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Phosphorus and Sulfur and the Related Elements Volume 18, 1983 - Issue 1-3
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Original Articles

Mechanism of Nucleophilic Substitution at Tricovalent Phosphorus

Otto Dahl Department of General and Organic Chemìstry, The H. C. ⊘rsted Institute, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark
Pages 201-204 | Published online: 19 Dec 2006

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Read on this site (4)

Oleg I. Kolodiazhnyi & Anastasy O. Kolodiazhna. (2017) Stereochemistry of nucleophilic substitution at trivalent phosphorus. Phosphorus, Sulfur, and Silicon and the Related Elements 192:6, pages 621-633.
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Han Joong Koh, Suk Jin Kang & DennisN. Kevill. (2008) Reaction Mechanism Studies of Solvolytic Displacement of Chloride from Phosphorus. Phosphorus, Sulfur, and Silicon and the Related Elements 183:2-3, pages 364-368.
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BjarneH. Dahl, John Nielsen & Otto Dahl. (1987) Substituent Influence on the Reaction Rate of Deoxyribonucleoside Phosphoramidites with Deoxyribonucleosides Catalysed by Tetrazole. Nucleosides and Nucleotides 6:1-2, pages 457-460.
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Gyorgy Keglevich & LouisD. Quin. (1986) REACTION OF GRIGNARD REAGENTS WITH PHOSPHINOUS CHLORIDES HAVING THE ANTI-7-PHOSPHANORBORNENE FRAMEWORK. Phosphorus and Sulfur and the Related Elements 26:2, pages 129-137.
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Articles from other publishers (15)

Oleg I. Kolodiazhnyi & Anastasy Kolodiazhna. (2017) Nucleophilic substitution at phosphorus: stereochemistry and mechanisms. Tetrahedron: Asymmetry 28:12, pages 1651-1674.
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O. I. Kolodiazhnyi. (2017) Stereoselective reactions of trivalent phosphorus compounds. Russian Journal of General Chemistry 87:3, pages 425-441.
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Oleg I. Kolodiazhnyi. 2016. Asymmetric Synthesis in Organophosphorus Chemistry. Asymmetric Synthesis in Organophosphorus Chemistry 35 99 .
Yu. I. Blokhin, K. N. Kornilov, A. V. Akilin, I. A. Abramov, A. M. Bagautdinov & I. A. Lyubimov. (2017) Advances in the studies of bisphosphorylated dihydric phenols. Russian Chemical Bulletin 65:4, pages 910-922.
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Dmitry A. Stetsenko. 2008. The Power of Functional Resins in Organic Synthesis. The Power of Functional Resins in Organic Synthesis 529 583 .
Mark A. Russell, Andrew P. Laws, John H. Atherton & Michael I. Page. (2008) The mechanism of the phosphoramidite synthesis of polynucleotides. Organic & Biomolecular Chemistry 6:18, pages 3270.
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Erkki Nurminen & Harri Lönnberg. (2003) Mechanisms of the substitution reactions of phosphoramidites and their congeners. Journal of Physical Organic Chemistry 17:1, pages 1-17.
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Edward E. Nifantiev, Mikhail K. Grachev & Sergei Yu. Burmistrov. (2000) Amides of Trivalent Phosphorus Acids as Phosphorylating Reagents for Proton-Donating Nucleophiles. Chemical Reviews 100:10, pages 3755-3800.
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Radhakrishnan P. Iyer & Serge L. Beaucage. 1999. Comprehensive Natural Products Chemistry. Comprehensive Natural Products Chemistry 105 152 .
Gerald Schmidt. 1997. Automatische genetische Analytik. Automatische genetische Analytik 45 63 .
BERNARD L. HIRSCHBEIN & KAREN L. FEARON. (1997) 31 P NMR Spectroscopy in Oligonucleotide Research and Development . Antisense and Nucleic Acid Drug Development 7:1, pages 55-61.
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Nitin Puri, Sabine Hünsch, Christian Sund, Ivar Ugi & Jyoti Chattopadhyaya. (1995) The synthesis and reactivity of new 2-(N,N-diisopropylamino)-3-methylsulfonyl-1,3,2-benzoxazaphospholes. The utility of the 5-chloro analogue in the one-pot synthesis of oligothiophosphates: [ApsppA, ApspppA, ppp5′A2′ps5′A, m7GpsppA, Apspppp, Apspp]. Tetrahedron 51:10, pages 2991-3014.
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Edward E Nifantiev & M K Grachev. (1994) Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines. Russian Chemical Reviews 63:7, pages 575-609.
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Serge L. Beaucage & Radhakrishman P. Iyer. (1992) Advances in the Synthesis of Oligonucleotides by the Phosphoramidite Approach. Tetrahedron 48:12, pages 2223-2311.
Crossref
M. V. Twigg. 1985. Mechanisms of Inorganic and Organometallic Reactions. Mechanisms of Inorganic and Organometallic Reactions 93 140 .

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