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A Study of the γ-Radiolysis of N,N-Didodecyl-N′,N′-Dioctyldiglycolamide Using UHPLC-ESI-MS Analysis

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Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Aspen N. Vandevender, Bruce J. Mincher, Gary S. Groenewold & Giuseppe Modolo. (2023) Gamma Radiolysis of Phenyl-Substituted TODGAs: Part II. Solvent Extraction and Ion Exchange 41:5, pages 582-605.
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Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Bruce J. Mincher, Gary S. Groenewold & Giuseppe Modolo. (2023) Gamma Radiolysis of Phenyl-Substituted TODGAs: Part I. Solvent Extraction and Ion Exchange 41:5, pages 564-581.
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Christian G. Bustillos, Randy O. Ngelale & Mikael Nilsson. (2023) Low and High LET Degradation Studies of Metal-Loaded Organic Phase Ligands in the ALSEP Process. Solvent Extraction and Ion Exchange 41:4, pages 449-482.
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Bart Verlinden, Andreas Wilden, Karen Van Hecke, Richard J. M. Egberink, Jurriaan Huskens, Willem Verboom, Michelle Hupert, Patrik Weßling, Andreas Geist, Petra J. Panak, Rainier Hermans, Marc Verwerft, Giuseppe Modolo, Koen Binnemans & Thomas Cardinaels. (2023) Solvent Optimization Studies for a New EURO-GANEX Process with 2,2’-Oxybis(N,N-di-n-decylpropanamide) (mTDDGA) and Its Radiolysis Products. Solvent Extraction and Ion Exchange 41:1, pages 59-87.
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Peter Zsabka, Karen Van Hecke, Andreas Wilden, Giuseppe Modolo, Michelle Hupert, Vincent Jespers, Stefan Voorspoels, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2020) Gamma Radiolysis of TODGA and CyMe4BTPhen in the Ionic Liquid Tri-n-Octylmethylammonium Nitrate. Solvent Extraction and Ion Exchange 38:2, pages 212-235.
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Andreas Wilden, Bruce J. Mincher, Stephen P. Mezyk, Liam Twight, Kristyn M. Rosciolo-Johnson, Christopher A. Zarzana, Mary E. Case, Michelle Hupert, Andrea Stärk & Giuseppe Modolo. (2018) Radiolytic and hydrolytic degradation of the hydrophilic diglycolamides. Solvent Extraction and Ion Exchange 36:4, pages 347-359.
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J Drader, G Saint-Louis, J.M Muller, M-C Charbonnel, P Guilbaud, L Berthon, K. M Roscioli-Johnson, C. A Zarzana, C Rae, G. S Groenewold, B. J Mincher, S.P Mezyk, K McCann, S. G Boyes & J Braley. (2017) Radiation chemistry of the branched-chain monoamide di-2-ethylhexyl-isobutyramide. Solvent Extraction and Ion Exchange 35:7, pages 480-495.
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Articles from other publishers (16)

Gregory P. Horne, Ryan P. Morco, Andrew R. Cook & Stephen P. Mezyk. (2023) Dioctyl ether radiolysis under used nuclear fuel reprocessing conditions: Foundational knowledge for the development of sacrificial ligand grafts. Radiation Physics and Chemistry 213, pages 111217.
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Ivan Sanchez-Garcia, Xavier Heres, Dean. R. Peterman, Hitos Galan, Sylvain Costenoble, Sylvain Broussard, Johann Sinot, Travis S. Grimes, Kash Reid Anderson, Santa Jansone-Popova, Maria Chiara Gullo, Alessandro Casnati, Andreas Wilden & Andreas Geist. (2023) Interinstitutional Study of the New EURO-GANEX Process Resistance by Gamma Irradiation Test Loops. Industrial & Engineering Chemistry Research 62:47, pages 20326-20339.
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Yizhi Chen, Peng Zhang, Xiaofan Yang, Qiqi Guo, Hanqin Weng, Hanbao Chong, Weiqun Shi & Mingzhang Lin. (2023) Radiolysis of diamide phenanthroline extractant: exploring the mechanism of HNO3 enhancing the extraction and An/Ln separation performance after irradiation. Separation and Purification Technology 318, pages 123994.
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Gregory P. Horne, Cristian Celis-Barros, Jacy K. Conrad, Travis S. Grimes, Jeffrey R. McLachlan, Brian M. Rotermund, Andrew R. Cook & Stephen P. Mezyk. (2023) Impact of lanthanide ion complexation and temperature on the chemical reactivity of N , N , N ′, N ′-tetraoctyl diglycolamide (TODGA) with the dodecane radical cation . Physical Chemistry Chemical Physics 25:24, pages 16404-16413.
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Brian T. Arko, David Dan, Sara Adelman, David B. Kimball, Stosh A. Kozimor, Marki M. Martinez, Tara Mastren, Daniel L. Huber, Veronika Mocko, Jung Rim, Jenifer C. Shafer, Benjamin W. Stein & E. Miller Wylie. (2023) Exploring how exposure to radiolysis and harsh chemical reagents impact americium-241 extraction chromatography. Materials Advances 4:1, pages 265-283.
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Anastasiia Smirnova, Maksim Yablonskiy, Vladimir Petrov & Artem Mitrofanov. (2022) DFT Prediction of Radiolytic Stability of Conformationally Flexible Ligands. Energies 16:1, pages 257.
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Bart Verlinden, Karen Van Hecke, Andreas Wilden, Michelle Hupert, Beatrix Santiago-Schübel, Richard J. M. Egberink, Willem Verboom, Piotr M. Kowalski, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2022) Gamma radiolytic stability of the novel modified diglycolamide 2,2′-oxybis( N , N -didecylpropanamide) (mTDDGA) for grouped actinide extraction . RSC Advances 12:20, pages 12416-12426.
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Ashleigh Kimberlin, Georges Saint-Louis, Dominique Guillaumont, Béatrice Camès, Philippe Guilbaud & Laurence Berthon. (2022) Effect of metal complexation on diglycolamide radiolysis: a comparison between ex situ gamma and in situ alpha irradiation . Physical Chemistry Chemical Physics 24:16, pages 9213-9228.
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M. V. Evsiunina, P. I. Matveev, S. N. Kalmykov & V. G. Petrov. (2021) Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests. Moscow University Chemistry Bulletin 76:5, pages 287-315.
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Ashleigh Kimberlin, Dominique Guillaumont, Sylvie Arpigny, Béatrice Camès, Philippe Guilbaud, Georges Saint-Louis, Hitos Galán & Laurence Berthon. (2021) An experimental and computational look at the radiolytic degradation of TODGA and the effect on metal complexation. New Journal of Chemistry 45:28, pages 12479-12493.
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Jeesmon Jose, T. Prathibha, N. S. Karthikeyan, K. A. Venkatesan, B. Robert Selvan, H. Seshadri, B. Venkatachalapathy & C. Ravichandran. (2021) Comparative evaluation of radiolytic stability of aqueous soluble BTP and BTBP derivatives under static gamma irradiation. Journal of Radioanalytical and Nuclear Chemistry 328:3, pages 1127-1136.
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Gregory P. Horne, Christopher A. Zarzana, Cathy Rae, Andrew R. Cook, Stephen P. Mezyk, Peter R. Zalupski, Andreas Wilden & Bruce J. Mincher. (2020) Does addition of 1-octanol as a phase modifier provide radical scavenging radioprotection for N , N , N ′, N ′-tetraoctyldiglycolamide (TODGA)? . Physical Chemistry Chemical Physics 22:43, pages 24978-24985.
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Gregory P. Horne, Andreas Wilden, Stephen P. Mezyk, Liam Twight, Michelle Hupert, Andrea Stärk, Willem Verboom, Bruce J. Mincher & Giuseppe Modolo. (2019) Gamma radiolysis of hydrophilic diglycolamide ligands in concentrated aqueous nitrate solution. Dalton Transactions 48:45, pages 17005-17013.
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Dean R. Peterman, Christopher A. Zarzana, Richard D. Tillotson, Rocklan G. McDowell, Cathy Rae, Gary S. Groenewold & Jack D. Law. (2018) Evaluation of the impacts of gamma radiolysis on an ALSEP process solvent. Journal of Radioanalytical and Nuclear Chemistry 316:2, pages 855-860.
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Bruce J. Mincher. (2018) The effects of radiation chemistry on radiochemistry: when unpaired electrons defy great expectations. Journal of Radioanalytical and Nuclear Chemistry 316:2, pages 799-804.
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P. I. Matveev, A. A. Mitrofanov, V. G. Petrov, S. S. Zhokhov, A. A. Smirnova, Yu. A. Ustynyuk & S. N. Kalmykov. (2017) Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation. RSC Advances 7:87, pages 55441-55449.
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