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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 16, 1994 - Issue 1-2
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Original Articles

Aqueous Chemistry of Labile Oxovanadates: Relevance to Biological Studies

Pages 1-33 | Received 05 Oct 1993, Published online: 23 Sep 2006

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Read on this site (3)

Enrique J. Baran. (2001) OXOVANADIUM(IV) COMPLEXES OF CARBOHYDRATES. Journal of Carbohydrate Chemistry 20:9, pages 769-788.
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N.S. Neelam Jalil, J.J. Bonire & I.Y. Abdulmumin. (1998) Complexing Behaviour of Vanadate Towards Thrombin. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 28:4, pages 669-681.
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Debbie C. Crans, Anastasios D. Keramidas & Chryssoula Drouza. (1996) Organic Vanadium Compounds - Transition State Analogy with Organic Phosphorus Compounds. Phosphorus, Sulfur, and Silicon and the Related Elements 109:1-4, pages 245-248.
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Articles from other publishers (104)

Sonia Irais Gonzalez-Cano, Gonzalo Flores, Jorge Guevara, Julio Cesar Morales-Medina, Samuel Treviño & Alfonso Diaz. (2024) Polyoxidovanadates a new therapeutic alternative for neurodegenerative and aging diseases. Neural Regeneration Research 19:3, pages 571-577.
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Kulsum Hashmi, Satya, Sakshi Gupta, Armeen Siddique, Tahmeena Khan & Seema Joshi. (2023) Medicinal applications of vanadium complexes with Schiff bases. Journal of Trace Elements in Medicine and Biology 79, pages 127245.
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Samantha L. Miller, Ernestas Gaidamauskas, Ataf Ali Altaf, Debbie C. Crans & Nancy E. Levinger. (2023) Where Are Sodium Ions in AOT Reverse Micelles? Fluoride Anion Probes Nanoconfined Ions by 19 F Nuclear Magnetic Resonance Spectroscopy . Langmuir 39:22, pages 7811-7819.
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Sabrina Bendia, Wafa Benabid, Riadh Bourzami & Kamel Ouari. (2023) Spectroscopic characterization of a mononuclear oxovanadium (IV) Schiff base complex. Oxidation catalysis applications and antibacterial activities. Journal of Molecular Structure 1281, pages 135131.
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Sazida Yasmin Sultana, Hiya Talukdar, Biraj Jyoti Borah, Mitu Sharma & Nashreen S. Islam. (2022) Synthesis, structure and catalytic activity of new oxovanadium(V) complexes with deferiprone and N,N-donor ligands. Inorganica Chimica Acta 534, pages 120813.
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Manuel Aureliano, Nadiia I. Gumerova, Giuseppe Sciortino, Eugenio Garribba, Craig C. McLauchlan, Annette Rompel & Debbie C. Crans. (2022) Polyoxidovanadates' interactions with proteins: An overview. Coordination Chemistry Reviews 454, pages 214344.
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Manuel Aureliano, Nadiia I. Gumerova, Giuseppe Sciortino, Eugenio Garribba, Annette Rompel & Debbie C. Crans. (2021) Polyoxovanadates with emerging biomedical activities. Coordination Chemistry Reviews 447, pages 214143.
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Henam Sylvia Devi, Akshita Mishra, Md Samim Reza, Parvez Akhtar, Henam Premananda Singh, Thiyam David Singh & Madhusudan Singh. (2021) Controlled phase synthesis of V m O n in differing oxidation states using a simplified formic acid process, quantified with a new generalized index designed for use with public domain material process information . Green Chemistry 23:20, pages 8200-8211.
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Debbie C. Crans, Jordan T. Koehn, Stephanie M. Petry, Caleb M. Glover, Asanka Wijetunga, Ravinder Kaur, Aviva Levina & Peter A. Lay. (2019) Hydrophobicity may enhance membrane affinity and anti-cancer effects of Schiff base vanadium( v ) catecholate complexes . Dalton Transactions 48:19, pages 6383-6395.
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Zhen Jiang, Konstantin Klyukin, Kaellen Miller & Vitaly Alexandrov. (2019) Mechanistic Theoretical Investigation of Self-Discharge Reactions in a Vanadium Redox Flow Battery. The Journal of Physical Chemistry B 123:18, pages 3976-3983.
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Aleksandar Bijelic & Annette Rompel. (2018) Polyoxometalates: more than a phasing tool in protein crystallography. ChemTexts 4:3.
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Jiawei Wen, Pengge Ning, Hongbin Cao, Zhi Sun, Yi Zhang & Gaojie Xu. (2018) Recovery of High-Purity Vanadium from Aqueous Solutions by Reusable Primary Amines N1923 Associated with Semiquantitative Understanding of Vanadium Species. ACS Sustainable Chemistry & Engineering 6:6, pages 7619-7626.
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Gongde Chen & Haizhou Liu. (2017) Understanding the Reduction Kinetics of Aqueous Vanadium(V) and Transformation Products Using Rotating Ring-Disk Electrodes. Environmental Science & Technology 51:20, pages 11643-11651.
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Sandhya Rani Gogoi, Gangutri Saikia, Kabirun Ahmed, Rituparna Duarah & Nashreen S. Islam. (2017) Niobium(V) peroxo α-amino acid complexes: Synthesis, stability and kinetics of inhibition of acid phosphatase activity. Polyhedron 121, pages 142-154.
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Daniele Sanna, Valeria Ugone, Angela Fadda, Giovanni Micera & Eugenio Garribba. (2016) Behavior of the potential antitumor VIVO complexes formed by flavonoid ligands. 3. Antioxidant properties and radical production capability. Journal of Inorganic Biochemistry 161, pages 18-26.
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Milan Žižić, Zoran Miladinović, Marina Stanić, Mirzeta Hadžibrahimović, Miroslav Živić & Joanna Zakrzewska. (2016) 51V NMR investigation of cell-associated vanadate species in Phycomyces blakesleeanus mycelium. Research in Microbiology 167:6, pages 521-528.
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Issam Omri, Tahar Mhiri & Mohsen Graia. (2016) A new monohydrogendecavanadate (V)-dihydrogendecavanadate (V) with dibutylammonium cations [C 8 NH 20 ] 9 [H 2 V 10 O 28 ][HV 10 O 28 ].2.13H 2 O: Synthesis, crystal structure, vibrational and optical properties. Journal of Molecular Structure 1108, pages 334-340.
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Issam Omri, Tahar Mhiri & Mohsen Graia. (2015) Novel decavanadate cluster complex (HImz)12(V10O28)2·3H2O: Synthesis, characterization, crystal structure, optical and thermal properties. Journal of Molecular Structure 1098, pages 324-331.
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Craig C. McLauchlan, Benjamin J. Peters, Gail R. Willsky & Debbie C. Crans. (2015) Vanadium–phosphatase complexes: Phosphatase inhibitors favor the trigonal bipyramidal transition state geometries. Coordination Chemistry Reviews 301-302, pages 163-199.
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Tatsuya Ueki, Nobuo Yamaguchi, Romaidi, Yoshiaki Isago & Hisashi Tanahashi. (2015) Vanadium accumulation in ascidians: A system overview. Coordination Chemistry Reviews 301-302, pages 300-308.
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Aleksandar Bijelic & Annette Rompel. (2015) The use of polyoxometalates in protein crystallography – An attempt to widen a well-known bottleneck. Coordination Chemistry Reviews 299, pages 22-38.
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Joanna Pranczk, Dagmara Jacewicz, Dariusz Wyrzykowski, Andrzej Wojtczak, Aleksandra Tesmar & Lech Chmurzyński. (2015) Crystal Structure, Antioxidant Properties and Characteristics in Aqueous Solutions of the Oxidovanadium(IV) Complex [VO(IDA)phen]·2H 2 O . European Journal of Inorganic Chemistry 2015:20, pages 3343-3349.
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M. Shahid, Prashant K. Sharma, Anjuli, Sandesh Chibber & Zafar A. Siddiqi. (2014) Isolation of a Decavanadate Cluster [H2V10O28][4-picH]4·2H2O (4-pic = 4-picoline): Crystal Structure, Electrochemical Characterization, Genotoxic and Antimicrobial Studies. Journal of Cluster Science 25:5, pages 1435-1447.
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Debbie C. Crans, Kellie A. Woll, Kestutis Prusinskas, Michael D. Johnson & Eugenijus Norkus. (2013) Metal Speciation in Health and Medicine Represented by Iron and Vanadium. Inorganic Chemistry 52:21, pages 12262-12275.
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Alvin A. Holder, Patrick Taylor, Anthony R. Magnusen, Erick T. Moffett, Kyle Meyer, Yiling Hong, Stuart E. Ramsdale, Michelle Gordon, Javelyn Stubbs, Luke A. Seymour, Dhiraj Acharya, Ralph T. Weber, Paul F. Smith, G. Charles Dismukes, Ping Ji, Laura Menocal, Fengwei Bai, Jennie L. Williams, Donald M. Cropek & William L. Jarrett. (2013) Preliminary anti-cancer photodynamic therapeutic in vitro studies with mixed-metal binuclear ruthenium(ii)–vanadium(iv) complexes. Dalton Transactions 42:33, pages 11881.
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Abeer Al-Qatati, Fabio L. Fontes, B. George Barisas, Dongmei Zhang, Deborah A. Roess & Debbie C. Crans. (2013) Raft localization of Type I Fcε receptor and degranulation of RBL-2H3 cells exposed to decavanadate, a structural model for V2O5. Dalton Transactions 42:33, pages 11912.
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Suman Kundu, Suvendu Maity, Amarendra Nath Maity, Shyue-Chu Ke & Prasanta Ghosh. (2013) Stabilization of oxidovanadium(iv) by organic radicals. Dalton Transactions 42:13, pages 4586.
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Zafar A. Siddiqi, Anjuli, Prashant K. Sharma, M. Shahid, Mohd. Khalid, Armeen Siddique & Sarvendra Kumar. (2012) Novel decavanadate cluster complexes [H2V10O28][LH]4·nH2O (L=Imidazole, n=2 or 2-methylimidazole, n=0): Preparation, characterization and genotoxic studies. Journal of Molecular Structure 1029, pages 86-91.
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Timothy L. Turner, Victoria H. Nguyen, Craig C. McLauchlan, Zaneta Dymon, Benjamin M. Dorsey, Jaqueline D. Hooker & Marjorie A. Jones. (2012) Inhibitory effects of decavanadate on several enzymes and Leishmania tarentolae In Vitro. Journal of Inorganic Biochemistry 108, pages 96-104.
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Nada Bošnjaković-Pavlović, Josselin Prévost & Anne Spasojević-de Biré. (2011) Crystallographic Statistical Study of Decavanadate Anion Based-Structures: Toward a Prediction of Noncovalent Interactions. Crystal Growth & Design 11:9, pages 3778-3789.
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Amit Saha Roy, Pinaki Saha, Nirmal Das Adhikary & Prasanta Ghosh. (2011) o -Iminobenzosemiquinonate and o -Imino- p -methylbenzosemiquinonate Anion Radicals Coupled VO 2+ Stabilization . Inorganic Chemistry 50:6, pages 2488-2500.
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Manuel Aureliano. (2011) Recent perspectives into biochemistry of decavanadate. World Journal of Biological Chemistry 2:10, pages 215.
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Jana Gáliková, Jozef Tatiersky, Erik Rakovský & Peter Schwendt. (2010) Synthesis and characterization of dinuclear vanadium(V) oxido peroxido tartrato complexes. Transition Metal Chemistry 35:6, pages 751-756.
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Debbie C. Crans, Boyan Zhang, Ernestas Gaidamauskas, Anastasios D. Keramidas, Gail R. Willsky & Chris R. Roberts. (2010) Is Vanadate Reduced by Thiols under Biological Conditions? Changing the Redox Potential of V(V)/V(IV) by Complexation in Aqueous Solution. Inorganic Chemistry 49:9, pages 4245-4256.
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Maria João Pereira, Eugénia Carvalho, Jan W. Eriksson, Debbie C. Crans & Manuel Aureliano. (2009) Effects of decavanadate and insulin enhancing vanadium compounds on glucose uptake in isolated rat adipocytes. Journal of Inorganic Biochemistry 103:12, pages 1687-1692.
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Vincent Laizé, Daniel M. Tiago, Manuel Aureliano & M. Leonor Cancela. (2009) New insights into mineralogenic effects of vanadate. Cellular and Molecular Life Sciences 66:24, pages 3831-3836.
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Nada Bošnjaković-Pavlović, Anne Spasojević-de Biré, Isabel Tomaz, Nouzha Bouhmaida, Fernando Avecilla, Ubavka B. Mioč, João Costa Pessoa & Nour Eddine Ghermani. (2009) Electronic Properties of a Cytosine Decavanadate: Toward a Better Understanding of Chemical and Biological Properties of Decavanadates. Inorganic Chemistry 48:20, pages 9742-9753.
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Debbie C. Crans, Bharat Baruah, Allison Ross & Nancy E. Levinger. (2009) Impact of confinement and interfaces on coordination chemistry: Using oxovanadate reactions and proton transfer reactions as probes in reverse micelles. Coordination Chemistry Reviews 253:17-18, pages 2178-2185.
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Mohsen Graia, Regaya Ksiksi & Ahmed Driss. (2009) Nonapiperidinium monohydrogen decavanadate tetranitrate. Acta Crystallographica Section E Structure Reports Online 65:8, pages m953-m954.
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M. A. Sedgwick, D. C. Crans & N. E. Levinger. (2009) What Is Inside a Nonionic Reverse Micelle? Probing the Interior of Igepal Reverse Micelles Using Decavanadate. Langmuir 25:10, pages 5496-5503.
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Manuel Aureliano & Debbie C. Crans. (2009) Decavanadate (V10O286-) and oxovanadates: Oxometalates with many biological activities. Journal of Inorganic Biochemistry 103:4, pages 536-546.
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Chunxiang Li, Yan Zhang, Kevin P. O’Halloran, Jiawei Zhang & Huiyuan Ma. (2008) Electrochemical behavior of vanadium-substituted Keggin-type polyoxometalates in aqueous solution. Journal of Applied Electrochemistry 39:3, pages 421-427.
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Manuel Aureliano. (2009) Decavanadate: a journey in a search of a role. Dalton Transactions:42, pages 9093.
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Susana Ramos, Rui O. Duarte, José J. G. Moura & Manuel Aureliano. (2009) Decavanadate interactions with actin: cysteine oxidation and vanadyl formation. Dalton Transactions:38, pages 7985.
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Anindita Sarkar & Samudranil Pal. (2008) Decavanadates with [Et3NH]+ and [Me2HN(CH2)2NHMe2]2+: Variation in protonation state and self-assembly. Polyhedron 27:17, pages 3472-3476.
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Sandra Sofia Soares, Fernando Henao, Manuel Aureliano & Carlos Gutiérrez-Merino. (2008) Vanadate Induces Necrotic Death in Neonatal Rat Cardiomyocytes Through Mitochondrial Membrane Depolarization. Chemical Research in Toxicology 21:3, pages 607-618.
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S.S. Soares, H. Martins, C. Gutiérrez-Merino & M. Aureliano. (2008) Vanadium and cadmium in vivo effects in teleost cardiac muscle: Metal accumulation and oxidative stress markers. Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology 147:2, pages 168-178.
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Ana González Baró, Ingegärd Andersson, Lage Pettersson & András Gorzsás. (2008) Speciation in the aqueous peroxovanadate–maltol and (peroxo)vanadate–uridine systems. Dalton Transactions:8, pages 1095.
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Teresa Tiago, Paulo Martel, Carlos Gutiérrez-Merino & Manuel Aureliano. (2007) Binding modes of decavanadate to myosin and inhibition of the actomyosin ATPase activity. Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics 1774:4, pages 474-480.
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Susana Ramos, Miguel Manuel, Teresa Tiago, Rui Duarte, Jorge Martins, Carlos Gutiérrez-Merino, José J.G. Moura & Manuel Aureliano. (2006) Decavanadate interactions with actin: Inhibition of G-actin polymerization and stabilization of decameric vanadate. Journal of Inorganic Biochemistry 100:11, pages 1734-1743.
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Debbie C. Crans, Bharat Baruah & Nancy E. Levinger. (2006) Oxovanadates: a novel probe for studying lipid–water interfaces. Biomedicine & Pharmacotherapy 60:4, pages 174-181.
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Anton D. Michel, Mengle Xing, Kyla M. Thompson, Clare A. Jones & Patrick P.A. Humphrey. (2006) Decavanadate, a P2X receptor antagonist, and its use to study ligand interactions with P2X7 receptors. European Journal of Pharmacology 534:1-3, pages 19-29.
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Patricia C. Wilkins, Michael D. Johnson, Alvin A. Holder & Debbie C. Crans. (2006) Reduction of Vanadium(V) by l -Ascorbic Acid at Low and Neutral pH:  Kinetic, Mechanistic, and Spectroscopic Characterization . Inorganic Chemistry 45:4, pages 1471-1479.
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Teresa Tiago, Manuel Aureliano & José J.G. Moura. (2004) Decavanadate as a biochemical tool in the elucidation of muscle contraction regulation. Journal of Inorganic Biochemistry 98:11, pages 1902-1910.
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