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Original Articles

Synergistic Solvent Extraction of Nickel and Cobalt: A Review of Recent Developments

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Pages 719-754 | Published online: 03 Oct 2011

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (9)

Yuqing Luo, Huiping Hu, Yongxi Wang, Fang Hu, Shan Zhu, Shuaifei Zhang, Ying Zhang, Shengkang Li & Junya Wang. (2019) Phase separation in solvent extraction of copper or nickel from acidic solution using a sulfonic acid (HDNNS) and a carboxylate ester (4PC). Journal of Dispersion Science and Technology 40:6, pages 819-827.
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Pratima Meshram, Abhilash & Banshi Dhar Pandey. (2019) Advanced Review on Extraction of Nickel from Primary and Secondary Sources. Mineral Processing and Extractive Metallurgy Review 40:3, pages 157-193.
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Shan Zhu, Huiping Hu, Jiugang Hu, Jiyuan Li, Fang Hu & Yongxi Wang. (2018) Structural insights into the extraction mechanism of cobalt(II) with dinonylnaphthalene sulfonic acid and 2-ethylhexyl 4-pyridinecarboxylate ester. Journal of Coordination Chemistry 71:15, pages 2441-2456.
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James W. Roebuck, Philip J. Bailey, Euan D. Doidge, Adam J. Fischmann, Mary R. Healy, Gary S. Nichol, Niall O’Toole, Max Pelser, Thomas Sassi, Kathryn C. Sole & Peter A. Tasker. (2018) Strong and Selective Ni(II) Extractants Based on Synergistic Mixtures of Sulfonic Acids and Bidentate N-Heterocycles. Solvent Extraction and Ion Exchange 36:5, pages 437-458.
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Qi Sun, Wei Wang, Limei Yang, Songtao Huang, Zheng Xu, Zhongguang Ji, Yan Li & Yihanna Hu. (2018) Separation and recovery of heavy metals from concentrated smelting wastewater by synergistic solvent extraction using a mixture of 2-hydroxy-5-nonylacetophenone oxime and bis(2,4,4-trimethylpentyl) -phosphinic acid. Solvent Extraction and Ion Exchange 36:2, pages 175-190.
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Shan Zhu, Huiping Hu, Jiugang Hu, Jiyuan Li, Fang Hu & Yongxi Wang. (2017) Insights into the extraction mechanism from the coordination chemistry of copper(II) with a synergistic mixture which mimics Versatic10 and 2-ethylhexyl 4-pyridinecarboxylate ester. Journal of Coordination Chemistry 70:19, pages 3325-3337.
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Hirokazu Narita, Kazuko Morisaku & Mikiya Tanaka. (2015) Synergistic Extraction of Rhodium(III) from Hydrochloric Acid Solution with Tri-n-octylamine and Sulfide-type Extractants. Solvent Extraction and Ion Exchange 33:5, pages 462-471.
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K. R. Barnard, N. J. Kelly, D. W. Shiers, T. M. McCoy, D. L. Jones & K. E. Mayhew. (2014) The Effect of LIX 63 Hydroxyoxime Degradation Products on Kinetics-Based Metal Extraction. Solvent Extraction and Ion Exchange 32:1, pages 95-110.
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M. Elizalde, A. Ocio, F. Andrade & B. Menoyo. (2013) Synergistic Extraction of Cobalt(II) by Mixtures of Bis(2-Ethylhexyl)Phosphoric Acid and LIX 860. Solvent Extraction and Ion Exchange 31:3, pages 269-280.
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Agnieszka Krzyżaniak, Boelo Schuur & André B. de Haan. (2013) Extractive recovery of aqueous diamines for bio-based plastics production. Journal of Chemical Technology & Biotechnology 88:10, pages 1937-1945.
Crossref
Adam Fischmann, Shane Wiggett, Troy Bednarski, Violina Cocalia & Cyril Bourget. 2013. Ni-Co 2013. Ni-Co 2013 391 403 .
Ranjit Kumar Biswas, Aneek Krishna Karmakar & Muhammad Saidur Rahman. (2013) Extraction Kinetics of Ni(II) in the Ni<sup>2+</sup>- SO<sub>4</sub><sup style="margin-left:-7px;">2-</sup>-Ac<sup>-</sup>(Na<sup>+</sup>, H<sup>+</sup>)-Cyanex 272 (H<sub>2</sub>A<sub>2</sub>)-Kerosene-3% (v/v) Octan-1-ol System Using Single Drop Technique. International Journal of Nonferrous Metallurgy 02:02, pages 80-88.
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Adam Fischmann, Shane Wiggett, Troy Bednarski, Violina Cocalia & Cyril Bourget. 2016. Ni-Co 2013. Ni-Co 2013 391 403 .
Sil Wellens, Ben Thijs & Koen Binnemans. (2012) An environmentally friendlier approach to hydrometallurgy: highly selective separation of cobalt from nickel by solvent extraction with undiluted phosphonium ionic liquids. Green Chemistry 14:6, pages 1657.
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