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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 12, 1992 - Issue 6
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Original Articles

High Pressure Kinetics. A Decisive Dimension in Mechanistic Studies of Inorganic Reactions

Rudi Van Eldik Institut für Anorganische Chemie, Universität Witten/Herdecke, Stockumer Strasse 10, 5810, Witten, Germany
&
André E. Merbach Institut de Chimie Minérale et Analytique, Universitè de Lausanne, 3, Place du Chǎteau, 1005, Lausanne, Switzerland
Pages 341-378 | Received 13 Sep 1991, Published online: 23 Oct 2006

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John Burgess & ColinD. Hubbard. (1995) Activation Volumes and Their Variation with Solvent Composition for Dissociation of Iron(II)—Diimine Complexes in Acidic and Basic Media. Comments on Inorganic Chemistry 17:5, pages 283-300.
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ColinD. Hubbard & Rudi van Eldik. (1995) Use of High Pressure Techniques For Measuring Reaction Rates in Liquid Solutions. Instrumentation Science & Technology 23:1, pages 1-41.
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Articles from other publishers (78)

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Hirokazu Narita, Ryo Kasuya, Tomoya Suzuki, Ryuhei Motokawa & Mikiya Tanaka. 2012. Encyclopedia of Inorganic and Bioinorganic Chemistry. Encyclopedia of Inorganic and Bioinorganic Chemistry 1 28 .
Boris A. Zakharov & Elena V. Boldyreva. (2019) High pressure: a complementary tool for probing solid-state processes. CrystEngComm 21:1, pages 10-22.
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Trung Quan Luong, Shobhna Kapoor & Roland Winter. (2015) Pressure—A Gateway to Fundamental Insights into Protein Solvation, Dynamics, and Function. ChemPhysChem 16:17, pages 3555-3571.
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Dominik Lieb, Achim Zahl, Tatyana E. Shubina & Ivana Ivanović-Burmazović. (2010) Water Exchange on Manganese(III) Porphyrins. Mechanistic Insights Relevant for Oxygen Evolving Complex and Superoxide Dismutation Catalysis. Journal of the American Chemical Society 132:21, pages 7282-7284.
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Ioannis P. Gerothanassis. (2010) Oxygen-17 NMR spectroscopy: Basic principles and applications (Part I). Progress in Nuclear Magnetic Resonance Spectroscopy 56:2, pages 95-197.
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D. Hugh Powell & Andr�� E. Merbach. 2007. Encyclopedia of Magnetic Resonance. Encyclopedia of Magnetic Resonance.
D. Jaganyi, N. Xaba, A. Mzinyati & C. Grimmer. (2007) Kinetics and mechanism of hydroboration reactions of HBBr2?SMe2 and HBCl2?SMe2 ? Application of 11B NMR spectroscopy. Journal of Organometallic Chemistry 692:5, pages 1150-1155.
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Rudi van Eldik & Colin D. Hubbard. 2006. Advances in Physical Organic Chemistry Volume 41. Advances in Physical Organic Chemistry Volume 41 1 78 .
Eric Maimon, Israel Zilbermann, Haim Cohen, Daniel Kost, Rudi van Eldik & Dan Meyerstein. (2005) Mechanism of Isomerization of Ni(cyclam) in Aqueous Solutions. European Journal of Inorganic Chemistry 2005:24, pages 4997-5004.
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Martin Br?ring, Carsten D. Brandt & Stephan Link. (2005) Cationic (tripyrrinato)palladium(II) complexes. Inorganica Chimica Acta 358:11, pages 3122-3134.
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David T. Richens. (2005) Ligand Substitution Reactions at Inorganic Centers. Chemical Reviews 105:6, pages 1961-2002.
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Basam M. Alzoubi, Mohamed S. A. Hamza, Alessandro Felluga, Lucio Randaccio, Giovanni Tauzher & Rudi van Eldik. (2004) Kinetics and Mechanism of Axial Ligand Substitution of Alkyl Cobaloximes by Substituted Pyridines in Different Solvents. European Journal of Inorganic Chemistry 2004:3, pages 653-659.
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FRANK A DUNAND, LOTHAR HELM & ANDRÉ E MERBACH. 2003. Solvent Exchange on Metal Ions. Solvent Exchange on Metal Ions 1 69 .
S.F. Lincoln, D.T. Richens & A.G. Sykes. 2003. Comprehensive Coordination Chemistry II. Comprehensive Coordination Chemistry II 515 555 .
Ivana Ivanovic-Burmazovic, Mohamed S. A. Hamza & Rudi van Eldik. (2002) A Detailed Mechanistic Study of the Substitution Behavior of an Unusual Seven-Coordinate Iron(III) Complex in Aqueous Solution. Inorganic Chemistry 41:20, pages 5150-5161.
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Lothar Helm & André E. Merbach. 2002. High Pressure Chemistry. High Pressure Chemistry 131 160 .
Rudi van Eldik & Colin D. Hubbard. 2002. High Pressure Chemistry. High Pressure Chemistry 3 40 .
Joanna Macyk & Rudi van Eldik. (2002) Effect of pressure on electron transfer reactions in inorganic and bioinorganic chemistry. Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology 1595:1-2, pages 283-296.
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Basam M. Alzoubi, Mohamed S. A. Hamza, Carlos Dücker-Benfer & Rudi van Eldik. (2002) Equilibrium, Kinetic and Leaving Group Effect Studies on Ligand Substitution Reactions of a Simple Model for Coenzyme B12. European Journal of Inorganic Chemistry 2002:4, pages 968-974.
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Mohamed S. A. Hamza, Xiang Zou, Kenneth L. Brown & Rudi van Eldik. (2001) Equilibrium and Kinetic Studies on the Reactions of Alkylcobalamins with Cyanide. Inorganic Chemistry 40:21, pages 5440-5447.
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Mohamed S. A. Hamza, Carlos Dücker-Benfer & Rudi van Eldik. (2000) Ligand Substitution Behavior of a Simple Model for Coenzyme B 12 . Inorganic Chemistry 39:17, pages 3777-3783.
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Rudi van Eldik & Colin D. Hubbard. (2000) Aufklärung anorganischer Reaktionsmechanismen: Anwendung von Hochdruck. Chemie in unserer Zeit 34:4, pages 240-252.
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François P. Rotzinger & David M. Benoit. (2000) Mechanism of the S → N Isomerization and Aquation of the Thiocyanato Pentaammine Cobalt(III) Ion. Inorganic Chemistry 39:5, pages 944-952.
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Michael Hartmann, Timothy Clark & Rudi van Eldik. (1999) Water Exchange Reactions and Hydrolysis of Hydrated Titanium(III) Ions. A Density Functional Theory Study. The Journal of Physical Chemistry A 103:48, pages 9899-9905.
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Jos Nijhoff, František Hartl, Derk J. Stufkens & Jan Fraanje. (1999) Light-Induced Insertion of a CO Ligand into an Os−N Bond of the Clusters Os 3 (CO) 10 (L), Where L Represents a Potentially Terdentate N,N ‘ -Chelating α-Diimine . Organometallics 18:21, pages 4380-4389.
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L. Helm & A.E. Merbach. (1999) Water exchange on metal ions: experiments and simulations. Coordination Chemistry Reviews 187:1, pages 151-181.
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Grazyna Stochel & Rudi van Eldik. (1999) Elucidation of inorganic reaction mechanisms through volume profile analysis. Coordination Chemistry Reviews 187:1, pages 329-374.
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Thomas W. Swaddle & Peter A. Tregloan. (1999) Electrode reactions of metal complexes in solution at high pressures. Coordination Chemistry Reviews 187:1, pages 255-289.
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Michael Becker, Siegfried Schindler, Kenneth D. Karlin, Thomas A. Kaden, Susan Kaderli, Tania Palanché & Andreas D. Zuberbühler. (1999) Intramolecular Ligand Hydroxylation:  Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen. Inorganic Chemistry 38:9, pages 1989-1995.
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Rudi van Eldik. (1999) Mechanistic studies in coordination chemistry. Coordination Chemistry Reviews 182:1, pages 373-410.
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Rudi Van Eldik, Carlos Dücker-Benfer & Florian Thaler. 1999. 1 58 .
Rudi Eldik. 1999. High Pressure Molecular Science. High Pressure Molecular Science 267 289 .
Jiri Jonas. 1999. High Pressure Molecular Science. High Pressure Molecular Science 231 259 .
Ji Sun, Chang Su, Martin Meier, Stephan S. Isied, James F. Wishart & Rudi van Eldik. (1998) Mechanistic Information from the First Volume Profile Analysis for Intramolecular Electron-Transfer Reactions:  Tetraammine−Ruthenium(Ligand) Complexes of Cytochrome c . Inorganic Chemistry 37:24, pages 6129-6135.
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A. Drljaca, C. D. Hubbard, R. van Eldik, T. Asano, M. V. Basilevsky & W. J. le Noble. (1998) Activation and Reaction Volumes in Solution. 3. Chemical Reviews 98:6, pages 2167-2290.
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Alexander Drljaca, Achim Zahl & Rudi van Eldik. (1998) High-Pressure Oxygen-17 NMR Study of the Dihydroxo-Bridged Rhodium(III) Hydrolytic Dimer. Mechanistic Evidence for Limiting Dissociative Water Exchange Pathways. Inorganic Chemistry 37:16, pages 3948-3953.
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Jos Nijhoff, Maarten J. Bakker, František Hartl, Derk J. Stufkens, Fu & Rudi van Eldik. (1998) Photochemistry of the Triangular Clusters Os 3 (CO) 10 (α-diimine): Homolysis of an Os−Os Bond and Solvent-Dependent Formation of Biradicals and Zwitterions . Inorganic Chemistry 37:4, pages 661-668.
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Israel Zilbermann, Eric Maimon, Haim Cohen, Rudi van Eldik & Dan Meyerstein. (1998) Cooperative oxidation of edta by Ni(III) and dioxygen. A pulse radiolysis study. Inorganic Chemistry Communications 1:2, pages 46-48.
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Gábor Laurenczy, Ferenc Lukács & Raymond Roulet. (1998) A new variable temperature and pressure infrared cell to study liquid and liquid–gas systems. Analytica Chimica Acta 359:3, pages 275-281.
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Etsuko Fujita & Rudi van Eldik. (1998) Effect of Pressure on the Reversible Binding of Acetonitrile to the “Co(I)−CO 2 ” Adduct To Form Cobalt(III) Carboxylate . Inorganic Chemistry 37:2, pages 360-362.
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Rudi Van Eldik & Peter C. Ford. 1998. Advances in Photochemistry. Advances in Photochemistry 61 146 .
Sara Goldstein, Dan Meyerstein, Rudi van Eldik & Gidon Czapski. (1997) Spontaneous Reactions and Reduction by Iodide of Peroxynitrite and Peroxynitrate:  Mechanistic Insight from Activation Parameters. The Journal of Physical Chemistry A 101:38, pages 7114-7118.
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Michael Hartmann, Timothy Clark & Rudi van Eldik. (1997) Hydration and Water Exchange of Zinc(II) Ions. Application of Density Functional Theory. Journal of the American Chemical Society 119:33, pages 7843-7850.
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Fu, Horst Kisch & Rudi van Eldik. (1997) Competing Thermal and Photochemical Ligand Substitution Reactions of the Dimetallacycle (CO) 4 Mo(μ-PMD) 2 Mo(CO) 4 (PMD = Pentamethylenediazirine). Mechanistic Information from Entering Nucleophile and Pressure Dependences . Organometallics 16:15, pages 3439-3446.
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Diane E. Cabelli, James F. Wishart, Jerzy Holcman, Martin Meier & Rudi van Eldik. (1997) Copper(III) Pyrophosphate Complexes in Aqueous Solution. A Pulse Radiolysis Study at Ambient and High Pressure. The Journal of Physical Chemistry A 101:28, pages 5131-5136.
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Janusz Chatlas, Donald A. House, Anton Neubrand & Rudi van Eldik. (1997) Anionopentaaminecobalt(III) complexes with polyamine ligands 27. Activation volumes for spontaneous and Hg2+-assisted chloride release reactions. Inorganica Chimica Acta 257:2, pages 173-177.
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G. Stochel & R. van Eldik. (1997) Photochemical behaviour of metal complexes. Pressure effect versus mechanism. Coordination Chemistry Reviews 159, pages 153-170.
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Roland Billing. (1997) Optical and photoinduced electron transfer in ion pairs of coordination compounds. Coordination Chemistry Reviews 159, pages 257-270.
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Kenneth K. Andersen, Colin D. Hubbard, Achim Gerhard, Rudi Van Eldik & Martin G. Kociolek. (1997) REACTIVITY OF NUCLEOPHILES TOWARDS X-3-(p-TOLYLSULFONYL)-1,2,3-BENZOXATHIAZOLE 2,2-DIOXIDES: KINETICS, ACTIVATION VOLUMES AND MECHANISM. Journal of Physical Organic Chemistry 10:3, pages 175-181.
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Fu & Rudi van Eldik. (1997) Photosubstitution Reactions of M(CO) 4 (1,10-phenanthroline) (M = Mo, W). Influence of Entering Ligand, Irradiation Wavelength, and Pressure . Organometallics 16:4, pages 572-578.
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Fu Wen-Fu & Rudi van Eldik. (1996) Photo-substitution reactions of Cr(CO)4(1,10-phenanthroline). Mechanistic information from entering nucleophile, irradiation wavelength and pressure dependences. Inorganica Chimica Acta 251:1-2, pages 341-346.
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Pascal Bugnon, Gábor Laurenczy, Yves Ducommun, Pierre-Yves Sauvageat, André E. Merbach, Roger Ith, René Tschanz, Michael Doludda, Rolf Bergbauer & Ernst Grell. (1996) High-Pressure Stopped-Flow Spectrometer for Kinetic Studies of Fast Reactions by Absorbance and Fluorescence Detection. Analytical Chemistry 68:17, pages 3045-3049.
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Jaqueline L. Kiplinger, Thomas G. Richmond, Atta M. Arif, Carlos Dücker-Benfer & Rudi van Eldik. (1996) Synthesis and Characterization of Highly Fluorinated Tungsten(II) Metallacyclopropene Complexes. Kinetics and Mechanism of an Unprecedented η 2 -Vinyl Isomerization . Organometallics 15:6, pages 1545-1564.
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Thomas Kowall, François Foglia, Lothar Helm & André E. Merbach. (2006) Mechanisms of Water Exchange between Lanthanide(III) Aqua Ions [Ln(H 2 O) n ] 3+ and bulk water: A Molecular Dynamics Simulation Approach Including High‐Pressure Effects . Chemistry – A European Journal 2:3, pages 285-294.
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Xiaoping Zhang, Colin D. Hubbard & Rudi van Eldik. (1996) Carbonic Anhydrase Catalysis:  A Volume Profile Analysis. The Journal of Physical Chemistry 100:21, pages 9161-9171.
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Andrew L. Feig, Michael Becker, Siegfried Schindler, Rudi van Eldik & Stephen J. Lippard. (1996) Mechanistic Studies of the Formation and Decay of Diiron(III) Peroxo Complexes in the Reaction of Diiron(II) Precursors with Dioxygen. Inorganic Chemistry 35:9, pages 2590-2601.
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Sofi K. C. Elmroth & Lars I. Elding. (1996) Competitive Substitution and Electron Transfer in Reactions between Haloamminegold(III) and Halocyanoaurate(III) Complexes and Thiocyanate. Inorganic Chemistry 35:8, pages 2337-2342.
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Lance Ballard & Jiri Jonas. 1996. Annual Reports on NMR Spectroscopy Volume 33. Annual Reports on NMR Spectroscopy Volume 33 115 150 .
Saad Alshehri, John Burgess, Rudi van Eldik & Colin D. Hubbard. (1995) Leaving group effects on ligand substitution reactions of pentacyanoferrate(II) complexes: rate constant and activation volume correlations. Inorganica Chimica Acta 240:1-2, pages 305-311.
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Carlos Dücker‐Benfer, Rudi van Eldik & Renata Dreos. (2003) Electronically Tuned trans Labilization Controls the Substitution Behavior of Rhodoximes . Angewandte Chemie International Edition in English 34:20, pages 2245-2247.
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Carlos Dücker‐Benfer, Rudi van Eldik & Renata Dreos. (2006) Beeinflussung des Substitutionsverhaltens von Rhodoximen durch elektronisch gesteuerte trans ‐Labilisierung . Angewandte Chemie 107:20, pages 2414-2416.
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István Fábián & Rudi Van Eldik. (2004) Temperature and pressure effects on the kinetics of the Bromate ion‐iodide ion‐L‐ascorbic acid clock reaction. International Journal of Chemical Kinetics 27:5, pages 491-498.
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Stephen F. Lincoln & André E. Merbach. 1995. 1 88 .
Haim Cohen, Rudi van Eldik, Wolfgang Gaede, Achim Gerhard, Sara Goldstein, Gidon Czapski & Dan Meyerstein. (1994) Volumes of activation for ?-elimination and related reactions of chromium(III)-alkyl complexes in aqueous solutions. Inorganica Chimica Acta 227:1, pages 57-61.
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Gábor Laurenczy, Giacomo Bondietti, André E. Merbach, Bertrand Moullet & Raymond Roulet. (2004) Variable‐Temperature and ‐Pressure 31 P‐NMR Study of the Intramolecular PPh 3 Migration in the Cluster Compound [Ir 2 Rh 2 (CO) 11 PPh 3 ] . Helvetica Chimica Acta 77:2, pages 547-553.
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Kedika B. Reddy, Shibai Cao, Edward C. Orr, István Fábián, Rudi van Eldik & Edward M. Eyring. (1994) Mechanistic information on ligand-substitution reactions of gadolinium( III ) in aqueous solution from high-pressure stopped-flow experiments . J. Chem. Soc., Dalton Trans.:17, pages 2497-2501.
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Wolfgang Gaede & Rudi van Eldik. (1994) Kinetics and mechanism of the phosphate-catalyzed heterolysis of the metal-carbon ? bond of ?-hydroxyalkyl-chromium(III) complexes. Effects of the non-participating ligands, temperature and pressure. Inorganica Chimica Acta 215:1-2, pages 173-178.
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A. Abou-Hamdan, N. Burki, S.F. Lincoln, A.E. Merbach & S.J.F. Vincent. (1993) Variable-pressure 1H NMR studies of hexamethylphosphoramide and trimethyl phosphate exchange on dioxouranium(VI). Inorganica Chimica Acta 207:1, pages 27-30.
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Pierre-André Pittet, Lynda Dadci, Pascal Zbinden, Amira Abou-Hamdan & André E. Merbach. (1993) High-pressure proton NMR study of acetonitrile exchange kinetics on [Rh2(CH3CN)10]4+ and 17O NMR investigation of aqueous solutions of [Rh2(H2O)10]4 +. Inorganica Chimica Acta 206:2, pages 135-140.
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Gabriel González, Manuel Martinez, Xavier Solans & Mercè Font-Bardía. (1993) Kinetic studies on sterically hindered pentaaminecobalt(III) complexes. Synthesis, anation reactions and crystal structure of [Co(EtNH2)5H2O] (ClO4)3·2H2O. Inorganica Chimica Acta 203:2, pages 229-233.
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Rudi Eldik. 1993. High Pressure Chemistry, Biochemistry and Materials Science. High Pressure Chemistry, Biochemistry and Materials Science 329 344 .
Rudi Eldik. 1993. High Pressure Chemistry, Biochemistry and Materials Science. High Pressure Chemistry, Biochemistry and Materials Science 309 328 .
Rudi van Eldik. 1993. Organic Synthesis via Organometallics (OSM 4). Organic Synthesis via Organometallics (OSM 4) 27 39 .
Kedika Bal Reddy, B.Ryan Brady, Edward M. Eyring & Rudi van Eldik. (1992) Effect of pressure on intramolecular ring-closure reactions of molybdenum carbonyl complexes induced by flash photolysis. Journal of Organometallic Chemistry 440:1-2, pages 113-117.
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Timothy I. Odiaka & Rudi van Eldik. (1992) Significance of entropies and volumes of activation for the addition of 4-formylpyridine to tricarbonyl(1?5-?-dienyl)iron(II) complexes (dienyl = C6H7, 2-MeOC6H6 and C7H9). Journal of Organometallic Chemistry 438:1-2, pages 131-142.
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Timothy I. Odiaka & Rudi van Eldik. (1992) Effects of temperature and pressure on the addition of 4-ethylpyridine to tricarbonyl(η 5 -dienyl)iron( II ) complexes . J. Chem. Soc., Dalton Trans.:14, pages 2215-2218.
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