Advanced search
Publication Cover
Solvent Extraction and Ion Exchange Volume 31, 2013 - Issue 7
Submit an article Journal homepage
347
Views
29
CrossRef citations to date
0
Altmetric
Original Articles

The Radiation Chemistry of CMPO: Part 1. Gamma Radiolysis

Bruce J. Mincher Aqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USACorrespondence[email protected]
,
Stephen P. Mezyk Department of Chemistry and Biochemistry, California State University at Long Beach, Long Beach, CA, USA
,
Gracy Elias Chemistry and Radiation Measurements Department, Idaho National Laboratory, Idaho Falls, ID, USA
,
Gary S. Groenewold Chemistry and Radiation Measurements Department, Idaho National Laboratory, Idaho Falls, ID, USA
,
Catherine L. Riddle Aqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USA
&
Lonnie G. Olson Aqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USA
Pages 715-730 | Published online: 27 Sep 2013

Citations (29)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (7)

Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Bruce J. Mincher, Gary S. Groenewold & Giuseppe Modolo. (2023) Gamma Radiolysis of Phenyl-Substituted TODGAs: Part I. Solvent Extraction and Ion Exchange 41:5, pages 564-581.
Read now
Christian G. Bustillos, Randy O. Ngelale & Mikael Nilsson. (2023) Low and High LET Degradation Studies of Metal-Loaded Organic Phase Ligands in the ALSEP Process. Solvent Extraction and Ion Exchange 41:4, pages 449-482.
Read now
Andreas Wilden, Bruce J. Mincher, Stephen P. Mezyk, Liam Twight, Kristyn M. Rosciolo-Johnson, Christopher A. Zarzana, Mary E. Case, Michelle Hupert, Andrea Stärk & Giuseppe Modolo. (2018) Radiolytic and hydrolytic degradation of the hydrophilic diglycolamides. Solvent Extraction and Ion Exchange 36:4, pages 347-359.
Read now
Kristyn M. Roscioli-Johnson, Christopher A. Zarzana, Gary S. Groenewold, Bruce J. Mincher, Andreas Wilden, Holger Schmidt, Giuseppe Modolo & Beatrix Santiago-Schübel. (2016) A Study of the γ-Radiolysis of N,N-Didodecyl-N′,N′-Dioctyldiglycolamide Using UHPLC-ESI-MS Analysis. Solvent Extraction and Ion Exchange 34:5, pages 439-453.
Read now
Andreas Wilden, Giuseppe Modolo, Michelle Hupert, Beatrix Santiago-Schübel, Elin Löfström-Engdahl, Jenny Halleröd, Christian Ekberg, Bruce J. Mincher & Stephen P. Mezyk. (2016) Gamma-Radiolytic Stability of Solvents Containing C5-BPP (2,6-Bis(5-(2,2-dimethylpropyl)-1-pyrazol-3-yl)pyridine) for Actinide(III)/Lanthanide(III) Separation. Solvent Extraction and Ion Exchange 34:1, pages 1-12.
Read now
Christopher A. Zarzana, Gary S. Groenewold, Bruce J. Mincher, Stephen P. Mezyk, Andreas Wilden, Holger Schmidt, Giuseppe Modolo, James F. Wishart & Andrew R. Cook. (2015) A Comparison of the γ-Radiolysis of TODGA and T(EH)DGA Using UHPLC-ESI-MS Analysis. Solvent Extraction and Ion Exchange 33:5, pages 431-447.
Read now
Bruce J. Mincher & James F. Wishart. (2014) The Radiation Chemistry of Ionic Liquids: A Review. Solvent Extraction and Ion Exchange 32:6, pages 563-583.
Read now

Articles from other publishers (22)

Gregory P. Horne, Ryan P. Morco, Andrew R. Cook & Stephen P. Mezyk. (2023) Dioctyl ether radiolysis under used nuclear fuel reprocessing conditions: Foundational knowledge for the development of sacrificial ligand grafts. Radiation Physics and Chemistry 213, pages 111217.
Crossref
Rachel E. Umpleby, Jacy K. Conrad, Joseph R. Wilbanks, Kastli D. Schaller & Gregory P. Horne. (2023) Radiolytic evaluation of acetohydroxamic acid (AHA) under biphasic (HNO3:n-dodecane and TBP/DEHBA/DEHiBA) used nuclear fuel reprocessing conditions. Radiation Physics and Chemistry 207, pages 110799.
Crossref
Brian T. Arko, David Dan, Sara Adelman, David B. Kimball, Stosh A. Kozimor, Marki M. Martinez, Tara Mastren, Daniel L. Huber, Veronika Mocko, Jung Rim, Jenifer C. Shafer, Benjamin W. Stein & E. Miller Wylie. (2023) Exploring how exposure to radiolysis and harsh chemical reagents impact americium-241 extraction chromatography. Materials Advances 4:1, pages 265-283.
Crossref
Brian T. Arko, David Dan, Sara L. Adelman, Daniel L. Huber, David B. Kimball, Stosh A. Kozimor, Mila Nhu Lam, Veronika Mocko, Jenifer C. Shafer, Benjamin W. Stein & Sara L. Thiemann. (2021) Characterizing Extraction Chromatography for Large-Scale Americium-241 Processing. Industrial & Engineering Chemistry Research 60:39, pages 14282-14296.
Crossref
M. V. Evsiunina, P. I. Matveev, S. N. Kalmykov & V. G. Petrov. (2021) Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests. Moscow University Chemistry Bulletin 76:5, pages 287-315.
Crossref
Ying Wang, Yaoshuang Wan, Yimin Cai, Lihua Yuan, Wen Feng & Ning Liu. (2021) A review of the alpha radiolysis of extractants for actinide lanthanide separation in spent nuclear fuel reprocessing. Radiochimica Acta 109:8, pages 603-623.
Crossref
Gregory P. Horne, Travis S. Grimes, Peter R. Zalupski, David S. Meeker, Thomas E. Albrecht-Schönzart, Andrew R. Cook & Stephen P. Mezyk. (2021) Curium( iii ) radiation-induced reaction kinetics in aqueous media . Dalton Transactions 50:31, pages 10853-10859.
Crossref
Bart Verlinden, Peter Zsabka, Karen Van Hecke, Ken Verguts, Liviu-Cristian Mihailescu, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2021) Dosimetry and methodology of gamma irradiation for degradation studies on solvent extraction systems. Radiochimica Acta 109:1, pages 61-72.
Crossref
Gregory P. Horne, Christopher A. Zarzana, Cathy Rae, Andrew R. Cook, Stephen P. Mezyk, Peter R. Zalupski, Andreas Wilden & Bruce J. Mincher. (2020) Does addition of 1-octanol as a phase modifier provide radical scavenging radioprotection for N , N , N ′, N ′-tetraoctyldiglycolamide (TODGA)? . Physical Chemistry Chemical Physics 22:43, pages 24978-24985.
Crossref
Mudassir Iqbal, Kanwal Waheed, Syeda Bushra Rahat, Tahir Mehmood & Man Seung Lee. (2020) An overview of molecular extractants in room temperature ionic liquids and task specific ionic liquids for the partitioning of actinides/lanthanides. Journal of Radioanalytical and Nuclear Chemistry 325:1, pages 1-31.
Crossref
Gregory P. Horne, Christopher A. Zarzana, Dayna L. Daubaras, Corey D. Pilgrim, Cathy Rae, Richard F. Faulkner, James J. Kiddle & Stephen P. Mezyk. (2020) Probing activated radioprotection of simple hydrophilic phosphonic acids in aqueous solution. Radiation Physics and Chemistry 170, pages 108636.
Crossref
Shunyan Ning, Shichang Zhang, Jie Zhou, Wei Zhang & Yuezhou Wei. (2019) Salt-free separation of 241Am(III) from lanthanides by highly stable macroporous silica-polymer based Me2-CA-BTP/SiO2-P adsorbent. Journal of Radioanalytical and Nuclear Chemistry 322:2, pages 1023-1030.
Crossref
Gregory P. Horne, Christopher A. Zarzana, Travis S. Grimes, Cathy Rae, Joakim Ceder, Stephen P. Mezyk, Bruce J. Mincher, Marie-Christine Charbonnel, Philippe Guilbaud, George Saint-Louis & Laurence Berthon. (2019) Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention . Dalton Transactions 48:38, pages 14450-14460.
Crossref
Gregory P. Horne, James J. Kiddle, Christopher A. Zarzana, Cathy Rae, Julie R. Peller, Andrew R. Cook, Stephen P. Mezyk & Bruce J. Mincher. (2019) 31 P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues . Dalton Transactions 48:30, pages 11547-11555.
Crossref
T. Prathibha, B. Robert Selvan, K. A. Venkatesan & M. P. Antony. (2019) Studies on the radiolytic degradation of N , N -dioctyl-2-hydroxyacetamide using dynamic light scattering and ATR-FTIR spectroscopy . Radiochimica Acta 107:5, pages 441-448.
Crossref
Bruce J. Mincher. (2018) The effects of radiation chemistry on radiochemistry: when unpaired electrons defy great expectations. Journal of Radioanalytical and Nuclear Chemistry 316:2, pages 799-804.
Crossref
J. A. Drader, N. Boubals, B. Camès, D. Guillaumont, P. Guilbaud, G. Saint-Louis & L. Berthon. (2018) Radiolytic stability of N , N -dialkyl amide: effect on Pu( iv ) complexes in solution . Dalton Transactions 47:1, pages 251-263.
Crossref
P. I. Matveev, A. A. Mitrofanov, V. G. Petrov, S. S. Zhokhov, A. A. Smirnova, Yu. A. Ustynyuk & S. N. Kalmykov. (2017) Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation. RSC Advances 7:87, pages 55441-55449.
Crossref
Krzysztof Bobrowski, Konrad Skotnicki & Tomasz Szreder. (2016) Application of Radiation Chemistry to Some Selected Technological Issues Related to the Development of Nuclear Energy. Topics in Current Chemistry 374:5.
Crossref
Stephen P. Mezyk, Bruce J. Mincher, Surajdevprakash B. Dhiman, Bobby Layne & James F. Wishart. (2015) The role of organic solvent radical cations in separations ligand degradation. Journal of Radioanalytical and Nuclear Chemistry 307:3, pages 2445-2449.
Crossref
Hitos Galán, Christopher A. Zarzana, Andreas Wilden, Ana Núñez, Holger Schmidt, Richard J. M. Egberink, Andrea Leoncini, Joaquín Cobos, Willem Verboom, Giuseppe Modolo, Gary S. Groenewold & Bruce J. Mincher. (2015) Gamma-radiolytic stability of new methylated TODGA derivatives for minor actinide recycling. Dalton Transactions 44:41, pages 18049-18056.
Crossref
Bruce J. Mincher. 2015. Reprocessing and Recycling of Spent Nuclear Fuel. Reprocessing and Recycling of Spent Nuclear Fuel 191 211 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.