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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 8, 1989 - Issue 5
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Original Articles

Stable, Two-Coordinate, Open Shell (d0—d9) Transition Metal Complexes

Philip P. Power Department of Chemistry, University of California, Davis, California, 95616
Pages 177-202 | Published online: 23 Sep 2006

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FrankT. Edelmann. (1992) The 2,4,6-Tris(trifluoromethyl)phenyl Substituent: An Ideal Combination of Steric and Electronic Stabilization. Comments on Inorganic Chemistry 12:5, pages 259-284.
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Articles from other publishers (68)

Awal Noor. (2023) Recent developments in two coordinate transition metal chemistry. Coordination Chemistry Reviews 476, pages 214941.
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Regina Matveeva, Clemens K. Blasius, Hubert Wadepohl & Lutz H. Gade. (2021) Reactivity of a T-shaped cobalt( i ) pincer-complex . Dalton Transactions 50:20, pages 6802-6810.
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Myron S. Huzan, Manuel Fix, Matteo Aramini, Peter Bencok, J. Frederick W. Mosselmans, Shusaku Hayama, Franziska A. Breitner, Leland B. Gee, Charles J. Titus, Marie-Anne Arrio, Anton Jesche & Michael L. Baker. (2020) Single-ion magnetism in the extended solid-state: insights from X-ray absorption and emission spectroscopy. Chemical Science 11:43, pages 11801-11810.
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Jianpei Xing, Peng Wang, Zhou Jiang, Xue Jiang, Yi Wang & Jijun Zhao. (2020) Rational design of 2D organic magnets with giant magnetic anisotropy based on two-coordinate 5d transition metals. APL Materials 8:7.
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Jonas C. Ott, Hubert Wadepohl & Lutz H. Gade. (2020) Opening up the Valence Shell: A T‐Shaped Iron(I) Metalloradical and Its Potential for Atom Abstraction. Angewandte Chemie International Edition 59:24, pages 9448-9452.
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Jonas C. Ott, Hubert Wadepohl & Lutz H. Gade. (2020) Öffnung der Valenzschale: Ein T‐förmiges Eisen(I)‐Metalloradikal und sein Potential als Atomabstraktor. Angewandte Chemie 132:24, pages 9535-9539.
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Zhenbo Mo & Liang Deng. (2017) Open-shell iron hydrocarbyls. Coordination Chemistry Reviews 350, pages 285-299.
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Chun-Yi Lin, James C. Fettinger & Philip P. Power. (2017) Reversible Complexation of Lewis Bases to Low-Coordinate Fe(II), Co(II), and Ni(II) Amides: Influence of the Metal, Donor Ligand, and Amide Substituent on Binding Constants. Inorganic Chemistry 56:16, pages 9892-9902.
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Chun-Yi Lin & Philip P. Power. (2017) Complexes of Ni( i ): a “rare” oxidation state of growing importance . Chemical Society Reviews 46:17, pages 5347-5399.
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Yin-Shan Meng, Zhenbo Mo, Bing-Wu Wang, Yi-Quan Zhang, Liang Deng & Song Gao. (2015) Observation of the single-ion magnet behavior of d 8 ions on two-coordinate Co( i )–NHC complexes . Chemical Science 6:12, pages 7156-7162.
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Shuang Yao, Dennis Yiu Sun Tam, Pak Shing Cheung, Chi-Keung Lam, Pei Guo, Sik Lok Lam & Hung Kay Lee. (2015) Cobalt( ii ) amido complexes derived from a monodentate arylamido ligand featuring a highly electron-withdrawing C 6 F 5 substituent . Dalton Transactions 44:41, pages 17950-17959.
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Aimee M. Bryan, Chun-Yi Lin, Michio Sorai, Yuji Miyazaki, Helen M. Hoyt, Annelise Hablutzel, Anne LaPointe, William M. Reiff, Philip P. Power & Charles E. Schulz. (2014) Measurement of Extreme Hyperfine Fields in Two-Coordinate High-Spin Fe 2+ Complexes by Mössbauer Spectroscopy: Essentially Free-Ion Magnetism in the Solid State . Inorganic Chemistry 53:22, pages 12100-12107.
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David P. Smith, Hong Chen, Seiji Ogo, Ana I. Elduque, Miriam Eisenstein, Marilyn M. Olmstead & Richard H. Fish. (2014) Bioorganometallic Chemistry. 27. Synthetic, X-ray Crystallographic, and Competitive Binding Studies in the Reactions of Nucleobases, Nucleosides, and Nucleotides with [Cp*Rh(H 2 O) 3 ](OTf) 2, as a Function of pH, and the Utilization of Several Cp*Rh–DNA Base Complexes in Host–Guest Chemistry . Organometallics 33:10, pages 2389-2404.
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Xiaojie Wang, Zhenbo Mo, Jie Xiao & Liang Deng. (2012) Monomeric Bis(anilido)iron(II) Complexes with N -Heterocyclic Carbene Ligation: Synthesis, Characterization, and Redox Reactivity toward Aryl Halides . Inorganic Chemistry 52:1, pages 59-65.
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Weiyin Yi, Jie Zhang, Zhenxia Chen & Xigeng Zhou. (2012) Me–Si Bond Cleavage of Anionic Bis(trimethylsilyl)amide in Scorpionate-Anchored Rare Earth Metal Complexes. Inorganic Chemistry 51:20, pages 10631-10638.
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Philip P. Power. (2012) Stable Two-Coordinate, Open-Shell (d 1 –d 9 ) Transition Metal Complexes . Chemical Reviews 112:6, pages 3482-3507.
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Jie Xiao & Liang Deng. (2011) Synthesis, Structure, and Reactivity Study of Iron(II) Complexes with Bulky Bis(anilido)thioether Ligation. Organometallics 31:1, pages 428-434.
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Michael I. Lipschutz & T. Don Tilley. (2012) Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex. Chemical Communications 48:57, pages 7146.
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Patrick L. Holland. (2011) Two‐Coordinate Transition‐Metal Centers With Metal–Metal Bonds. Angewandte Chemie International Edition 50:28, pages 6213-6214.
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Patrick L. Holland. (2011) Zweifach koordinierte Übergangsmetallzentren mit Metall‐Metall‐Bindungen. Angewandte Chemie 123:28, pages 6337-6338.
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Patrick L. Holland. (2011) All square for high-spin iron(II). Nature Chemistry 3:7, pages 507-508.
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Scott A. SulwayDavid CollisonJoseph J. W. McDouallFloriana TunaRichard A. Layfield. (2011) Iron(II) Cage Complexes of N-Heterocyclic Amide and Bis(trimethylsilyl)amide Ligands: Synthesis, Structure, and Magnetic Properties. Inorganic Chemistry 50:6, pages 2521-2526.
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Deborah L. Kays. (2011) Recent developments in transition metal diaryl chemistry. Dalton Trans. 40:4, pages 769-778.
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Antonio Ruiz‐Martínez, David Casanova & Santiago Alvarez. (2010) Ligand Association/Dissociation Paths and Ill‐Defined Coordination Numbers. Chemistry – A European Journal 16:22, pages 6567-6581.
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Benjamin E Moulton, Dominic S Wright, Nathan Patmore, Charlotte E Willans, Andrew E H Wheatley, A Sella, M G Humphrey, Deborah Kays & Stephen LiddleDeborah L. Kays. 2010. Organometallic Chemistry. Organometallic Chemistry 56 76 .
Chengbao Ni & Philip P. Power. 2010. Metal-Metal Bonding. Metal-Metal Bonding 59 111 .
Chengbao Ni, Gary J. Long, Fernande Grandjean & Philip P. Power. (2009) Synthesis, Characterization, and Magnetism of Divalent Aryl Transition-Metal Complexes of the Simplest Dialkylamide, NMe 2 : Rare T-Shaped Coordination at Chromium . Inorganic Chemistry 48:24, pages 11594-11600.
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W. Alexander Merrill, Troy A. Stich, Marcin Brynda, Gregory J. Yeagle, James C. Fettinger, Raymond De Hont, William M. Reiff, Charles E. Schulz, R. David Britt & Philip P. Power. (2009) Direct Spectroscopic Observation of Large Quenching of First-Order Orbital Angular Momentum with Bending in Monomeric, Two-Coordinate Fe(II) Primary Amido Complexes and the Profound Magnetic Effects of the Absence of Jahn− and Renner−Teller Distortions in Rigorously Linear Coordination. Journal of the American Chemical Society 131:35, pages 12693-12702.
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Chengbao Ni, James C. Fettinger, Gary J. Long & Philip P. Power. (2009) Spin-State Crossover with Structural Changes in a Cobalt(II) Organometallic Species: Low-Coordinate, First Row, Heteroleptic Amido Transition Metal Aryls. Synthesis and Characterization of Ar′MN(H)Ar # (M = Mn, Fe, Co) (Ar′ = C 6 H 3 -2,6-(C 6 H 3 -2,6- i Pr 2 ) 2 , Ar # = C 6 H 3 -2,6-(C 6 H 2 -2,4,6-Me 3 ) 2 ) . Inorganic Chemistry 48:6, pages 2443-2448.
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William M. Reiff, Charles E. Schulz, Myung-Hwan Whangbo, Jung In Seo, Yoon Sup Lee, Gregory R. Potratz, Charles W. Spicer & Gregory S. Girolami. (2008) Consequences of a Linear Two-Coordinate Geometry for the Orbital Magnetism and Jahn−Teller Distortion Behavior of the High Spin Iron(II) Complex Fe[N( t -Bu) 2 ] 2 . Journal of the American Chemical Society 131:2, pages 404-405.
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Chengbao Ni, Brian Rekken, James C. Fettinger, Gary J. Long & Philip P. Power. (2009) Two-coordinate, homoleptic manganese(ii) primary terphenyl amido complexes: the effects of secondary coordination on geometry and Lewis base complexation. Dalton Transactions:39, pages 8349.
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Jianfeng Li, Haibin Song, Chunming Cui & Jin-Pei Cheng. (2008) Synthesis and Characterization of Linear and Square-Planar Nickel Complexes with Primary Amido Ligands. Inorganic Chemistry 47:9, pages 3468-3470.
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Robert Wolf, Chengbao Ni, Tailuan Nguyen, Marcin Brynda, Gary J. Long, Andrew D. Sutton, Roland C. Fischer, J. C. Fettinger, Matthew Hellman, Lihung Pu & Philip P. Power. (2007) Substituent Effects in Formally Quintuple-Bonded ArCrCrAr Compounds (Ar = Terphenyl) and Related Species. Inorganic Chemistry 46:26, pages 11277-11290.
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Ho Yu Au-Yeung, Chung Hei Lam, Chi-Keung Lam, Wai-Yeung Wong & Hung Kay Lee. (2007) Unusual Iron(II) and Cobalt(II) Complexes Derived from Monodentate Arylamido Ligands. Inorganic Chemistry 46:19, pages 7695-7697.
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Robert Wolf, Marcin Brynda, Chengbao Ni, Gary J. Long & Philip P. Power. (2007) Monomeric, Two-Coordinate, Univalent Chromium(I) Compounds:  Steric Prevention of Metal−Metal Bond Formation. Journal of the American Chemical Society 129:19, pages 6076-6077.
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Shin Takemoto, Shin-ichiro Ogura, Ho Yo, Yuko Hosokoshi, Ken Kamikawa & Hiroyuki Matsuzaka. (2006) Diiron Amido−Imido Complex [(Cp*Fe) 2 (μ 2 -NHPh)(μ 2 -NPh)]:  Synthesis and a Net Hydrogen Atom Abstraction Reaction To Form a Bis(imido) Complex . Inorganic Chemistry 45:13, pages 4871-4873.
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Gaurav Bhalla, Xiang Yang Liu, Jonas Oxgaard, William A. Goddard & Roy A. Periana. (2005) Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes:  C−H Activation Studies with Benzene. Journal of the American Chemical Society 127:32, pages 11372-11389.
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Tailuan Nguyen, Arunashree Panda, Marilyn M. Olmstead, Anne F. Richards, Mathias Stender, Marcin Brynda & Philip P. Power. (2005) Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr*) 2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar* = C 6 H 3 -2,6(C 6 H 2 -2,4,6-Pr i 3 ) 2 . Journal of the American Chemical Society 127:23, pages 8545-8552.
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Gaurav Bhalla & Roy A. Periana. (2005) CH Activation of Alkanes and Arenes Catalyzed by an O‐Donor Bis(tropolonato)iridium( III ) Complex . Angewandte Chemie International Edition 44:10, pages 1540-1543.
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Philip P. Power. (2004) Some highlights from the development and use of bulky monodentate ligands. Journal of Organometallic Chemistry 689:24, pages 3904-3919.
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Antek G. Wong-Foy, Gaurav Bhalla, Xiang Yang Liu & Roy A. Periana. (2003) Alkane C−H Activation and Catalysis by an O-Donor Ligated Iridium Complex. Journal of the American Chemical Society 125:47, pages 14292-14293.
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