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Original Articles

Radiolytic Stability of N,N,N,N′-Tetraoctyl Diglycolamide (TODGA) in the Presence of Phase Modifiers Dissolved in n-Dodecane

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Pages 278-290 | Published online: 29 May 2012

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Read on this site (6)

Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Bruce J. Mincher, Gary S. Groenewold & Giuseppe Modolo. (2023) Gamma Radiolysis of Phenyl-Substituted TODGAs: Part I. Solvent Extraction and Ion Exchange 41:5, pages 564-581.
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Peter Zsabka, Karen Van Hecke, Lesley Adriaensen, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2018) Solvent Extraction of Am(III), Cm(III), and Ln(III) Ions from Simulated Highly Active Raffinate Solutions by TODGA Diluted in Aliquat-336 Nitrate Ionic Liquid. Solvent Extraction and Ion Exchange 36:6, pages 519-541.
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Daniel Whittaker, Andreas Geist, Giuseppe Modolo, Robin Taylor, Mark Sarsfield & Andreas Wilden. (2018) Applications of Diglycolamide Based Solvent Extraction Processes in Spent Nuclear Fuel Reprocessing, Part 1: TODGA. Solvent Extraction and Ion Exchange 36:3, pages 223-256.
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Kristyn M. Roscioli-Johnson, Christopher A. Zarzana, Gary S. Groenewold, Bruce J. Mincher, Andreas Wilden, Holger Schmidt, Giuseppe Modolo & Beatrix Santiago-Schübel. (2016) A Study of the γ-Radiolysis of N,N-Didodecyl-N′,N′-Dioctyldiglycolamide Using UHPLC-ESI-MS Analysis. Solvent Extraction and Ion Exchange 34:5, pages 439-453.
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Christopher A. Zarzana, Gary S. Groenewold, Bruce J. Mincher, Stephen P. Mezyk, Andreas Wilden, Holger Schmidt, Giuseppe Modolo, James F. Wishart & Andrew R. Cook. (2015) A Comparison of the γ-Radiolysis of TODGA and T(EH)DGA Using UHPLC-ESI-MS Analysis. Solvent Extraction and Ion Exchange 33:5, pages 431-447.
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Articles from other publishers (28)

T. Prathibha, Satendra Kumar, Swaroop Chandra, S. Maji & N. Ramanathan. (2023) The complexation of lanthanides by glycolamide extractants: Evidences from electronic spectroscopy and DFT calculations. Inorganica Chimica Acta 548, pages 121396.
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Brian T. Arko, David Dan, Sara Adelman, David B. Kimball, Stosh A. Kozimor, Marki M. Martinez, Tara Mastren, Daniel L. Huber, Veronika Mocko, Jung Rim, Jenifer C. Shafer, Benjamin W. Stein & E. Miller Wylie. (2023) Exploring how exposure to radiolysis and harsh chemical reagents impact americium-241 extraction chromatography. Materials Advances 4:1, pages 265-283.
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Biswajit Sadhu & Aurora E. Clark. (2022) Modulating Aggregation in Microemulsions: The Dispersion by Competitive Intermolecular Interaction Model. The Journal of Physical Chemistry Letters 13:47, pages 10981-10987.
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Andreas Wilden, Dimitri Schneider, Zaina Paparigas, Maximilian Henkes, Fabian Kreft, Andreas Geist, Eros Mossini, Elena Macerata, Mario Mariani, Maria Chiara Gullo, Alessandro Casnati & Giuseppe Modolo. (2022) Selective actinide(III) separation using 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl]pyridine (PyTri-Diol) in the innovative-SANEX process: laboratory scale counter current centrifugal contactor demonstration. Radiochimica Acta 110:6-9, pages 515-525.
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Ashleigh Kimberlin, Georges Saint-Louis, Dominique Guillaumont, Béatrice Camès, Philippe Guilbaud & Laurence Berthon. (2022) Effect of metal complexation on diglycolamide radiolysis: a comparison between ex situ gamma and in situ alpha irradiation . Physical Chemistry Chemical Physics 24:16, pages 9213-9228.
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Brian T. Arko, David Dan, Sara L. Adelman, Daniel L. Huber, David B. Kimball, Stosh A. Kozimor, Mila Nhu Lam, Veronika Mocko, Jenifer C. Shafer, Benjamin W. Stein & Sara L. Thiemann. (2021) Characterizing Extraction Chromatography for Large-Scale Americium-241 Processing. Industrial & Engineering Chemistry Research 60:39, pages 14282-14296.
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Ashleigh Kimberlin, Dominique Guillaumont, Sylvie Arpigny, Béatrice Camès, Philippe Guilbaud, Georges Saint-Louis, Hitos Galán & Laurence Berthon. (2021) An experimental and computational look at the radiolytic degradation of TODGA and the effect on metal complexation. New Journal of Chemistry 45:28, pages 12479-12493.
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Jeesmon Jose, T. Prathibha, N. S. Karthikeyan, K. A. Venkatesan, B. Robert Selvan, H. Seshadri, B. Venkatachalapathy & C. Ravichandran. (2021) Comparative evaluation of radiolytic stability of aqueous soluble BTP and BTBP derivatives under static gamma irradiation. Journal of Radioanalytical and Nuclear Chemistry 328:3, pages 1127-1136.
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K. Rama Swami, K.A. Venkatesan, Pooja Sahu & Sk. Musharaf Ali. (2020) The effect of alkyl chain length attached to the diglycolamide and n-paraffin on the aggregation behaviour of diglycolamide and MD simulation of aggregates. Journal of Molecular Structure 1221, pages 128795.
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K. Rama Swami, K.A. Venkatesan, B. Robert Selvan, Dattatraya Vasant Hase & R.V. Jayaram. (2020) Investigations on the unusual aggregation behaviour of tetra(2-ethyhexyl)diglycolamide in n-dodecane medium upon gamma irradiation. Journal of Molecular Liquids 319, pages 114177.
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N. Parvathy, K. Rama Swami, T. Prathibha & K.A. Venkatesan. (2020) Antagonism in the aggregation behaviour of N,N,N′,N′-tetraoctyldiglycolamide in n-dodecane upon adding N,N-dioctylhydroxyacetamide during trivalent metal extraction. Journal of Molecular Liquids 317, pages 113940.
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K. Rama Swami, K. A. Venkatesan & B. Robert Selvan. (2020) Studies on the aggregation behaviour of radiolytically degraded tetra(2-ethyhexyl)diglycolamide in n-dodecane medium during the extraction of trivalent metal ions. Journal of Radioanalytical and Nuclear Chemistry 325:1, pages 283-291.
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Jeesmon Jose, T. Prathibha, N.S. Karthikeyan, K.A. Venkatesan, B. Robert Selvan, H. Seshadri, B. Venkatachalapathy & C. Ravichandran. (2020) Evaluation of selected solvent systems for the single-cycle separation of Am(III) from Eu(III) using aqueous soluble sulphonated bis-triazinylpyridine. Journal of Molecular Liquids 306, pages 112893.
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K. Rama Swami & K.A. Venkatesan. (2019) Unraveling the role of phase modifiers in the extraction of Nd(III) from nitric acid medium in tetra-bis(2-ethylhexyl)diglycolamide in n-dodecane containing long chain aliphatic alcohols. Journal of Molecular Liquids 296, pages 111741.
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Tatsuya Kudo, Tatsuya Ito & Seong-Yun Kim. (2017) Adsorption Behavior of Sr(II) from High-level Liquid Waste using Crown Ether with Ionic Liquid Impregnated Silica Adsorbent. Energy Procedia 131, pages 189-194.
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T. Prathibha, B. Robert Selvan, K. A. Venkatesan, S. Rajeswari & M. P. Antony. (2017) Radiolytic stability of N,N-di-alkyl-2-hydroxyacetamides. Journal of Radioanalytical and Nuclear Chemistry 311:3, pages 1929-1935.
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Jinqing CHEN, Chao HUANG, Yanliang WANG, Bin HUANG & Xiaoqi SUN. (2016) Extraction behavior of bifunctional ionic liquid [N1888][SOPAA] and TBP for rare earth elements. Journal of Rare Earths 34:12, pages 1252-1259.
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Dean Peterman, Andreas Geist, Bruce Mincher, Giuseppe Modolo, Maria Hitos Galán, Lonnie Olson & Rocklan McDowell. (2016) Performance of an i -SANEX System Based on a Water-Soluble BTP under Continuous Irradiation in a γ-Radiolysis Test Loop . Industrial & Engineering Chemistry Research 55:39, pages 10427-10435.
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A. Sengupta, P.K. Mohapatra, A.B. Patil, R.M. Kadam & W. Verboom. (2016) Radiation stability of diglycolamide functionalized calix[4]arenes in ionic liquid: Solvent extraction, EPR and GC–MS studies. Separation and Purification Technology 162, pages 77-83.
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S. Rajeswari, M. P. Antony & P. R. Vasudeva Rao. (2015) Evaluation of hydrodynamic suitability of N,N-didodecyl N′,N′-di-octyl diglycolamide: a potential candidate for minor actinide partitioning. Journal of Radioanalytical and Nuclear Chemistry 306:2, pages 407-415.
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Hitos Galán, Christopher A. Zarzana, Andreas Wilden, Ana Núñez, Holger Schmidt, Richard J. M. Egberink, Andrea Leoncini, Joaquín Cobos, Willem Verboom, Giuseppe Modolo, Gary S. Groenewold & Bruce J. Mincher. (2015) Gamma-radiolytic stability of new methylated TODGA derivatives for minor actinide recycling. Dalton Transactions 44:41, pages 18049-18056.
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Jammu Ravi, B. Robert Selvan, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2014) Radiolytic stability of N,N-didodecyl-N’,N’-diethylhexyl diglycolamide. Journal of Radioanalytical and Nuclear Chemistry 300:3, pages 981-986.
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Jammu Ravi, B. Robert Selvan, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2013) Evaluation of radiation stability of N,N-didodecyl N′,N′-di-octyl diglycolamide: a promising reagent for actinide partitioning. Journal of Radioanalytical and Nuclear Chemistry 299:1, pages 879-885.
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Yu Gong, Han-Shi Hu, Linfeng Rao, Jun Li & John K. Gibson. (2013) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl–, Neptunyl–, and Plutonyl–Diglycolamide Complexes. The Journal of Physical Chemistry A 117:40, pages 10544-10550.
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Giuseppe Modolo, A. Wilden, H. Daniels, Andreas Geist, Daniel Magnusson & Rikard Malmbeck. (2013) Development and demonstration of a new SANEX Partitioning Process for selective actinide(III)/lanthanide(III) separation using a mixture of CyMe 4 BTBP and TODGA . Radiochimica Acta 101:3, pages 155-162.
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Prasanta K. Mohapatra, Arijit Sengupta, Mudassir Iqbal, Jurriaan Huskens & Willem Verboom. (2013) Highly Efficient Diglycolamide‐Based Task‐Specific Ionic Liquids: Synthesis, Unusual Extraction Behaviour, Irradiation, and Fluorescence Studies. Chemistry – A European Journal 19:9, pages 3230-3238.
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S. Panja, P.K. Mohapatra, S.C. Tripathi, P.M. Gandhi & P. Janardan. (2012) Supported liquid membrane transport studies on Am(III), Pu(IV), U(VI) and Sr(II) using irradiated TODGA. Journal of Hazardous Materials 237-238, pages 339-346.
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A. Sengupta, P. K. Mohapatra, M. Iqbal, W. Verboom, J. Huskens & S. V. Godbole. (2012) Extraction of Am(iii) using novel solvent systems containing a tripodal diglycolamide ligand in room temperature ionic liquids: a ‘green’ approach for radioactive waste processing. RSC Advances 2:19, pages 7492.
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