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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 18, 1996 - Issue 3
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Original Articles

Azide Bridged Dicopper and Dinickel Complexes: Structure and Magnetism

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Pages 125-144 | Received 19 Oct 1995, Published online: 23 Sep 2006

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (3)

Habibar Chowdhury, Rajesh Bera, Corrado Rizzoli, Dariusz Bieńko & Chandan Adhikary. (2020) Double end-on azido derivative of a tridentate (NNO) Schiff base dimeric copper(II) complex: synthesis, X-ray structure, magnetic property and catalytic effectiveness. Journal of Coordination Chemistry 73:20-22, pages 3062-3078.
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Dasarath Mal, Rupam Sen, Chandan Adhikary, Yoshitaro Miyashita, Ken-Ichi Okamoto, Ashis Bhattacharjee, Philipp Gütlich & Subratanath Koner. (2008) Synthesis, X-ray crystal structure and magnetic study of a μ 1,5-dca bridged ferromagnetic dimeric copper(II) complex. Journal of Coordination Chemistry 61:21, pages 3486-3492.
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Subratanath Koner, Seiichiro Iijima, Masanobu Watanabe & Masaru Sato. (2003) μ-Azido- and μ-Oxo-Complexes of Fe(III) with Schiff Bases. Journal of Coordination Chemistry 56:2, pages 103-111.
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Articles from other publishers (82)

Manas Kumar Mahish, Luca M. Carrella, Apu Patra, Dama Saren, Ennio Zangrando, Pavel Vojtíšek, Eva Rentschler & Subal Chandra Manna. (2022) Tryptophan moiety ligand based tri/tetranuclear Ni( ii ) complexes: syntheses, structure and magnetic properties . New Journal of Chemistry 46:35, pages 16899-16906.
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Gavriilia T. Papanikolaou, Konstantinos N. Pantelis, Gerasimi Lazari, Luis Cunha-Silva, Albert Escuer & Theocharis C. Stamatatos. (2021) New classes of organic Chelate-Free coordination Polymers: An End-On Azido-Bridged Cu(II) 1-D chain composed of {Cu6(N3)12} repeating units. Polyhedron 206, pages 115315.
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Habibar Chowdhury & Chandan Adhikary. (2021) Syntheses, Structures, Magnetic Properties and Antibacterial Activities of Two Copper(II) Azido Complexes with Varied Nuclearities Containing Symmetrical 1,3-Diammine as Chelator. Asian Journal of Chemistry 33:2, pages 359-366.
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Santokh S. Tandon, Scott D. Bunge, Neil Patel, Esther C. Wang & Laurence K. Thompson. (2020) Self-Assembly of Antiferromagnetically-Coupled Copper(II) Supramolecular Architectures with Diverse Structural Complexities. Molecules 25:23, pages 5549.
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Theocharis C. Stamatatos & Eva Rentschler. (2019) Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me 3 SiN 3 : a new synthetic route to complexes with beautiful structures and diverse magnetic properties . Chemical Communications 55:1, pages 11-26.
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Aparup Paul, Albert Figuerola, Horst Puschmann & Subal Chandra Manna. (2019) Double μ2-(phenoxido)-bridged dinuclear and polynuclear nickel(II) complexes: Magnetic properties and DNA/protein interaction. Polyhedron 157, pages 39-48.
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Mima Č. Romanović, Božidar R. Čobeljić, Andrej Pevec, Iztok Turel, Vojislav Spasojević, Arshak A. Tsaturyan, Igor N. Shcherbakov, Katarina K. Anđelković, Marina Milenković, Dušanka Radanović & Milica R. Milenković. (2017) Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard’s T reagent. Polyhedron 128, pages 30-37.
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Santokh S. Tandon, Scott D. Bunge, Neil Patel & Joaquin Sanchiz. (2017) H-bonding directed formation of 1D-single chains, 2D-sheets, and 3D structures in magnetically coupled tetranuclear nickel(II) complexes with incomplete double cubane core. Polyhedron 123, pages 361-375.
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Pravat Ghorai, Anindita Chakraborty, Anangamohan Panja, Tapan Kumar Mondal & Amrita Saha. (2016) Mono- and di-nuclear nickel( ii ) complexes derived from NNO donor ligands: syntheses, crystal structures and magnetic studies of dinuclear analogues . RSC Advances 6:42, pages 36020-36030.
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Amitabha Datta, Kuheli Das, Chandana Sen, Nirmal Kumar Karan, Jui-Hsien Huang, Chia-Her Lin, Eugenio Garribba, Chittaranjan Sinha, Tulin Askun, Pinar Celikboyun & Sandeep B. Mane. (2015) Doubly end-on azido bridged mixed-valence cobalt trinuclear complex: Spectral study, VTM, inhibitory effect and antimycobacterial activity on human carcinoma and tuberculosis cells. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 148, pages 427-434.
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G. Liu, B. Chen & J. T. Cheng. (2014) A new azido-bridged copper(II) complex containing nitronyl nitroxide radicals: Syntheses, crystal structures. Crystallography Reports 59:7, pages 1033-1036.
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Albert Escuer, Jordi Esteban, Spyros P. Perlepes & Theocharis C. Stamatatos. (2014) The bridging azido ligand as a central ?player? in high-nuclearity 3d-metal cluster chemistry. Coordination Chemistry Reviews 275, pages 87-129.
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Xiangyu Liu, Peipei Cen, Hui Li, Hongshan Ke, Sheng Zhang, Qing Wei, Gang Xie, Sanping Chen & Shengli Gao. (2014) Solvent-Induced Syntheses, Crystal Structures, Magnetic Properties, and Single-Crystal-to-Single-Crystal Transformation of Azido-Cu(II) Coordination Polymers with 2-Naphthoic Acid as Co-ligand. Inorganic Chemistry 53:15, pages 8088-8097.
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A. ?witlicka-Olszewska, B. Machura & J. Mrozi?ski. (2014) Synthesis, magnetic behavior and structural characterization of novel one-dimensional copper(II) coordination polymer based on azide and oxalate bridges. Inorganic Chemistry Communications 43, pages 86-89.
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Ravindra Singh, Francesc Lloret & Rabindranath Mukherjee. (2014) Mono‐ and Di‐chloro‐bridged Discrete Dimers and Trimers and Mono‐Chloro‐Bridged 1D‐Coordination Polymer of Copper(II). Magneto‐structural Studies. Zeitschrift für anorganische und allgemeine Chemie 640:6, pages 1086-1094.
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Wen‐Bo Shi, Ai‐Li Cui & Hui‐Zhong Kou. (2013) In Situ Formation of Semichelating Ligands: A Strategy for Tuning the Magnetic Coupling in Azide‐Bridged Copper(II) Complexes. ChemPlusChem 79:2, pages 310-317.
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Wen-Bo Shi, Ai-Li Cui & Hui-Zhong Kou. (2014) Assembly of dinuclear copper( ii ) secondary building units into polymeric complexes: crystal structures and magnetic properties . CrystEngComm 16:34, pages 8027.
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Wolf Peter Fehlhammer & Wolfgang Beck. (2013) Azide Chemistry – An Inorganic Perspective, Part I Metal ­Azides: Overview, General Trends and Recent Developments. Zeitschrift für anorganische und allgemeine Chemie 639:7, pages 1053-1082.
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Gerard A. van Albada, Ilpo Mutikainen, Olivier Roubeau & Jan Reedijk. (2013) A dinuclear end-on azide-bridged copper(II) compound with weak antiferromagnetic interaction – Synthesis, characterization, magnetism and X-ray structure of bis[(μ-azido-κN1)-(azido-κN1)(1,3-bis(benzimidazol-2-yl)-2-methylpropane)copper(II)]. Journal of Molecular Structure 1036, pages 252-256.
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Aliakbar Dehno Khalaji, Smail Triki, Juan M. Clemente-Juan & Carlos J. G?mez-Garc?a. (2013) A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties. Polyhedron 50:1, pages 45-50.
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Anindita Chakraborty, Lingampalli Srinivasa Rao, Arun Kumar Manna, Swapan K. Pati, Joan Ribas & Tapas Kumar Maji. (2013) Discrete dinuclear complex to extended 2D compound in a Cu–azido system by controlling coligand stoichiometry: synthesis and magneto-structural correlations. Dalton Transactions 42:30, pages 10707.
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Wen-Bo Shi, Ai-Li Cui & Hui-Zhong Kou. (2012) Ligand-Directed Assembly of Azide-Bridged Tetranuclear, One-Dimensional and Two-Dimensional Cu(II) Complexes: Synthesis, Crystal Structure and Magnetic Properties. Crystal Growth & Design 12:7, pages 3436-3443.
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Dasarath Mal, Rupam Sen, Eva Rentschler, Ken-ichi Okamoto, Yoshitaro Miyashita & Subratanath Koner. (2012) Fully interlocked three-dimensional molecular scaffolding: Synthesis, X-ray structure, magnetic and nitrogen sorption study. Inorganica Chimica Acta 385, pages 27-30.
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Santokh S. Tandon, Scott D. Bunge, Joaquin Sanchiz & Laurence K. Thompson. (2012) Structures and Magnetic Properties of an Antiferromagnetically Coupled Polymeric Copper(II) Complex and Ferromagnetically Coupled Hexanuclear Nickel(II) Clusters. Inorganic Chemistry 51:5, pages 3270-3282.
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Devaraj Pandiarajan & Rengan Ramesh. (2012) ?-Halo bridged binuclear ruthenium(III) complexes featuring pyridazine ligands: Synthesis, structure, spectral and electrochemical properties. Polyhedron 34:1, pages 136-142.
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Noelia De la Pinta, M. Luz Fidalgo, Luis Lezama, Gotzon Madariaga, Lorena Callejo & Roberto Cortés. (2011) Ferromagnetic End-to-End Azides and Tetrahedral Cobalt: Unusual Findings in the M-BPA-Pseudohalide 2 System . Crystal Growth & Design 11:4, pages 1310-1317.
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Gerard A. van Albada, Maarten G. van der Horst, Ilpo Mutikainen, Urho Turpeinen & Jan Reedijk. (2011) Dinuclear and polynuclear Cu(II) azido-bridged compounds with 7-azaindole as a ligand. Synthesis, characterization and 3D structures. Inorganica Chimica Acta 367:1, pages 15-20.
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Hua-Cai Fang, Ying-Ying Ge, Hong-Yang Jia, Shan-Shan Li, Feng Sun, Li-Guo Zhang & Yue-Peng Cai. (2011) Construction of three high-dimensional supramolecular networks from temperature-driven conformational isomers. CrystEngComm 13:1, pages 67-71.
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Chandan Adhikary & Subratanath Koner. (2010) Structural and magnetic studies on copper(II) azido complexes. Coordination Chemistry Reviews 254:23-24, pages 2933-2958.
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Santokh S. Tandon, Scott D. Bunge, Neil Patel & Laurence K. Thompson. (2009) The synthesis, structure, and magnetic properties of a novel copper(II) cluster with H-bonding directed 3D-structure comprised of interconnected double-stranded ladders. Inorganic Chemistry Communications 12:10, pages 1077-1080.
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Rupam Sen, Ashis Bhattacharjee, Philipp Gütlich, Yoshitaro Miyashita, Ken-Ichi Okamoto & Subratanath Koner. (2009) Structural and magnetic diversity in metal-dicyanamido polymer moieties: Paramagnetic and antiferromagnetic 1D chain compound and weakly ferromagnetic 2D motif. Inorganica Chimica Acta 362:13, pages 4663-4670.
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Santokh Singh Tandon, Scott D. Bunge, Douglas Motry, José Sánchez CostaGuillem AromíJan Reedijk & Laurence K. Thompson. (2009) Copper Coordination Polymers Based on Single-Chain or Sheet Structures Involving Dinuclear and Tetranuclear Copper(II) Units: Synthesis, Structures, and Magnetostructural Correlations. Inorganic Chemistry 48:11, pages 4873-4881.
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Jiong-Peng Zhao, Bo-Wen Hu, E. C. Sañudo, Qian Yang, Yong-Fei Zeng & Xian-He Bu. (2009) Tuning the Structure and Magnetism of Azido-Mediated Cu II Systems by Coligand Modifications . Inorganic Chemistry 48:6, pages 2482-2489.
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Santokh S. Tandon, Scott D. Bunge, Robert Rakosi, Zhiqiang Xu & Laurence K. Thompson. (2009) Self-assembly of mixed-valence Co(ii/iii) and Ni(ii) clusters: azide-bridged 1D single chain coordination polymers comprised of tetranuclear units, tetranuclear Co(ii/iii) complexes, ferromagnetically coupled azide-bridged tetranuclear, and hexanuclear Ni(ii) complexes: synthesis, structural, and magnetic properties. Dalton Transactions:33, pages 6536.
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Gerard A. van Albada, Maarten G. van der Horst, Ilpo Mutikainen, Urho Turpeinen & Jan Reedijk. (2008) Synthesis, Crystal Structure and Spectroscopy of catena-poly-bis(azido-N1,N1)(2-Aminopyrimidine)Copper(II). Journal of Chemical Crystallography 38:6, pages 413-417.
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Guoqi Liu, Huanwang Jing & Desheng Xue. (2007) Synthesis, crystal structure, and magnetic properties of 1D Azido-bridged copper(II) complex. Structural Chemistry 19:1, pages 81-86.
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Feng-Mei Nie, Serhiy Demeshko, Sebastian Fuchs, Sebastian Dechert, Thomas Pruschke & Franc Meyer. (2008) Targeted self-assembly and quantum Monte Carlo magnetic study of an alternating nickel(ii) 1D coordination polymer composed of highly preorganized binuclear tectons. Dalton Transactions:30, pages 3971.
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Theocharis C. Stamatatos, Giannis S. Papaefstathiou, Leonard R. MacGillivray, Albert Escuer, Ramon Vicente, Eliseo Ruiz & Spyros P. Perlepes. (2007) Ferromagnetic Coupling in a 1D Coordination Polymer Containing a Symmetric [Cu(μ 1,1 -N 3 ) 2 Cu(μ 1,1 -N 3 ) 2 Cu] 2+ Core and Based on an Organic Ligand Obtained from the Solid State . Inorganic Chemistry 46:21, pages 8843-8850.
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Dasarath Mal, Subratanath Koner, Jean-Pierre Tuchagues & Georgina M. Rosair. (2007) Encapsulation of [Mn(bpy)3]2+ cations in 2D [Mn(dca)3]? sheet: Synthesis, X-ray structure and EPR study. Inorganica Chimica Acta 360:11, pages 3575-3580.
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Chandan Adhikary, Dasarath Mal, Rupam Sen, Ashis Bhattacharjee, Philipp G?tlich, Siddhartha Chaudhuri & Subratanath Koner. (2007) Synthesis, X-ray crystal structure and magnetic study of a novel ?2-1,1-azido bridged dimeric copper(II) complex. Polyhedron 26:8, pages 1658-1662.
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Serhiy Demeshko, Guido Leibeling, Sebastian Dechert, Sebastian Fuchs, Thomas Pruschke & Franc Meyer. (2007) Alternating Spin Chains: Controlled Assembly from Bimetallic Building Blocks and QMC Simulation of Spin Correlation. ChemPhysChem 8:3, pages 405-417.
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Sujittra Youngme, Thidarat Chotkhun, Somying Leelasubcharoen, Narongsak Chaichit, Chaveng Pakawatchai, Gerard A. van Albada & Jan Reedijk. (2007) Three new dinuclear bis-μ-azido-bridged Cu(II) compounds with di-2-pyridylamine as a ligand: Syntheses, X-ray structure and magnetic measurements. Polyhedron 26:3, pages 725-735.
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Fu-Chen Liu, Yong-Fei Zeng, Jiong-Peng Zhao, Bo-Wen Hu, Xian-He Bu, Joan Ribas & Stuart R. Batten. (2007) An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties. Inorganic Chemistry Communications 10:2, pages 129-132.
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Feng-juan CHEN, Guo-qi LIU, Zhi-hong XU & Zheng-zhi ZENG. (2007) Synthesis and Structure of a Novel Two-dimensional Manganese(II) Azide Complex with N-Methylimidazole. Analytical Sciences: X-ray Structure Analysis Online 23, pages x175-x176.
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Sujittra Youngme, Thidarat Chotkhun, Somying Leelasubcharoen, Narongsak Chaichit, Gerard A. van Albada, Marta Viciano-Chumillas & Jan Reedijk. (2007) An unique trinuclear triply bridged Cu(II) compound containing double acetato and single azido bridges: Synthesis, X-ray structure and magnetism of [Cu3(dpyam)2(μ1,1-N3)2(μ-CH3COO- κ-O1)2(μ-CH3COO-κ-O1,O2)2]·2(H2O) (dpyam=di-2-pyridylamine). Inorganic Chemistry Communications 10:1, pages 109-113.
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Dasarath Mal, Jean-Pierre Tuchagues, Santu Chakraborty, Alok K. Mukherjee, Rupam Sen & Subratanath Koner. (2006) Synthesis, X-ray crystal structure and magnetic study of the 1D {[Cu2(N,N,N?,N?-tetramethyl-ethylenediamine)2(?-1,5-dca)2(dca)2]}n complex. Inorganica Chimica Acta 359:13, pages 4431-4435.
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Licun Li, Daizheng Liao, Zonghui Jiang, Jean-Marie Mouesca & Paul Rey. (2006) An Unprecedented Asymmetric End-On Azido-Bridged Copper(II) Imino Nitroxide Complex: Structure, Magnetic Properties, and Density Functional Theory Analysis. Inorganic Chemistry 45:19, pages 7665-7670.
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Qing-Lun Wang, Xue-Qiao Jia, Dai-Zheng Liao, Shi-Ping Yan, Peng Cheng, Guang-Ming Yang, Hong-Xia Ren & Zong-Hui Jiang. (2006) A Binuclear Copper(II) Complex with Two Symmetric End-on Azido Bridges. Synthesis, Spectroscopy, Crystal Structure and Magnetism. Transition Metal Chemistry 31:4, pages 434-440.
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Mohamed Zbiri, Sandip Saha, Chandan Adhikary, Siddhartha Chaudhuri, Claude Daul & Subratanath Koner. (2006) Asymmetric ?2-1,1-azido bridged copper(II) complex: Synthesis, X-ray structure, magnetic study and DFT calculations. Inorganica Chimica Acta 359:4, pages 1193-1199.
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Hui-Bo Zhou, Dai-Zheng Liao, Li-Xin Deng, Jing-Zhong Yu, Yang-Ping Gao, Xiao-Fang Yang, Zong-Hui Jiang, Shi-Ping Yan & Peng Cheng. (2006) Synthesis, crystal structure and spectroscopic properties of two new complexes containing azido or dicyanamido bridges. Structural Chemistry 17:1, pages 43-47.
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Phalguni Chaudhuri, Rita Wagner, Sumit Khanra & Thomas Weyhermüller. (2006) Ferromagnetic vs. antiferromagnetic coupling in bis(µ 2 -1,1-azido)dinickel( ii ) complexes with syn- and anti-conformations of the end-on azide bridges . Dalton Trans.:41, pages 4962-4968.
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Serhiy Demeshko, Guido Leibeling, Sebastian Dechert & Franc Meyer. (2006) Targeted construction of azido-bridged Ni 4 complexes with decisive effect of µ-1,3-azide torsion on the spin ground state . Dalton Trans.:28, pages 3458-3465.
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Sandip Saha, Subratanath Koner, Jean-Pierre Tuchagues, Athanassios K. Boudalis, Ken-Ichi Okamoto, Surajit Banerjee & Dasarath Mal. (2005) Cation-Dependent Nuclearity of the Copper−Azido Moiety:  Synthesis, Structure, and Magnetic Study. Inorganic Chemistry 44:18, pages 6379-6385.
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Yufei Song, Chiara Massera, Manuel Quesada, Anna Maria Manotti Lanfredi, Ilpo Mutikainen, Urho Turpeinen & Jan Reedijk. (2005) A one-dimensional copper (II) coordination polymer [Cu3(ampym)2(μ1,1-N3)4(μ1,3-N3)2(dmf)2] (ampym = 2-aminopyrimidine) containing both end-on and end-to-end azido bridges. Inorganica Chimica Acta 358:4, pages 1171-1178.
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Franc Meyer, Serhiy Demeshko, Guido Leibeling, Berthold Kersting, Elisabeth Kaifer & Hans Pritzkow. (2005) Structures and Magnetic Properties of Tetranuclear Nickel( II ) Complexes with Unusual μ 3 ‐1,1,3 Azido Bridges . Chemistry – A European Journal 11:5, pages 1518-1526.
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Serhiy Demeshko, Guido Leibeling, Walter Maringgele, Franc Meyer, Christopher Mennerich, Hans-Henning Klauss & Hans Pritzkow. (2005) Structural Variety and Magnetic Properties of Tetranuclear Nickel(II) Complexes with a Central μ 4 -Azide . Inorganic Chemistry 44:3, pages 519-528.
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Sandip Saha, Dasarath Mal, Subratanath Koner, Ashis Bhattacherjee, Philipp Gütlich, Swastik Mondal, Monika Mukherjee & Ken-Ichi Okamoto. (2004) Synthesis, X-ray structure and magnetic properties of the azido adducts of quadridentate Schiff base manganese(III) complexes. Polyhedron 23:10, pages 1811-1817.
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Guido Leibeling, Serhiy Demeshko, Bernhard Bauer‐Siebenlist, Franc Meyer & Hans Pritzkow. (2004) Polynuclear and Extended Coordination Compounds from Preorganized Bimetallic Components: Tuning the Magnetic Properties of Dinickel( II ) Building Blocks . European Journal of Inorganic Chemistry 2004:12, pages 2413-2420.
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Subratanath Koner, Sandip Saha, Tallal Mallah & Ken-Ichi Okamoto. (2004) End-on double azido bridged copper (II) complex with (N, N, O) schiff base: synthesis, structure and magnetic study. Journal of Physics and Chemistry of Solids 65:4, pages 697-700.
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