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Liquid Crystals Volume 35, 2008 - Issue 4
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Original Articles

A comparison of proton‐detected 13C local field experiments with deuterium NMR at natural abundance for studying liquid crystals

James W. Emsley School of Chemistry, University of Southampton, Southampton SO17 1BJ, UKCorrespondence[email protected]
,
Philippe Lesot Laboratoire de Chimie Structurale Organique, RMN en Milieu Orienté, Université de Paris‐Sud (XI), ICMMO, UMR CNRS 8182, Bât. 410, F‐91405 Orsay cedex, France
,
Giuseppina De Luca Dipartimento di Chimica, Universita della Calabria, 87030 Arcavacata di Rende, Italy
,
Anne Lesage Université de Lyon, Laboratoire de Chimie, Ecole Normale Supérieure de Lyon, CNRS, France
,
Denis Merlet Laboratoire de Chimie Structurale Organique, RMN en Milieu Orienté, Université de Paris‐Sud (XI), ICMMO, UMR CNRS 8182, Bât. 410, F‐91405 Orsay cedex, France
&
Giuseppe Pileio School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK
Pages 443-464 | Received 23 Nov 2007, Accepted 22 Jan 2008, Published online: 23 May 2008

Citations (32)

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G. De Luca, J. W. Emsley, A. Lesage & D. Merlet. (2012) The structures and conformations of mesogenic molecules in the pre-transitional region of the isotropic phase: 5OCB and MBBA and their mixtures. Liquid Crystals 39:2, pages 211-219.
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G. Celebre, G. De Luca & M. Longeri. (2010) Exploiting the information content of dipolar couplings: determination of the temperature dependence of the inter-ring twist angle of biphenyl dissolved in uniaxial mesophases. Liquid Crystals 37:6-7, pages 923-933.
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Articles from other publishers (30)

C. Chamignon, M. Lelli, J. W. Emsley, G. R. Luckhurst & H. Zimmermann. (2023) Proton-decoupled deuterium NMR study of an asymmetric liquid crystal dimer having two nematic phases. Physical Review E 108:2.
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Giacomo Prampolini, Leandro Greff da Silveira, J. G. Vilhena & Paolo Roberto Livotto. (2021) Predicting Spontaneous Orientational Self-Assembly: In Silico Design of Materials with Quantum Mechanically Derived Force Fields . The Journal of Physical Chemistry Letters 13:1, pages 243-250.
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Debashis Majhi & Sergey V. Dvinskikh. (2021) Ion conformation and orientational order in a dicationic ionic liquid crystal studied by solid-state nuclear magnetic resonance spectroscopy. Scientific Reports 11:1.
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Debashis Majhi, Andrei V. Komolkin & Sergey V. Dvinskikh. (2020) NMR Spectroscopic Studies of Cation Dynamics in Symmetrically-Substituted Imidazolium-Based Ionic Liquid Crystals. International Journal of Molecular Sciences 21:14, pages 5024.
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Debashis Majhi, Jing Dai, Andrei V. Komolkin & Sergey V. Dvinskikh. (2020) Understanding ionic mesophase stabilization by hydration: a solid-state NMR study. Physical Chemistry Chemical Physics 22:24, pages 13408-13417.
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Lukas Jackalin, Boris B. Kharkov, Andrei V. Komolkin & Sergey V. Dvinskikh. (2018) Experimental strategies for 13 C– 15 N dipolar NMR spectroscopy in liquid crystals at the natural isotopic abundance . Physical Chemistry Chemical Physics 20:34, pages 22187-22196.
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Philippe Lesot. 2018. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.
J. W. Emsley, M. Lelli, G. R. Luckhurst & H. Zimmermann. (2017) NMR study of the director distribution adopted by the modulated nematic phases formed by liquid-crystal dimers with odd numbers of atoms in their spacers . Physical Review E 96:6.
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Lukas Jackalin & Sergey V. Dvinskikh. (2017) Natural Abundance Nitrogen-15 NMR in Thermotropic Liquid Crystals With Cyano-Group. Zeitschrift für Physikalische Chemie 231:4, pages 795-808.
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J. W. Emsley, M. Lelli, H. Joy, M.-G. Tamba & G. H. Mehl. (2016) Similarities and differences between molecular order in the nematic and twist-bend nematic phases of a symmetric liquid crystal dimer. Physical Chemistry Chemical Physics 18:14, pages 9419-9430.
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Ronald Y. Dong. 2016. 41 174 .
Philippe Lesot, Olivier Lafon & Philippe Berdagué. (2014) Correlation 2D-NMR experiments involving both 13 C and 2 H isotopes in oriented media: methodological developments and analytical applications . Magnetic Resonance in Chemistry 52:10, pages 595-613.
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Maria Enrica Di Pietro, Christie Aroulanda, Denis Merlet, Giorgio Celebre & Giuseppina De Luca. (2014) Conformational Investigation in Solution of a Fluorinated Anti-inflammatory Drug by NMR Spectroscopy in Weakly Ordering Media. The Journal of Physical Chemistry B 118:30, pages 9007-9016.
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Valentina Domenici, Moreno Lelli, Mario Cifelli, Vera Hamplova, Alessandro Marchetti & Carlo Alberto Veracini. (2014) Conformational Properties and Orientational Order of a de Vries Liquid Crystal Investigated through NMR Spectroscopy. ChemPhysChem 15:7, pages 1485-1495.
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Nitin P. Lobo, B. V. N. Phani Kumar, T. Narasimhaswamy & Asit Baran Mandal. (2014) 13 C NMR investigations and the molecular order of 4-(trans-4′-hexylcyclohexyl)-isothiocyanatobenzene (6CHBT) . Phys. Chem. Chem. Phys. 16:28, pages 14713-14721.
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T. Gopinath, Kaustubh R. Mote & Gianluigi Veglia. (2013) Sensitivity and resolution enhancement of oriented solid-state NMR: Application to membrane proteins. Progress in Nuclear Magnetic Resonance Spectroscopy 75, pages 50-68.
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Mario Cifelli, Valentina Domenici & Carlo Alberto Veracini. (2013) Recent advancements in understanding thermotropic liquid crystal structure and dynamics by means of NMR spectroscopy. Current Opinion in Colloid & Interface Science 18:3, pages 190-200.
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James W. Emsley, Moreno Lelli, Anne Lesage & Geoffrey R. Luckhurst. (2013) A Comparison of the Conformational Distributions of the Achiral Symmetric Liquid Crystal Dimer CB7CB in the Achiral Nematic and Chiral Twist-Bend Nematic Phases. The Journal of Physical Chemistry B 117:21, pages 6547-6557.
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Giorgio Celebre, Giuseppina De Luca & Maria Enrica Di Pietro. (2013) The stable conformations of 4,4′-dichloro-trans-stilbene in solution by liquid crystal NMR spectroscopy. Journal of Molecular Structure 1034, pages 283-288.
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B. B. Kharkov, V. I. Chizhik & S. V. Dvinskikh. (2012) Sign-sensitive determination of heteronuclear dipolar coupling to spin-1 by selective decoupling. The Journal of Chemical Physics 137:23.
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Laetitia Beguin, James W. Emsley, Moreno Lelli, Anne Lesage, Geoffrey R. Luckhurst, Bakir A. Timimi & Herbert Zimmermann. (2012) The Chirality of a Twist–Bend Nematic Phase Identified by NMR Spectroscopy. The Journal of Physical Chemistry B 116:27, pages 7940-7951.
Crossref
Giorgio Celebre, Giuseppina De Luca & Maria Enrica Di Pietro. (2012) Conformational Distribution of trans -Stilbene in Solution Investigated by Liquid Crystal NMR Spectroscopy and Compared with in Vacuo Theoretical Predictions . The Journal of Physical Chemistry B 116:9, pages 2876-2885.
Crossref
Markus Leutzsch, Matthias Findeisen & Stefan Berger. (2012) Aligned deuterochloroform in cross‐linked polystyrene as a new sample for adjusting the magic angle in HR‐MAS. Magnetic Resonance in Chemistry 50:1, pages 5-6.
Crossref
Olivier Lafon, Bingwen Hu, Jean‐Paul Amoureux & Philippe Lesot. (2011) Fast and High‐Resolution Stereochemical Analysis by Nonuniform Sampling and Covariance Processing of Anisotropic Natural Abundance 2D 2 H NMR Datasets . Chemistry – A European Journal 17:24, pages 6716-6724.
Crossref
S. Borsacchi, L. Calucci & M. Geppi. (2011) Orientational order of liquid crystals by 11B NMR spectroscopy. Chemical Physics Letters 508:1-3, pages 63-66.
Crossref
Giuseppina De Luca, James W. Emsley, Elodie Salager & Anne Lesage. (2010) A general strategy for obtaining 19F–19F and 13C–19F residual dipolar couplings in perfluorocarbons from the NMR spectroscopy of liquid crystalline samples. Physical Chemistry Chemical Physics 12:28, pages 7968.
Crossref
James W. Emsley, Philippe Lesot, Anne Lesage, Giuseppina De Luca, Denis Merlet & Giuseppe Pileio. (2010) The conformation and orientational order of a 1,2-disubstituted ethane nematogenic molecule (I22) in liquid crystalline and isotropic phases studied by NMR spectroscopy. Physical Chemistry Chemical Physics 12:12, pages 2895.
Crossref
Stefano Caldarelli. 2007. Encyclopedia of Magnetic Resonance. Encyclopedia of Magnetic Resonance.
J. W. Emsley, G. De Luca, A. Lesage, M. Longeri, F. B. Mallory & C. W. Mallory. (2008) The indirect through-space F–F coupling in peri-difluoronaphthalene: is it anisotropic?. Physical Chemistry Chemical Physics 10:43, pages 6534.
Crossref
Philippe Lesot. 2007. eMagRes. eMagRes 315 334 .

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