne Ehleiter, Gotthelf Wolmersh?user, Achim Ecker, Christoph ?ffing & Hansgeorg Schn?ckel. (1997) Zwei strukturell verschiedenartige Stibocenium-Kationen. Journal of Organometallic Chemistry 527:1-2, pages 209-213.
Crossref
Karen E. du Plooy, Johan du Toit, Demetrius C. Levendis & Neil J. Coville. (1996) Multiply substituted cyclopentadienyl metal complexes: I. Solid-state and solution conformational studies on. Journal of Organometallic Chemistry 508:1-2, pages 231-242.
Crossref
Peter Jutzi & Jürgen Dahlhaus. (1994) (Dimethylaminoethyl)cyclopentadienyl ligands in compounds of s- and p-block elements. Coordination Chemistry Reviews 137, pages 179-199.
Crossref
Jürgen Dahlhaus, Peter Jutzi, Hubert‐Joachim Frenck & Wilhelm Kulisch. (2004) (Me 5 C 5 )SiH 3 and (Me 5 C 5 ) 2 SiH 2 as precursors for low‐temperature remote plasma‐enhanced CVD of thin Si 3 N 4 and SiO 2 films . Advanced Materials 5:5, pages 377-380.
Crossref
M. J. Taylor & P. J. Brothers. 1993. Chemistry of Aluminium, Gallium, Indium and Thallium. Chemistry of Aluminium, Gallium, Indium and Thallium 111 247 .
Gerd Rabe, Herbert W. Roesky, Dietmar Stalke, Frank Pauer & George M. Sheldrick. (1991) The preparation and crystal structures of sodium and potassium pentamethylcyclopentadienyl pyridine solvates. Journal of Organometallic Chemistry 403:1-2, pages 11-19.
Crossref
Peter Jutzi, Rainer Kroos, Achim Müller, Hartmut Bögge & Michael Penk. (2006) Synthese und Struktur der Polycyclohexaphosphane P 6 (C 5 Me 5 ) 4 und P 6 (C 5 Me 5 ) 2 . Chemische Berichte 124:1, pages 75-81.
Crossref
Peter Jutzi & Andreas Möhrke. (2003) Bis(pentamethylcyclopentadienyl)silylene as Ligand in Gold( I ) Chloride Complexes . Angewandte Chemie International Edition in English 29:8, pages 893-894.
Crossref
Peter Jutzi & Andreas Möhrke. (2006) Bis(pentamethylcyclopentadienyl)silylen als Ligand in Gold(I)‐chlorid‐Komplexen. Angewandte Chemie 102:8, pages 913-914.
Crossref
Peter Jutzi & Rainer Kroos. (1990) Phosphiniden- und arsiniden-komplexe mit pentamethylcyclopentadienyl (Cp★)-liganden am gruppe 15-element: Synthese und Cp★-übertragung. Journal of Organometallic Chemistry 390:3, pages 317-322.
Crossref
S. N. Tandura, S. N. Gurkova & A. I. Gusev. (1990) Molecular structure of germylenes and their complexes. Journal of Structural Chemistry 31:2, pages 318-341.
Crossref
Peter Jutzi, Andreas Möhrke, Achim Müller & Hartmut Bögge. (1989) Reaction of Decamethylsilicocene with Sulfur, Selenium, and Tellurium : From a p π p π System to New Heterocycles . Angewandte Chemie International Edition in English 28:11, pages 1518-1519.
Crossref
Peter Jutzi, Andreas Möhrke, Achim Müller & Hartmut Bögge. (1989) Reaktion von Decamethylsilicocen mit Schwefel, Selen und Tellur: Vom pπ-pπ-System zu neuen Heterocyclen. Angewandte Chemie 101:11, pages 1527-1528.
Crossref
Peter Jutzi, Udo Holtmann, Dieter Kanne, Carl Krüger, Richard Blom, Rolf Gleiter & Isabella Hyla‐Kryspin. (2006) Decamethylsilicocene — The first stable silicon(II) compound: Synthesis, structure, and bonding. Chemische Berichte 122:9, pages 1629-1639.
Crossref
Jörg Lorberth, Sung-Hee Shin, Sigrid Wocadlo & Werner Massa. (1989) Pentabenzylcyclopentadienylpotassium ?? 3 THF, an Organopotassium Compound with“Piano Stool” Geometry. Angewandte Chemie International Edition in English 28:6, pages 735-736.
Crossref
Jörg Lorberth, Sung‐Hee Shin, Sigrid Wocadlo & Werner Massa. (2006) Pentabenzylcyclopentadienylkalium · 3 THF, eine Organokaliumverbindung mit „Klavierstuhl”︁‐Geometrie. Angewandte Chemie 101:6, pages 793-794.
Crossref
Jörg Lorberth, Theo F. Berlitz & Werner Massa. (2003) Pentamethylcyclopentadienylmercury Chloride: An Organomercury Compound with Novel Battlement‐like Structure. Angewandte Chemie International Edition in English 28:5, pages 611-613.
Crossref
Jörg Lorberth, Theo F. Berlitz & Werner Massa. (2006) Pentamethylcyclopentadienyl‐quecksilberchlorid: Eine Organoquecksilberverbindung mit neuartiger Zinnenstruktur. Angewandte Chemie 101:5, pages 623-624.
Crossref
Leonid N. Markovski & Vadim D. Romanenko. (1989) Phosphaalkynes and phosphaalkenes. Tetrahedron 45:19, pages 6019-6090.
Crossref
Peter Jutzi, Dieter Kanne, Mike Hursthouse & Andrew J. Howes. (2006) Mono‐ und Bis(η 1 ‐pentamethylcyclopentadienyl)silane – Synthese, Struktur und Eigenschaften . Chemische Berichte 121:7, pages 1299-1305.
Crossref
P. JUTZI. (2016) ChemInform Abstract: The Versatility of the Pentamethylcyclopentadienyl Ligand in Main‐Group Chemistry. ChemInform 19:10.
Crossref
Peter Jutzi & Udo Meyer. (2006) Arsaphosphenyl‐ und Diphosphenyl‐Komplexe von Chrom und Molybdän. Chemische Berichte 121:3, pages 559-560.
Crossref
Gerard Parkin & John E. Bercaw. (1988) Halide, hydride, alkyl, oxo and related derivatives of bis(pentamethylcyclopentadienyl)tungsten(IV). Polyhedron 7:19-20, pages 2053-2082.
Crossref
Christoph Elschenbroich & Albrecht SalzerChristoph Elschenbroich & Albrecht Salzer. 1988. Organometallchemie. Organometallchemie 515 539 .
P. Jutzi & U. Meyer. (1987) Photochemie von pentamethylcyclopentadienyl-substituierten Diphosphenen und Phosphaarsenen. Journal of Organometallic Chemistry 333:2, pages C18-C20.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.