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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 7, 1988 - Issue 1
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Original Articles

Molecular Hydrogen Coordination to Transition Metals

Pages 17-40 | Published online: 13 Dec 2006

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CleanthesA. Nicolaides & EmmanuelD. Simandiras. (1996) Prediction of Nonclassical Hydrogen Complexes of Nontransition Metals. Comments on Inorganic Chemistry 18:2, pages 65-75.
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Piero Zanello. (1991) Can Electrochemistry Distinguish Classical from Nonclassical Transition-Metal Polyhydrides?. Comments on Inorganic Chemistry 11:5-6, pages 339-359.
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Articles from other publishers (43)

Yaru Dang, Na Zhang, Zheng Sun, Qingzhong Li & Xiaoyan Li. (2019) New insights into the dihydrogen bonds (MHδ−···Hδ+X) in CpM(PMe3)(L)2H···HX (M=Cr, Mo, W; L=PMe3, CO; X=F, OH, NH2). Structural Chemistry 30:5, pages 1819-1830.
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Kerstin Freitag, Mariusz Molon, Paul Jerabek, Katharina Dilchert, Christoph Rösler, Rüdiger W. Seidel, Christian Gemel, Gernot Frenking & Roland A. Fischer. (2016) Zn⋯Zn interactions at nickel and palladium centers. Chemical Science 7:10, pages 6413-6421.
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Brandon K. Mitchell & Ryan P. Steele. (2014) Nuclear Motion in the σ-Bound Regime of Metal–H 2 Complexes: [Mg(H 2 ) n =1–6 ] 2+ . The Journal of Physical Chemistry A 118:43, pages 10057-10066.
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Pavel A. Dub, Natalia V. Belkova, Oleg A. Filippov, Jean‐Claude Daran, Lina M. Epstein, Agustí Lledós, Elena S. Shubina & Rinaldo Poli. (2009) Solvent‐Dependent Dihydrogen/Dihydride Stability for [Mo(CO)(Cp*)H 2 (PMe 3 ) 2 ] + [BF 4 ] − Determined by Multiple Solvent⋅⋅⋅Anion⋅⋅⋅Cation Non‐Covalent Interactions . Chemistry – A European Journal 16:1, pages 189-201.
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Carole A. Morrison & Anthony M. Reilly. (2010) Investigating anharmonicity using molecular dynamics calculations: the TM hydride series (PH3)3MH4, (M = Os, Ru and Fe). Dalton Transactions 39:23, pages 5527.
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Olga V. Turova, Eugenia V. Starodubtseva, Maxim G. Vinogradov & Vladimir A. Ferapontov. (2009) Kinetic study of asymmetric hydrogenation of methyl levulinate using the (COD)Ru(2-methylallyl)2?BINAP?HCl catalytic system. Journal of Molecular Catalysis A: Chemical 311:1-2, pages 61-65.
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Kazuo Nakamoto. 2008. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Infrared and Raman Spectra of Inorganic and Coordination Compounds 1 273 .
Gregory J. Kubas. (2007) Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage . Chemical Reviews 107:10, pages 4152-4205.
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Claudio Bianchini & Maurizio Peruzzini. 2001. Recent Advances in Hydride Chemistry. Recent Advances in Hydride Chemistry 271 297 .
Heiko Jacobsen & Heinz Berke. 2001. Recent Advances in Hydride Chemistry. Recent Advances in Hydride Chemistry 89 116 .
Elizabeth T. Papish, Matthew P. Magee & Jack R. Norton. 2001. Recent Advances in Hydride Chemistry. Recent Advances in Hydride Chemistry 39 74 .
Feliu Maseras, Agustí Lledós, Eric Clot & Odile Eisenstein. (2000) Transition Metal Polyhydrides:  From Qualitative Ideas to Reliable Computational Studies. Chemical Reviews 100:2, pages 601-636.
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Zhida Chen, Tong Cai, Jiang Bian, Lemin Li & Guangxian Xu. (1999) Density functional theory study on the relative stability and equivalence of ligand replacement in rhenium polyhydride compounds [ReHx(PR3)y]n− (x=9, y=0, n=2; x=7,5,3, y=2,3,4, n=0). Journal of Molecular Structure: THEOCHEM 466:1-3, pages 187-196.
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Elena S. Shubina, Natalia V. Belkova, Ekaterina V. Bakhmutova, Evgenii V. Vorontsov, Vladimir I. Bakhmutov, Alexei V. Ionidis, Claudio Bianchini, Lorenza Marvelli, Maurizio Peruzzini & Lina M. Epstein. (1998) In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [{MeC(CH2PPh2)3}Re (CO)2H]. ReH?H bonding and proton-transfer pathways. Inorganica Chimica Acta 280:1-2, pages 302-307.
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Guada Barea, Miguel A. Esteruelas, Agustí Lledós, Ana M. López, Enrique Oñate & José I. Tolosa. (1998) Synthesis and Characterization of OsX{NHC(Ph)C 6 H 4 }H 2 (P i Pr 3 ) 2 (X = H, Cl, Br, I):  Nature of the H 2 Unit and Its Behavior in Solution . Organometallics 17:18, pages 4065-4076.
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Miguel A. Esteruelas & Luis A. Oro. (1998) Dihydrogen Complexes as Homogeneous Reduction Catalysts. Chemical Reviews 98:2, pages 577-588.
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Cristina Bohanna, Berta Callejas, Andrew J. Edwards, Miguel A. Esteruelas, Fernando J. Lahoz, Luis A. Oro, Natividad Ruiz & Cristina Valero. (1998) The Five-Coordinate Hydrido−Dihydrogen Complex [OsH(η 2 -H 2 )(CO)(P i Pr 3 ) 2 ]BF 4 Acting as a Template for the Carbon−Carbon Coupling between Methyl Propiolate and 1,1-Diphenyl-2-propyn-1-ol . Organometallics 17:3, pages 373-381.
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Jaume Tomàs, Agustí Lledós & Yves Jean. (1998) The Kubas Complex Revisited. A Theoretical Study of Dihydrogen Addition and Structure of the Dihydride Form. Organometallics 17:2, pages 190-195.
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Heiko Jacobsen & Heinz Berke. (2006) A Density Functional Study of [Fe(PR 3 ) 4 H 3 ] + Isomers: Comparing Model Compounds (r = H) with Real Molecules (R = CH 3 ) . Chemistry – A European Journal 3:6, pages 881-886.
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Kohtaro Osakada, Take-aki Koizumi & Takakazu Yamamoto. (1997) Si?H and Si?C Bond Activation of a Triorganosilane Promoted by [RhCl{P( i -Pr) 3 } 2 ]. Synthesis and Structure of a Dinuclear Rh(IV) Complex with ? -Silylene Ligands . Bulletin of the Chemical Society of Japan 70:1, pages 189-195.
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Ling-Kang Liu & Lung-Shiang Luh. (1996) Consecutive Butylations on the Cyclopentadienyl Ring of the [(η 5 -C 5 H 5 )Fe(CO) 2 PPh 3 ] + Cation . Organometallics 15:25, pages 5263-5265.
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Silvio Aime, Walter Dastrù, Roberto Gobetto, Jochen Krause, Lluisa Matas & Alessandra Viale. (1996) H/D Isotopic Exchange on the Surface of a Triosmium Carbonyl Cluster. Organometallics 15:23, pages 4967-4970.
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Jian Li & Tom Ziegler. (1996) Periodic Trends and Ligand Effects in Transition Metal Dihydrogen Complexes:  A Quasi-relativistic Density Functional Study. Organometallics 15:18, pages 3844-3849.
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Vladimir I. Bakhmutov, Juan Bertrán, Miguel A. Esteruelas, Agustí Lledós, Feliu Maseras, Javier Modrego, Luis A. Oro & Eduardo Sola. (2006) Dynamic Behavior in Solution of the Trans ‐Hydridodihydrogen Complex [OsHCl( n 2 ‐H 2 )(CO)(P i Pr 3 ) 2 ]: Ab Initio and NMR Studies . Chemistry – A European Journal 2:7, pages 815-825.
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Jörg J. Schneider. (2003) SiH and CH Activation by Transition Metal Complexes: A Step Towards Isolable Alkane Complexes?. Angewandte Chemie International Edition in English 35:10, pages 1068-1075.
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Jörg J. Schneider. (1996) Si-H- und C-H-Aktivierung durch Übergangsmetallkomplexe – gibt es bald auch isolierbare Alkankomplexe?. Angewandte Chemie 108:10, pages 1132-1139.
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Miguel A. Esteruelas, Fernando J. Lahoz, Ana M. López, Enrique Oñate, Luis A. Oro, Natividad Ruiz, Eduardo Sola & José I. Tolosa. (1996) Quantum Mechanical Exchange Coupling in Trihydridoosmium Complexes Containing Azole Ligands. Inorganic Chemistry 35:26, pages 7811-7817.
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Arlen Ferrari, Eleonora Polo, Heinz Rüegger, Silvana Sostero & Luigi M. Venanzi. (1996) Photochemistry of Dihydrido(hydrotris(3,5-dimethylpyrazolyl)borato)( Z -cyclooctene)iridium. Synthetic Intermediates and Mechanism of the Photochemical Formation of Hydridophenyl(hydrotris(3,5-dimethylpyrazolyl)borato)(trimethyl phosphite)iridium . Inorganic Chemistry 35:6, pages 1602-1608.
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Moris S. Eisen & Tobin J. Marks. (1994) Recent developments in the surface and catalytic chemistry of supported organoactinides. Journal of Molecular Catalysis 86:1-3, pages 23-50.
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K. W. Kramarz & J. R. Norton. 1994. Progress in Inorganic Chemistry. Progress in Inorganic Chemistry 1 65 .
Robert Bau, Christina J. Schwerdtfeger, Luigi Garlaschelli & Thomas F. Koetzle. (1993) Neutron diffraction study of fac-[IrH 3 (PPh 2 Me) 3 ]?MeOH . J. Chem. Soc., Dalton Trans.:22, pages 3359-3362.
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M. T. Ashby. 1993. Inorganic Reactions and Methods. Inorganic Reactions and Methods 77 79 .
Philip G. Jessop & Robert H. Morris. (1992) Reactions of transition metal dihydrogen complexes. Coordination Chemistry Reviews 121, pages 155-284.
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Gerard Parkin. (2002) Do bond-stretch isomers really exist?. Accounts of Chemical Research 25:10, pages 455-460.
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Eric P. Wasserman, C. Bradley Moore & Robert G. Bergman. (1992) Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex. Science 255:5042, pages 315-318.
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Malcolm L. H. Green, Andrew K. Hughes & Philip Mountford. (1991) Synthesis and reactivity of bis(?-cyclopentadienyl) trimethyltin derivatives of niobium: crystal and molecular structure of [{Nb(?-C 5 H 5 ) 2 (SnMe 3 )} 2 (?-O)] . J. Chem. Soc., Dalton Trans.:6, pages 1407-1416.
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Qian Feng, Montserrat Ferrer, Malcolm L. H. Green, Philip Mountford, Victor S. B. Mtetwa & Keith Prout. (1991) Oxidative-addition reactions of [W 2 (?-C 5 H 4 R) 2 X 4 ](R = Pr i or Me; X = Cl or Br): reversible addition of dihydrogen to a tungsten?tungsten triple bond and X-ray crystal structures of [W 2 (?-C 5 H 4 Pr i ) 2 Cl 4 (?-H)(?-PPh 2 )] and [W 2 (?-C 5 H 4 Pr i ) 2 Cl 3 (?-Cl)(?-H)(?-PPh 2 )(PMe 3 )] . J. Chem. Soc., Dalton Trans.:6, pages 1397-1406.
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Claudio Bianchini, Maurizio Peruzzini & Fabrizio Zanobini. (1990) Distinct reaction pathways for some classical and nonclassical transition metal dihydrides. Journal of Organometallic Chemistry 390:1, pages c16-c19.
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G. J. KUBAS. (2016) ChemInform Abstract: Molecular Hydrogen Coordination to Transition Metals. ChemInform 19:47.
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