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Solvent Extraction and Ion Exchange Volume 33, 2015 - Issue 4
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Original Articles

Solvent Extraction Separation of Trivalent Americium from Curium and the Lanthanides

Mark P. JensenChemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, USACorrespondence[email protected]
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Renato ChiariziaChemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, USAView further author information
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Joseph S. UlickiDepartment of Chemistry and Biochemistry, University of Wisconsin–Milwaukee, Milwaukee, WI, USAView further author information
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Brian D. SpindlerDepartment of Chemistry and Biochemistry, University of Wisconsin–Milwaukee, Milwaukee, WI, USAView further author information
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Daniel J. MurphyDepartment of Chemistry and Biochemistry, University of Wisconsin–Milwaukee, Milwaukee, WI, USAView further author information
,
M. Mahmun HossainDepartment of Chemistry and Biochemistry, University of Wisconsin–Milwaukee, Milwaukee, WI, USAView further author information
,
Adrián Roca-SabioDepartamento de Química Fundamental, Universidade da Coruña, Campus da Zapateira, Coruña, SpainView further author information
,
Andrés de BlasDepartamento de Química Fundamental, Universidade da Coruña, Campus da Zapateira, Coruña, SpainView further author information
&
Teresa Rodríguez-BlasDepartamento de Química Fundamental, Universidade da Coruña, Campus da Zapateira, Coruña, SpainView further author information
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Pages 329-345 | Published online: 25 Jun 2015

Citations (33)

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Petr Matveev, Prasanta K. Mohapatra, Stepan N. Kalmykov & Vladimir Petrov. (2021) Solvent extraction systems for mutual separation of Am(III) and Cm(III) from nitric acid solutions. A review of recent state-of-the-art. Solvent Extraction and Ion Exchange 39:7, pages 679-713.
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Andreas Geist & Petra J. Panak. (2021) Recent Progress in Trivalent Actinide and Lanthanide Solvent Extraction and Coordination Chemistry with Triazinylpyridine N Donor Ligands. Solvent Extraction and Ion Exchange 39:2, pages 128-151.
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Jonathan D. Burns & Abraham Clearfield. (2018) Kinetics of Ion Exchange of Zr/Sn(IV) Phosphonate–Phosphate Hybrid Materials for Separation of Lanthanides from Oxidized Actinides. Solvent Extraction and Ion Exchange 36:7, pages 674-686.
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Emily Campbell, Vanessa E. Holfeltz, Gabriel B. Hall, Kenneth L. Nash, Gregg J. Lumetta & Tatiana G. Levitskaia. (2018) Extraction Behavior of Ln(III) Ions by T2EHDGA/n-Dodecane from Nitric Acid and Sodium Nitrate Solutions. Solvent Extraction and Ion Exchange 36:4, pages 331-346.
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Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, Ashfaq Afsar, Dominic M. Laventine, Kamila Šťastná, Jan John & Petr Distler. (2018) Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium. Solvent Extraction and Ion Exchange 36:2, pages 115-135.
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Articles from other publishers (28)

P. Zsabka, A. Wilden, K. Van Hecke, G. Modolo, M. Verwerft & T. Cardinaels. (2023) Beyond U/Pu separation: Separation of americium from the highly active PUREX raffinate. Journal of Nuclear Materials 581, pages 154445.
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Joseph A. Mattocks, Jonathan J. Jung, Chi-Yun Lin, Ziye Dong, Neela H. Yennawar, Emily R. Featherston, Christina S. Kang-Yun, Timothy A. Hamilton, Dan M. Park, Amie K. Boal & Joseph A. CotruvoJrJr. (2023) Enhanced rare-earth separation with a metal-sensitive lanmodulin dimer. Nature 618:7963, pages 87-93.
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Allison A. Peroutka, Shane S. Galley & Jenifer C. Shafer. (2023) Elucidating the speciation of extracted lanthanides by diglycolamides. Coordination Chemistry Reviews 482, pages 215071.
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Maxime Courchesne, Raoul-Marie Couture, Justine Basque, Nicolas Reynier & Dominic Larivière. (2023) Co-Extraction of Uranium and Mercury Using Ion Exchange from Cemented Radioactive Waste Sulfuric Leachate in Iodide Media. Minerals 13:3, pages 405.
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Katherine R. Johnson, Darren M. Driscoll, Joshua T. Damron, Alexander S. Ivanov & Santa Jansone-Popova. (2023) Size Selective Ligand Tug of War Strategy to Separate Rare Earth Elements. JACS Au 3:2, pages 584-591.
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Yang Liu, Cong-Zhi Wang, Qun-Yan Wu, Jian-Hui Lan, Zhi-Fang Chai, Wang-Suo Wu & Wei-Qun Shi. (2022) Theoretical Probing of Size-Selective Crown Ether Macrocycle Ligands for Transplutonium Element Separation. Inorganic Chemistry 61:10, pages 4404-4413.
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V.L. Vidanov, A.Yu. Shadrin, L.I. Tkachenko, E.V. Kenf, P.V. Parabin & S.S. Shirokov. (2021) Separation of americium and curium for transmutation in the fast neutron reactor. Nuclear Engineering and Design 385, pages 111434.
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A. M. Safiulina, A. V. Lizunov, N. E. Borisova, T. V. Baulina, E. I. Goryunov, I. B. Goryunova & V. K. Brel’. (2021) Extraction Properties of Diphenylposphorylureas with Aliphatic ω-Nitrogen-Containing Substituents. Russian Journal of Inorganic Chemistry 66:5, pages 731-739.
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Alfiya Safiulina, Nataliya Borisova, Mikhail Grigoriev, Dmitriy Baulin, Vladimir Baulin & Aslan Tsivadze. (2021) Design of Extractants for F-Block Elements in a Series of (2-(Diphenylphosphoryl)methoxyphenyl)diphenylphosphine Oxide Derivatives: Synthesis, Quantum-Chemical, and Extraction Studies. Molecules 26:8, pages 2217.
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Peter R. Zalupski, Travis S. Grimes, Corey D. Pilgrim, Colt R. Heathman, Santa Jansone-Popova, Katherine R. Johnson, Vyacheslav Bryantsev & Robert C. ChapleskiJrJr. 2021. Including Actinides. Including Actinides 1 162 .
Nikki A. Thiele, David J. Fiszbein, Joshua J. Woods & Justin J. Wilson. (2020) Tuning the Separation of Light Lanthanides Using a Reverse-Size Selective Aqueous Complexant. Inorganic Chemistry 59:22, pages 16522-16530.
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O Lobacheva & N Dzhevaga. (2020) Method for removing valuable components from technogenic solutions by the example of rare earth elements. Journal of Physics: Conference Series 1679:4, pages 042016.
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A.N. Turanov, V.K. Karandashev & M. Boltoeva. (2020) Solvent extraction of intra-lanthanides using a mixture of TBP and TODGA in ionic liquid. Hydrometallurgy 195, pages 105367.
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N V Dzhevaga & O L Lobacheva. (2019) Analysis of the mixture of rare earth elements by atomic spectroscopy. Journal of Physics: Conference Series 1384:1, pages 012008.
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An T. Ta, Mark P. Jensen & Shubham Vyas. (2019) Dynamic and Solvation Behaviors of ALSEP Organic Ligands. The Journal of Physical Chemistry B 123:40, pages 8550-8558.
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A. M. Safiulina, D. V. Ivanets, E. M. Kudryavtsev, D. V. Baulin, V. E. Baulin & A. Yu. Tsivadze. (2019) Liquid- and Solid-Phase Extraction of Uranium(VI), Thorium(IV), and Rare Earth Elements(III) from Nitric Acid Solutions Using Acid-Type Phosphoryl-Containing Podands. Russian Journal of Inorganic Chemistry 64:4, pages 536-542.
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Ying Dai, Bin Cao, Shimin Zhong, Guanbao Xie, Youqun Wang, Yuhui Liu, Zhibin Zhang, Yunhai Liu & Xiaohong Cao. (2019) Homogeneous liquid–liquid extraction of europium from aqueous solution with ionic liquids. Journal of Radioanalytical and Nuclear Chemistry 319:3, pages 1219-1225.
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David Dan, Cristian Celis‐Barros, Frankie D. White, Joseph M. Sperling & Thomas E. Albrecht‐Schmitt. (2019) Origin of Selectivity of a Triazinyl Ligand for Americium(III) over Neodymium(III). Chemistry – A European Journal 25:13, pages 3248-3252.
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Laurence M. Harwood, Ashfaq Afsar, Petr Distler, Jan John, Jasraj S. Babra, Zoe Y. Selfe, Joeseph Cowell & James Westwood. (2019) Separation of Minor Actinides from Lanthanides Using Immobilized Ligand Systems: The Role of the Counterion. HETEROCYCLES 99:2, pages 825.
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Michael J. Martínez-Rodríguez, Luke C. Olson, Joshua R. Gray & Brenda L. García-Díaz. (2019) Non-Aqueous Electrochemical Fluorination of Used Nuclear Fuel as an Advanced Separation Process. Journal of The Electrochemical Society 166:8, pages E231-E239.
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Lei Mei, Jianhui Lan, Kongqiu Hu & Weiqun Shi. 2012. Encyclopedia of Inorganic and Bioinorganic Chemistry. Encyclopedia of Inorganic and Bioinorganic Chemistry 1 19 .
Gabriela A. Picayo & Mark P. Jensen. 2018. Including Actinides. Including Actinides 145 225 .
Seraj Ahmad Ansari, Rajesh Bhikaji Gujar & Prasanta Kumar Mohapatra. (2017) Complexation of tetraalkyl diglycolamides with trivalent f-cations in a room temperature ionic liquid: extraction and spectroscopic investigations. Dalton Transactions 46:23, pages 7584-7593.
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Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2017) Ligands for f-element extraction used in the nuclear fuel cycle. Chemical Society Reviews 46:23, pages 7229-7273.
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Ashfaq Afsar, Petr Distler, Laurence M. Harwood, Jan John & James Westwood. (2017) Extraction of minor actinides, lanthanides and other fission products by silica-immobilized BTBP/BTPhen ligands. Chemical Communications 53:28, pages 4010-4013.
Crossref
Andrea Leoncini, Seraj A. Ansari, Prasanta K. Mohapatra, Arijit Sengupta, Jurriaan Huskens & Willem Verboom. (2017) Diglycolamide-functionalized poly(propylene imine) diaminobutane dendrimers for sequestration of trivalent f-elements: synthesis, extraction and complexation. Dalton Transactions 46:2, pages 501-508.
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Peter Antal, Bohuslav Drahoš, Radovan Herchel & Zdeněk Trávníček. (2016) Late First-Row Transition-Metal Complexes Containing a 2-Pyridylmethyl Pendant-Armed 15-Membered Macrocyclic Ligand. Field-Induced Slow Magnetic Relaxation in a Seven-Coordinate Cobalt(II) Compound. Inorganic Chemistry 55:12, pages 5957-5972.
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Moheddine Wehbie, Guilhem Arrachart, Iyad Karamé, Leila Ghannam & Stéphane Pellet-Rostaing. (2016) Diglycolamide-functionalized resorcinarene for rare earths extraction. New Journal of Chemistry 40:11, pages 9344-9351.
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