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Solvent Extraction and Ion Exchange Volume 32, 2014 - Issue 4
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Original Articles

Trivalent Lanthanide/Actinide Separation Using Aqueous-Modified TALSPEAK Chemistry

Travis S. GrimesAqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USA
,
Richard D. TillotsonAqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USA
&
Leigh R. MartinAqueous Separations and Radiochemistry Department, Idaho National Laboratory, Idaho Falls, ID, USACorrespondence[email protected]
Pages 378-390 | Published online: 05 May 2014

Citations (24)

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Nicolas E. F. Uhnak & Kenneth L. Nash. (2021) Functionalized Dipicolinic Acid Derivatives as TALSPEAK-MME Stripping Agents. Solvent Extraction and Ion Exchange 39:1, pages 18-37.
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Nicolas E. F. Uhnak & Kenneth L. Nash. (2020) Pyridine Polyaminocarboxylate Ligands for Use as Actinide-selective Holdback Reagents in Simplified TALSPEAK-like Extraction Systems. Solvent Extraction and Ion Exchange 38:4, pages 401-416.
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Mamdoh R. Mahmoud, Mohamed A. Soliman & Ghada M. Rashad. (2019) Competitive foam separation of rare earth elements from aqueous solutions using a cationic collector. Separation Science and Technology 54:15, pages 2374-2385.
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David Woodhead, Fiona McLachlan, Robin Taylor, Udo Müllich, Andreas Geist, Andreas Wilden & Giuseppe Modolo. (2019) Nitric Acid Extraction into a TODGA Solvent Modified with 1-Octanol. Solvent Extraction and Ion Exchange 37:2, pages 173-190.
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K. V. Syamala, K. A. Venkatesan, M. P. Antony & P. R. Vasudeva Rao. (2016) Kinetics of Eu(III) extraction in macroporous bifunctional phosphinic acid resin. Separation Science and Technology 51:12, pages 2001-2007.
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Aaron T. Johnson & Kenneth L. Nash. (2015) Mixed Monofunctional Extractants for Trivalent Actinide/Lanthanide Separations: TALSPEAK-MME. Solvent Extraction and Ion Exchange 33:7, pages 642-655.
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Kenneth L. Nash. (2015) The Chemistry of TALSPEAK: A Review of the Science. Solvent Extraction and Ion Exchange 33:1, pages 1-55.
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Articles from other publishers (17)

Anjan Dhawa, Jammu Ravi, R. Puspalata, N. R. Jawahar & K. A. Venkatesan. (2023) Diglycolamic acid for the mutual separation of lanthanides and actinides from dilute nitric acid solution: solvent extraction, dynamic light scattering, and spectroscopic investigations. New Journal of Chemistry.
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Gauri Salunkhe, Arijit Sengupta, Anil Boda, Roxana Paz, Nishesh Kumar Gupta, Carolina Leyva, Rohit Singh Chauhan & Sk Musharaf Ali. (2022) Application of hybrid MOF composite in extraction of f-block elements: Experimental and computational investigation. Chemosphere 287, pages 132232.
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Alok Rout & K.A. Venkatesan. (2020) Synergic extraction of europium(III) in hydrophobic ammonium ionic liquid containing neutral and acidic extractants. Journal of Molecular Liquids 312, pages 113377.
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Arunasis Bhattacharyya & Prasanta K. Mohapatra. (2019) Separation of trivalent actinides and lanthanides using various ‘N’, ‘S’ and mixed ‘N,O’ donor ligands: a review. Radiochimica Acta 107:9-11, pages 931-949.
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Anyun Zhang, Huimin Wu, Hao Fu, Zhanghao Xu & Yanqin Ji. (2019) Highly Selective Adsorption of New Bis-Opened-Triazine Materials Hybridized with a Cross-Linked Polymer Support for Palladium and Some Typical Coexisting Metals. Journal of Chemical & Engineering Data 64:4, pages 1529-1537.
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Colt R. Heathman, Travis S. Grimes, Santa Jansone‐Popova, Santanu Roy, Vyacheslav S. Bryantsev & Peter R. Zalupski. (2019) Influence of a Pre‐organized N‐Donor Group on the Coordination of Trivalent Actinides and Lanthanides by an Aminopolycarboxylate Complexant. Chemistry – A European Journal 25:10, pages 2545-2555.
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Nur Nadiatul Hidayah & Sumaiya Zainal Abidin. (2018) The evolution of mineral processing in extraction of rare earth elements using liquid-liquid extraction: A review. Minerals Engineering 121, pages 146-157.
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Ying Dai, Riwen Lv, Dejuan Huang & Qinqin Tao. (2018) Sorption of Uranium on a Bifunctional Polymer of Diethylenetriaminepentaacetic Acid Cross-Linked β-Cyclodextrin in the Presence of Humic Acid: Kinetics, Isotherms, and Thermodynamics. Water, Air, & Soil Pollution 229:4.
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Travis S. Grimes, Colt R. Heathman, Santa Jansone-Popova, Alexander S. Ivanov, Santanu Roy, Vyacheslav S. Bryantsev & Peter R. Zalupski. (2018) Influence of a Heterocyclic Nitrogen-Donor Group on the Coordination of Trivalent Actinides and Lanthanides by Aminopolycarboxylate Complexants. Inorganic Chemistry 57:3, pages 1373-1385.
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Colt R. Heathman, Travis S. Grimes, Santa Jansone-Popova, Alexander S. Ivanov, Vyacheslav S. Bryantsev & Peter R. Zalupski. (2018) Synthesis and characterization of a novel aminopolycarboxylate complexant for efficient trivalent f-element differentiation: N -butyl-2-acetamide-diethylenetriamine- N , N ′, N ′′, N ′′-tetraacetic acid . Dalton Transactions 47:4, pages 1092-1105.
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Dai Ying, Zhang Zhibin, Cao Bin, Cao Xiaohong & Liu Yunhai. (2017) Sorption of europium onto diethylenetriaminepentaacetic acid based silica dioxide: kinetics, isotherm, thermodynamics. Journal of Radioanalytical and Nuclear Chemistry 314:3, pages 2449-2457.
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Hitoshi Watarai & Jiayue Chen. (2017) Magnetophoretic Mole-Ratio Method. Analytical Chemistry 89:19, pages 10141-10146.
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K. Larsson, T. D. Cullen, S. P. Mezyk, R. G. McDowell & L. R. Martin. (2017) Complications in complexation kinetics for lanthanides with DTPA using dye probe molecules in aqueous solution. RSC Advances 7:42, pages 26507-26512.
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Colt R. Heathman, Travis S. Grimes & Peter R. Zalupski. (2016) Coordination Chemistry and f-Element Complexation by Diethylenetriamine- N , N ″-bis(acetylglycine)- N , N ′, N ″-triacetic Acid . Inorganic Chemistry 55:21, pages 11600-11611.
Crossref
Gregg J. Lumetta, Sergey I. Sinkov, Jeanette A. Krause & Lucas E. Sweet. (2016) Neodymium(III) Complexes of Dialkylphosphoric and Dialkylphosphonic Acids Relevant to Liquid–Liquid Extraction Systems. Inorganic Chemistry 55:4, pages 1633-1641.
Crossref
Xiaoqi Sun & Kristian E. Waters. (2014) The adjustable synergistic effects between acid-base coupling bifunctional ionic liquid extractants for rare earth separation. AIChE Journal 60:11, pages 3859-3868.
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Shao-Hua Yin, Shi-Wei Li, Wen-Yuan Wu, Xue Bian, Jin-Hui Peng & Li-Bo Zhang. (2014) Extraction and separation of Ce( iii ) and Pr( iii ) in the system containing two complexing agents with di-(2-ethylhexyl) phosphoric acid . RSC Adv. 4:104, pages 59997-60001.
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