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Polymer-Plastics Technology and Engineering Volume 49, 2010 - Issue 7
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Original Articles

Development of Novel Bio-Based Soybean Oil Epoxy Resins as a Function of Hardener Stoichiometry

A. P. Gupta Department of Applied Chemistry and Polymer Technology, Delhi College of Engineering (University of Delhi), Bawana Road, Delhi, IndiaCorrespondence[email protected] ; [email protected]
,
Sharif Ahmad Materials Research Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi, India
&
Anshu Dev Department of Applied Chemistry and Polymer Technology, Delhi College of Engineering (University of Delhi), Bawana Road, Delhi, India
Pages 657-661 | Published online: 15 Jun 2010

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Rohani Mustapha, Abdul Razak Rahmat, Rohah Abdul Majid & Siti Noor Hidayah Mustapha. (2019) Vegetable oil-based epoxy resins and their composites with bio-based hardener: a short review. Polymer-Plastics Technology and Materials 58:12, pages 1311-1326.
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H. Salam, Y. Dong, I. J. Davies & A. Pramanik. (2018) Identification of preferred combination of factors in manufacturing bioepoxy/clay nanocomposites. Advanced Composite Materials 27:5, pages 511-530.
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Shrikant K. Bobade, Nagarjuna Reddy Paluvai, Smita Mohanty & S. K. Nayak. (2016) Bio-Based Thermosetting Resins for Future Generation: A Review. Polymer-Plastics Technology and Engineering 55:17, pages 1863-1896.
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Articles from other publishers (52)

Akash Pratim Bora, Pragati Agrawal & Sumit H. Dhawane. 2024. Vegetable Oil-Based Composites. Vegetable Oil-Based Composites 107 131 .
Chuang Wang, Haolin Zhang, Yuyao Wang, Chi Chen, Zaiqin Zhang & Yang Wang. (2023) Effect of Hardener Stoichiometry on the Dielectric Properties of Epoxy Resin/Liquid Nitrile Rubber Composite Materials. IEEE Transactions on Dielectrics and Electrical Insulation 30:3, pages 1178-1187.
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Xia Liu, Weifeng Fan & Xiaoniu Yang. (2022) Bio‐based epoxy‐anhydride thermosets from multi‐armed cardanol‐derived epoxy oligomers. Polymers for Advanced Technologies 33:8, pages 2571-2580.
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Harikumar Sreehari, Anandhavally Sabarisadhanam Sethulekshmi & Appukuttan Saritha. (2022) Bio Epoxy Coatings: An Emergent Green Anticorrosive Coating for the Future. Macromolecular Materials and Engineering 307:8.
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Fanica Mustata, Dan Rosu, Cristian-Dragos Varganici, Liliana Rosu, Irina Rosca & Nita Tudorachi. (2022) Assessing the thermal and fungal behavior of eco-friendly epoxy thermosets derived from vegetable oils for wood protective coatings. Progress in Organic Coatings 163, pages 106612.
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Anish Khan, Sanjay M. Rangappa, Suchart Siengchin & Abdullah M. AsiriDipen Kumar Rajak, Durgesh D. Pagar & Catalin I. Pruncu. 2021. Biobased Composites. Biobased Composites 87 106 .
Ahmad Y. Al‐Maharma, Yousef Heider, Bernd Markert & Marcus Stoffel. 2021. Bio‐Based Epoxy Polymers, Blends and Composites. Bio‐Based Epoxy Polymers, Blends and Composites 215 248 .
Sudheer Kumar & Sukhila Krishnan. 2021. Bio‐Based Epoxy Polymers, Blends and Composites. Bio‐Based Epoxy Polymers, Blends and Composites 117 141 .
Haipan Salam & Yu DongHaipan Salam & Yu Dong. 2021. Bioepoxy/Clay Nanocomposites. Bioepoxy/Clay Nanocomposites 113 144 .
Haipan Salam & Yu DongHaipan Salam & Yu Dong. 2021. Bioepoxy/Clay Nanocomposites. Bioepoxy/Clay Nanocomposites 1 69 .
Daniel Angel Bellido-Aguilar, Shunli Zheng, Yinjuan Huang, Ye Sun, Xianting Zeng, Qichun Zhang & Zhong Chen. (2020) Hydrophobization of fully bio-based epoxy polymers using water as solvent: Effect of additives. European Polymer Journal 140, pages 110043.
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Elena Mazzon, Pascal Guigues & Jean-Pierre Habas. (2020) Biobased structural epoxy foams derived from plant-oil: Formulation, manufacturing and characterization. Industrial Crops and Products 144, pages 111994.
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Nicolas Auclair, Alireza Kaboorani, Bernard Riedl & Véronic Landry. (2019) Effects of surface modification of cellulose nanocrystals (CNCs) on curing behavior, optical, and thermal properties of soybean oil bio-nanocomposite. Journal of Coatings Technology and Research 17:1, pages 57-67.
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Haipan Salam & Yu Dong. (2019) Theoretical Modelling Analysis on Tensile Properties of Bioepoxy/Clay Nanocomposites Using Epoxidised Soybean Oils. Journal of Nanomaterials 2019, pages 1-20.
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H. Salam & Y. Dong. (2019) Property evaluation and material characterization of soybean oil modified bioepoxy/clay nanocomposites for environmental sustainability. Materials Today Sustainability 5, pages 100012.
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Rangana Wijayapala, Satish Mishra, Bill Elmore, Charles Freeman & Santanu Kundu. (2019) Synthesis and characterization of crosslinked polymers from cottonseed oil. Journal of Applied Polymer Science 136:24.
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Qiuyu Tang, Yahua Chen, Huizhi Gao, Qian Li, Zhenhao Xi, Ling Zhao, Chong Peng & Lanpeng Li. 2019. Soybean - Biomass, Yield and Productivity. Soybean - Biomass, Yield and Productivity.
H. Salam, Y. Dong, I. J. Davies & A. Pramanik. (2017) Optimization of material formulation and processing parameters in relation to mechanical properties of bioepoxy/clay nanocomposites using Taguchi design of experiments. Journal of Applied Polymer Science 135:5.
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F. N. Alhabill, R. Ayoob, T. Andritsch & A. S. Vaughan. (2017) Effect of resin/hardener stoichiometry on electrical behavior of epoxy networks. IEEE Transactions on Dielectrics and Electrical Insulation 24:6, pages 3739-3749.
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Célia F. Frias, Arménio C. Serra, A. Ramalho, Jorge F.J. Coelho & Ana C. Fonseca. (2017) Preparation of fully biobased epoxy resins from soybean oil based amine hardeners. Industrial Crops and Products 109, pages 434-444.
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Ghodsieh Mashouf Roudsari, Amar K. Mohanty & Manjusri Misra. (2017) Green Approaches To Engineer Tough Biobased Epoxies: A Review. ACS Sustainable Chemistry & Engineering 5:11, pages 9528-9541.
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Ghodsieh Mashouf Roudsari, Manjusri Misra & Amar K. Mohanty. (2016) A study of mechanical properties of biobased epoxy network: Effect of addition of epoxidized soybean oil and poly(furfuryl alcohol). Journal of Applied Polymer Science 134:1.
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Saeid Nikafshar, Omid Zabihi, Susan Hamidi, Yousef Moradi, Saeed Barzegar, Mojtaba Ahmadi & Minoo Naebe. (2017) A renewable bio-based epoxy resin with improved mechanical performance that can compete with DGEBA. RSC Advances 7:14, pages 8694-8701.
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Aditi Saikia & Niranjan Karak. (2017) Renewable resource based thermostable tough hyperbranched epoxy thermosets as sustainable materials. Polymer Degradation and Stability 135, pages 8-17.
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Kazuki Satoh, Takeshi Yokoyama, Toshiaki Shimasaki, Naozumi Teramoto & Mitsuhiro Shibata. (2016) Bio-based epoxy networks incorporating covalent and melamine cyanurate-type multiple hydrogen-bonding crosslinkages. Journal of Polymer Research 23:9.
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Naheed Saba, Mohammad Jawaid, Othman Y Alothman, MT Paridah & Azman Hassan. (2015) Recent advances in epoxy resin, natural fiber-reinforced epoxy composites and their applications. Journal of Reinforced Plastics and Composites 35:6, pages 447-470.
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Ren Liu, Xiaopeng Zhang, Shuai Gao, Xiaoya Liu, Zhen Wang & Jingling Yan. (2016) Bio-based epoxy-anhydride thermosets from six-armed linoleic acid-derived epoxy resin. RSC Advances 6:58, pages 52549-52555.
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Mitsuhiro Shibata, Toshiaki Shimasaki, Hiroyuki Satoh, Misaki Iwai & Makiyo Neda. (2015) Bio-based thermosetting resins composed of aliphatic polyol-derived polymaleimides and allyleugenol. Reactive and Functional Polymers 97, pages 69-76.
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Aparna Kadam, Manisha Pawar, Omprakash Yemul, Viresh Thamke & Kisan Kodam. (2015) Biodegradable biobased epoxy resin from karanja oil. Polymer 72, pages 82-92.
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V. Nguyen, A. Vaughan, P. Lewin & A. Krivda. (2015) The effect of resin stoichiometry and nanoparticle addition on epoxy/silica nanodielectrics. IEEE Transactions on Dielectrics and Electrical Insulation 22:2, pages 895-905.
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H. Salam, Y. Dong & I. Davies. 2015. Fillers and Reinforcements for Advanced Nanocomposites. Fillers and Reinforcements for Advanced Nanocomposites 101 132 .
Rongpeng Wang & Thomas Schuman. 2014. Green Materials from Plant Oils. Green Materials from Plant Oils 202 241 .
Fei Liu & Jin Zhu. 2014. Green Materials from Plant Oils. Green Materials from Plant Oils 93 126 .
S.G. Tan, Z. Ahmad & W.S. Chow. (2014) Reinforcing ability and co-catalytic effects of organo-montmorillonite clay on the epoxidized soybean oil bio-thermoset. Applied Clay Science 90, pages 11-17.
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Ramzi Belhassen, Fabiola Vilaseca, Pere Mutjé & Sami Boufi. (2014) Thermoplasticized starch modified by reactive blending with epoxidized soybean oil. Industrial Crops and Products 53, pages 261-267.
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Chun Hua Zhao, Shun Jiang Wan, Lu Wang, Xiang Dong Liu & Takeshi Endo. (2013) Carbonyldiimidazole‐accelerated efficient cure of epoxidized soybean oil with dicyandiamide. Journal of Polymer Science Part A: Polymer Chemistry 52:3, pages 375-382.
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Seah Guan Tan, Zulkifli Ahmad & Wen Shyang Chow. (2013) Interpenetrating polymer network structured thermosets prepared from epoxidized soybean oil/diglycidyl ether of bisphenol A. Polymer International 63:2, pages 273-279.
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Rémi Auvergne, Sylvain Caillol, Ghislain David, Bernard Boutevin & Jean-Pierre Pascault. (2013) Biobased Thermosetting Epoxy: Present and Future. Chemical Reviews 114:2, pages 1082-1115.
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Mitsuhiro Shibata, Naozumi Teramoto, Satoru Yoshihara & Yusuke Itakura. (2012) Preparation and properties of biocomposites composed of sorbitol‐based epoxy resin, tung oil‐pyrogallol resin, and wood flour. Journal of Applied Polymer Science 129:1, pages 282-288.
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Mitsuhiro Shibata, Satoru Yoshihara, Mio Yashiro & Yukito Ohno. (2012) Thermal and mechanical properties of sorbitol‐based epoxy resin cured with quercetin and the biocomposites with wood flour. Journal of Applied Polymer Science 128:5, pages 2753-2758.
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Guozhen Yang, Brian J. Rohde & Megan L. Robertson. (2013) Hydrolytic degradation and thermal properties of epoxy resins derived from soybean oil. Green Materials 1:2, pages 125-134.
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S.G. Tan, Z. Ahmad & W.S. Chow. (2013) Relationships of cure kinetics and processing for epoxidized soybean oil bio-thermoset. Industrial Crops and Products 43, pages 378-385.
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J. M. España, L. Sánchez‐Nacher, T. Boronat, V. Fombuena & R. Balart. (2012) Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA). Journal of the American Oil Chemists' Society 89:11, pages 2067-2075.
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V. Nguyen, A. S. Vaughan, P. L. Lewin & A. Krivda. (2012) On the stoichiometry with space charge and breakdown behaviour of an epoxy based system with nano-sized and micro-sized fillers. On the stoichiometry with space charge and breakdown behaviour of an epoxy based system with nano-sized and micro-sized fillers.
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S. G. Tan & W. S. Chow. (2012) Effects of 2-ethyl-4-methylimidazole and tetraethylammonium bromide on the fracture properties of epoxidized soybean oil based thermoset. Iranian Polymer Journal 21:6, pages 353-363.
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T. Boronat, J.M. España, I. Rico, O. Fenollar & R. Balart. (2012) Processing and Characterization of New Organic Matrix for Composite Materials Based on Acrylated Epoxidized Vegetable Oils. Advanced Materials Research 498, pages 201-206.
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Chahinez Aouf, Jérôme Lecomte, Pierre Villeneuve, Eric Dubreucq & Hélène Fulcrand. (2012) Chemo-enzymatic functionalization of gallic and vanillic acids: synthesis of bio-based epoxy resins prepolymers. Green Chemistry 14:8, pages 2328.
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Judith D. Espinoza‐Perez, Brent A. Nerenz, Darrin M. Haagenson, Zhigang Chen, Chad A. Ulven & Dennis P. Wiesenborn. (2011) Comparison of curing agents for epoxidized vegetable oils applied to composites. Polymer Composites 32:11, pages 1806-1816.
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V. Nguyen, A. S. Vaughan, P. L. Lewin & A. Krivda. (2011) Stoichiometry and effects of nano-sized and micro-sized fillers on an epoxy based system. Stoichiometry and effects of nano-sized and micro-sized fillers on an epoxy based system.
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Xiao Pan, Partha Sengupta & Dean C. Webster. (2011) High Biobased Content Epoxy–Anhydride Thermosets from Epoxidized Sucrose Esters of Fatty Acids. Biomacromolecules 12:6, pages 2416-2428.
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