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Solvent Extraction and Ion Exchange Volume 26, 2008 - Issue 4
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Original Articles

Sans Study of Reverse Micelles Formed upon the Extraction of Inorganic Acids by TBP in n‐OctaneFootnote

R. Chiarizia Chemistry Division, Argonne National Laboratory, Argonne, IL 60439Correspondence[email protected]
,
A. Briand Student from Ecole Nationale Supérieure de Chimie de Paris – ENSCP
,
M. P. Jensen Chemistry Division, Argonne National Laboratory, Argonne, IL 60439
&
P. Thiyagarajan IPNS Division, Argonne National Laboratory, Argonne, IL 60439
Pages 333-359 | Received 21 Jan 2008, Accepted 16 Mar 2008, Published online: 16 Jul 2008

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Subramee Sarkar, S. Rajeswari, A. Suresh & N. Sivaraman. (2022) Hydrodynamic Properties of Tris(2-methylbutyl) Phosphate and Tri-n-alkyl Phosphates in n-Dodecane – A Comparative Investigation between Unirradiated and Gamma Irradiated Solvent Systems. Solvent Extraction and Ion Exchange 40:5, pages 455-476.
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Subramee Sarkar, A. Suresh, N. Sivaraman & Vinod K Aswal. (2022) Studies on the aggregation behavior of mineral acid and Zr(IV) loaded Tris(2-methylbutyl) phosphate and tri-n-alkyl phosphate systems using small angle neutron scattering. Separation Science and Technology 57:6, pages 968-978.
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Ch. Venkateswara Rao, Alok Rout & K. A. Venkatesan. (2021) Aggregation behavior of ionic liquid in molecular liquid medium: a dynamic light scattering study. Separation Science and Technology 56:4, pages 757-765.
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K. Rama Swami, K. A. Venkatesan & M. P. Antony. (2019) Role of Phase Modifiers in Controlling the Third-phase Formation During the Solvent Extraction of Trivalent Actinides. Solvent Extraction and Ion Exchange 37:7, pages 500-517.
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J. Durain, D. Bourgeois, M. Bertrand & D. Meyer. (2019) Comprehensive Studies on Third Phase Formation: Application to U(VI)/Th(IV) Mixtures Extracted by TBP in N-dodecane. Solvent Extraction and Ion Exchange 37:5, pages 328-346.
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Andy Jackson & Mikael Nilsson. (2019) Synergism and Aggregation in Multi-Extractant Solvent Extraction Systems. Solvent Extraction and Ion Exchange 37:3-4, pages 269-283.
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Kirstian J. MacRuary, Ross J. Gordon, Richard A. Grant, Stephen Woollam, Ross J. Ellis, Peter A. Tasker, Jason B. Love & Carole A. Morrison. (2017) On the Extraction of HCl and H2PtCl6 by Tributyl Phosphate: A Mode of Action Study. Solvent Extraction and Ion Exchange 35:7, pages 531-548.
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P. Ivanov, J. Mu, L. Leay, S.-Y. Chang, C. A. Sharrad, A. J. Masters & S. L. M. Schroeder. (2017) Organic and Third Phase in HNO3/TBP/n-Dodecane System: No Reverse Micelles. Solvent Extraction and Ion Exchange 35:4, pages 251-265.
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R. Chiarizia, D. Stepinski & M. R. Antonio. (2010) SANS Study of HCl Extraction by Selected Neutral Organophosphorus Compounds in n-Octane. Separation Science and Technology 45:12-13, pages 1668-1678.
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MarkR. Antonio, Renato Chiarizia & Fanny Jaffrennou . (2010) Third-Phase Formation in the Extraction of Phosphotungstic Acid by TBP in n-Octane. Separation Science and Technology 45:12-13, pages 1689-1698.
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Daniel Massey, Christopher D. Williams, Junju Mu, Andrew J. Masters, Ryuhei Motokawa, Noboru Aoyagi, Yuki Ueda & Mark R. Antonio. (2023) Hierarchical Aggregation in a Complex Fluid─The Role of Isomeric Interconversion. The Journal of Physical Chemistry B 127:9, pages 2052-2065.
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Daniel MasseyAndrew Masters, Jonathan Macdonald-TaylorDavid WoodheadRobin Taylor. (2022) Molecular Dynamics Study of the Aggregation Behavior of N , N , N ′, N ′-Tetraoctyl Diglycolamide . The Journal of Physical Chemistry B 126:33, pages 6290-6300.
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Michael J. Servis, Srikanth Nayak & Soenke Seifert. (2021) The pervasive impact of critical fluctuations in liquid–liquid extraction organic phases. The Journal of Chemical Physics 155:24.
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Subramee Sarkar, Suresh Ammath, Subashree Kirubananthan & Asokan Sudha Suneesh. (2021) Investigation of the Phase Splitting Behaviour of U(VI) and Th(IV) loaded Trialkyl Phosphate Solvents in the Absence of Aqueous Phase. ChemistrySelect 6:48, pages 13725-13735.
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Diego Moreno Martinez, Eléonor Acher, Marin Vatin, Sandrine Dourdain, Dominique Guillaumont & Philippe Guilbaud. (2021) Aggregation of Bifunctional Extractants Used for Uranium(VI) Separation. The Journal of Physical Chemistry B 125:38, pages 10759-10771.
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Subramee Sarkar, A. Suresh & N. Sivaraman. (2021) Third phase formation behaviour of tris(2-methylbutyl) phosphate and tri- n -alkyl phosphates in the extraction of mineral acids and tetravalent metal ions . Radiochimica Acta 109:8, pages 625-634.
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K. Rama Swami, K.A. Venkatesan, B. Robert Selvan, Dattatraya Vasant Hase & R.V. Jayaram. (2020) Investigations on the unusual aggregation behaviour of tetra(2-ethyhexyl)diglycolamide in n-dodecane medium upon gamma irradiation. Journal of Molecular Liquids 319, pages 114177.
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K. Rama Swami & K. A. Venkatesan. (2019) Effect of pKa of organophosphorus acidic extractants on the aggregation behavior of diglycolamide in n-dodecane. Journal of Radioanalytical and Nuclear Chemistry 322:2, pages 1055-1064.
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K. Rama swami, T. Prathibha & K.A. Venkatesan. (2019) Aggregation and organic phase splitting behavior of a synergic extractant system probed by dynamic light scattering spectroscopy. Journal of Molecular Liquids 291, pages 111320.
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Ryuhei Motokawa, Tohru Kobayashi, Hitoshi Endo, Junju Mu, Christopher D. Williams, Andrew J. Masters, Mark R. Antonio, William T. Heller & Michihiro Nagao. (2018) A Telescoping View of Solute Architectures in a Complex Fluid System. ACS Central Science 5:1, pages 85-96.
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K. Rama Swami, K. A. Venkatesan & M. P. Antony. (2018) Aggregation Behavior of Alkyldiglycolamides in n -Dodecane Medium during the Extraction of Nd(III) and Nitric Acid . Industrial & Engineering Chemistry Research 57:40, pages 13490-13497.
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Junju Mu, Ryuhei Motokawa, Kazuhiro Akutsu, Shotaro Nishitsuji & Andrew J. Masters. (2018) A Novel Microemulsion Phase Transition: Toward the Elucidation of Third-Phase Formation in Spent Nuclear Fuel Reprocessing. The Journal of Physical Chemistry B 122:4, pages 1439-1452.
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K. Rama Swami, R. Kumaresan, K. A. Venkatesan & M. P. Antony. (2018) Minimizing the aggregation of diglycolamide reverse micelles in the n -dodecane phase with bis-(2-ethylhexyl)phosphoric acid “reactive” phase modifier . New Journal of Chemistry 42:11, pages 8891-8899.
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Phillipe Guilbaud, Laurence Berthon, Wilfried Louisfrema, Olivier Diat & Nicole Zorz. (2017) Determination of the Structures of Uranyl-Tri- n -butyl-Phosphate Aggregates by Coupling Experimental Results with Molecular Dynamic Simulations . Chemistry - A European Journal 23:65, pages 16660-16670.
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Anna G. Baldwin, Michael J. Servis, Yuan Yang, Nicholas J. Bridges, David T. Wu & Jenifer C. Shafer. (2017) The structure of tributyl phosphate solutions: Nitric acid, uranium (VI), and zirconium (IV). Journal of Molecular Liquids 246, pages 225-235.
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Michael J. Servis, David T. Wu & Jenifer C. Braley. (2017) Network analysis and percolation transition in hydrogen bonded clusters: nitric acid and water extracted by tributyl phosphate. Physical Chemistry Chemical Physics 19:18, pages 11326-11339.
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M. Campos Assuncao, G. Cote, M. Andre, H. Halleux & A. Chagnes. (2017) Phosphoric acid recovery from concentrated aqueous feeds by a mixture of di-isopropyl ether (DiPE) and tri-n-butylphosphate (TBP): extraction data and modelling. RSC Advances 7:12, pages 6922-6930.
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Anna G. Baldwin, Yuan Yang, Nicholas J. Bridges & Jenifer C. Braley. (2016) Tributyl Phosphate Aggregation in the Presence of Metals: An Assessment Using Diffusion NMR Spectroscopy. The Journal of Physical Chemistry B 120:47, pages 12184-12192.
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Shengting Cui, Valmor F. de Almeida & Bamin Khomami. (2014) Molecular Dynamics Simulations of Tri- n -butyl-phosphate/ n -Dodecane Mixture: Thermophysical Properties and Molecular Structure . The Journal of Physical Chemistry B 118:36, pages 10750-10760.
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Ross J. Ellis. (2013) Critical Exponents for Solvent Extraction Resolved Using SAXS. The Journal of Physical Chemistry B 118:1, pages 315-322.
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Rachel Schurhammer & Georges Wipff. (2011) Liquid−Liquid Extraction of Pertechnetic Acid (Tc VII ) by Tri- n -butyl Phosphate: Where Is the Proton? A Molecular Dynamics Investigation . The Journal of Physical Chemistry B 115:10, pages 2338-2348.
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