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Solvent Extraction and Ion Exchange Volume 17, 1999 - Issue 1
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Original Articles

AGGREGATION OF COMPLEXES FORMED IN THE EXTRACTION OF SELECTED METAL CATIONS BY P,P'-DI(2-ETHYLHEXYL) METHANEDIPHOSPHONIC ACIDFootnote*

R. Chiarizia Chemistry Division, Argonne National Laboratory, Argonne, Il, 60439, USA
,
V. Urban IPNS Division, Argonne National Laboratory, Argonne, Il, 60439, USA
,
P. Thiyagarajan IPNS Division, Argonne National Laboratory, Argonne, Il, 60439, USA
&
A.W. Herlinger Department of Chemistry, Loyola University Chicago, Chicago, Il, 60626, USA
Pages 113-132 | Received 01 May 1998, Published online: 10 May 2007

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P. Jost, N. Galand, R. Schurhammer & G. Wipff. (2007) Supramolecular Interactions of Cryptates in Concentrated Solutions: The Effect of Solvent and Counterions Investigated by MD Simulations. Solvent Extraction and Ion Exchange 25:2, pages 257-271.
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R. Chiarizia, M. P. Jensen, M. Borkowski, P. Thiyagarajan & K. C. Littrell. (2004) Interpretation of Third Phase Formation in the Th(IV)–HNO3, TBP–n‐Octane System with Baxter's “Sticky Spheres” Model. Solvent Extraction and Ion Exchange 22:3, pages 325-351.
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R. Chiarizia, M. P. Jensen, M. Borkowski, J. R. Ferraro, P. Thiyagarajan & K. C. Littrell. (2003) Sans Study Of Third Phase Formation In The U(vi)-hno3/tbp-n-dodecane System. Separation Science and Technology 38:12-13, pages 3313-3331.
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M. Borkowski, R. Chiarizia, M. P. Jensen, J. R. Ferraro, P. Thiyagarajan & K. C. Littrell. (2003) Sans Study Of Third Phase Formation In The Th(iv)-hno3/tbp-n-octane System. Separation Science and Technology 38:12-13, pages 3333-3351.
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A. W. Herlinger, D. R. McAlister, R. Chiarizia & M. L. Dietz. (2003) Aggregation, Metal Ion Extraction, and Solubility Properties of Silyl-Substituted Alkylenediphosphonic Acids. Separation Science and Technology 38:12-13, pages 2741-2762.
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E. O. Otu & R. Chiarizia. (2003) Temperature Effect On The Extraction Of Am(iii), U(vi), And Sr(ii) By Dialkyl-substituted Alkylenediphosphonic Acids. Separation Science and Technology 38:12-13, pages 2619-2636.
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R. Chiarizia, M. P. Jensen, M. Borkowski, J. R. Ferraro, P. Thiyagarajan & K. C. Littrell. (2003) Third Phase Formation Revisited: The U(VI), HNO3–TBP, n‐Dodecane System. Solvent Extraction and Ion Exchange 21:1, pages 1-27.
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D. R. McAlister, R. Chiarizia, M. L. Dietz, A. W. Herlinger & P. R. Zalupski. (2002) EXTRACTION OF ALKALINE EARTH AND ACTINIDE CATIONS BY MIXTURES OF DI(2-ETHYLHEXYL) ALKYLENEDIPHOSPHONIC ACIDS AND NEUTRAL SYNERGISTS. Solvent Extraction and Ion Exchange 20:4-5, pages 447-469.
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D. R. McAlister, M. L. Dietz, R. Chiarizia, P. R. Zalupski & A. W. Herlinger. (2002) Metal extraction by silyl-substituted diphosphonic acids. II. Effect of alkylene bridge length on aggregation and metal ion extraction behavior. Separation Science and Technology 37:10, pages 2289-2315.
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Shoichi Tachimori, Yuji Sasaki & Shin-ichi Suzuki. (2002) MODIFICATION OF TODGA- -DODECANE SOLVENT WITH A MONOAMIDE FOR HIGH LOADING OF LANTHANIDES(III) AND ACTINIDES(III). Solvent Extraction and Ion Exchange 20:6, pages 687-699.
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A. N. Turanov, V. K. Karandashev & A. N. Yarkevich. (2002) METAL EXTRACTION FROM NITRIC ACID SOLUTIONS BY (DIPHENYL-PHOSPHINYLMETHYL) PHENYLPHOSPHINIC ACID. Solvent Extraction and Ion Exchange 20:6, pages 633-663.
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E. O. Otu, R. Chiarizia, P. G. Rickert & K. L. Nash. (2002) THE EXTRACTION OF AMERICIUM AND STRONTIUM BY P,P′-DI(2-ETHYLHEXYL) BENZENE-1,2-DIPHOSPHONIC ACID*. Solvent Extraction and Ion Exchange 20:6, pages 607-632.
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D. R. McAlister, M. L. Dietz, R. Chiarizia & A. W. Herlinger. (2001) METAL ION EXTRACTION BY SILYL-SUBSTITUTED DIPHOSPHONIC ACIDS. I. P,P′-DI-[3-(TRIMETHYLSILYL)-1-PROPYLENE] METHYLENE- AND ETHYLENEDIPHOSPHONIC ACIDS. Separation Science and Technology 36:16, pages 3541-3562.
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E. O. Otu & R. Chiarizia. (2001) THERMODYNAMICS OF THE EXTRACTION OF METAL IONS BY DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS. II. THE U(VI) AND Sr(II) CASE. Solvent Extraction and Ion Exchange 19:6, pages 1017-1036.
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E. O. Otu & R. Chiarizia. (2001) TEMPERATURE EFFECTS IN THE EXTRACTION OF METAL IONS BY DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS. I. THE Am(III) CASE. Solvent Extraction and Ion Exchange 19:5, pages 885-904.
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M. P. Jensen, R. Chiarizia & V. Urban. (2001) INVESTIGATION OF THE AGGREGATION OF THE NEODYMIUM COMPLEXES OF DIALKYLPHOSPHORIC, -OXOTHIOPHOSPHINIC, AND -DITHIOPHOSPHINIC ACIDS IN TOLUENE. Solvent Extraction and Ion Exchange 19:5, pages 865-884.
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R. Chiarizia, R. E. Barrans$suffix/text()$suffix/text(), J. R. Ferraro, A. W. Herlinger & D. R. McAlister. (2001) AGGREGATION OF DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS AND ITS EFFECT ON METAL ION EXTRACTION. Separation Science and Technology 36:5-6, pages 687-708.
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R. Chiarizia, D. R. McAlister & A. W. Herlinger. (2001) SOLVENT EXTRACTION BY DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS IN A DEPOLYMERIZING DILUENT. II. Fe(III) AND ACTINIDE IONS. Solvent Extraction and Ion Exchange 19:3, pages 415-440.
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R. Chiarizia, D. R. McAlister, A. W. Herlinger & A. H. Bond. (2001) SOLVENT EXTRACTION BY DIALKYL-SUBSTITUTED DIPHOSPHONIC ACIDS IN A DEPOLYMERIZING DILUENT. I. ALKALINE EARTH CATIONS. Solvent Extraction and Ion Exchange 19:2, pages 261-276.
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L. Troxler, M. Baaden, V. Böhmer & G. Wipff. (2000) Complexation of M3+ Lanthanide Cations by Calix[4]arene-CMPO Ligands: A Molecular Dynamics Study in Methanol Solution and at a Water/Chloroform Interface. Supramolecular Chemistry 12:1, pages 27-51.
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MARTYN S. RAY. (2000) Equilibrium-Staged Separations: A Bibliography Update (1999). Separation Science and Technology 35:16, pages 2765-2781.
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Justine Basque, Janyce Lavoie, Nicolas Reynier & Dominic Larivière. (2023) Quantitative separation of thorium from rare earth elements and uranium in a rare earth element sulfuric acid leachate using cloud point extraction. Microchemical Journal 190, pages 108724.
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Justine Basque, Janyce Lavoie, Nicolas Reynier & Dominic Lariviere. (2023) Quantitative Separation of Thorium from Rare Earth Elements and Uranium in a Rare Earth Element Sulfuric Acid Leachate Using Cloud Point Extraction. SSRN Electronic Journal.
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Cyril Lavaud, Frédéric Goettmann, Agnès Grandjean & Jérémy Causse. (2015) Simultaneous lanthanides and surfactants micelles removal from aqueous outflows by complexation and sol–gel chemistry. Separation and Purification Technology 145, pages 17-23.
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G. I. Timofeeva, A. G. Matveeva, A. M. Safiulina, D. V. Ivanets, E. M. Kudryavtsev, V. E. Baulin & A. Yu. Tsivadze. (2015) Phosphoryl-containing acidic podands as extractants for recovery of f-elements. Russian Chemical Bulletin 64:1, pages 224-227.
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A. M. Safiulina, A. G. Matveeva, D. V. Ivanets, E. M. Kudryavtsev, M. S. Grigor´ev, V. E. Baulin & A. Yu. Tsivadze. (2015) Phosphoryl-containing acidic podands as extractants for recovery of f-elements. Russian Chemical Bulletin 64:1, pages 161-168.
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Travis S. Grimes, Mark P. Jensen, Lisa Debeer-Schmidt, Ken Littrell & Kenneth L. Nash. (2012) Small-Angle Neutron Scattering Study of Organic-Phase Aggregation in the TALSPEAK Process. The Journal of Physical Chemistry B 116:46, pages 13722-13730.
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C. Hill. 2011. Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment. Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment 311 362 .
Bernard Coupez & Georges Wipff. (2004) The synergistic effect of cobalt-dicarbollide anions on the extraction of M3+ lanthanide cations by Calix[4]arenes: a molecular dynamics study at the water–‘oil’ interface. Comptes Rendus Chimie 7:12, pages 1153-1164.
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Georges Wipff. 2002. Calixarenes 2001. Calixarenes 2001 312 333 .

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