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Solvent Extraction and Ion Exchange Volume 36, 2018 - Issue 2
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Original Articles

Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium

Frank W. LewisDepartment of Applied Sciences, Faculty of Health and Life Sciences, Northumbria University, Newcastle upon Tyne, UKCorrespondence[email protected]
ORCID Iconhttp://orcid.org/0000-0003-3176-8162View further author information
ORCID Icon,
Laurence M. HarwoodDepartment of Chemistry, University of Reading, Whiteknights, Reading, UKORCID Iconhttp://orcid.org/0000-0002-8442-7380View further author information
ORCID Icon,
Michael J. HudsonDepartment of Chemistry, University of Reading, Whiteknights, Reading, UKView further author information
,
Ashfaq AfsarDepartment of Chemistry, University of Reading, Whiteknights, Reading, UKView further author information
,
Dominic M. LaventineDepartment of Chemistry, University of Reading, Whiteknights, Reading, UKView further author information
,
Kamila ŠťastnáDepartment of Nuclear Chemistry, Czech Technical University in Prague, Břehová, Prague, Czech RepublicView further author information
,
Jan JohnDepartment of Nuclear Chemistry, Czech Technical University in Prague, Břehová, Prague, Czech RepublicView further author information
&
Petr DistlerDepartment of Nuclear Chemistry, Czech Technical University in Prague, Břehová, Prague, Czech RepublicView further author information
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Pages 115-135 | Published online: 25 Jan 2018

Citations (19)

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Read on this site (6)

Yuji Sasaki, Masashi Kaneko, Yasutoshi Ban & Hideya Suzuki. (2023) Mutual separation of Am and Cm using ADAAM (alkyl DiAmide AMine) and reduction of volumes for liquid waste generated via batch-wise multistage extractions. Journal of Nuclear Science and Technology 0:0, pages 1-11.
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Petr Matveev, Prasanta K. Mohapatra, Stepan N. Kalmykov & Vladimir Petrov. (2021) Solvent extraction systems for mutual separation of Am(III) and Cm(III) from nitric acid solutions. A review of recent state-of-the-art. Solvent Extraction and Ion Exchange 39:7, pages 679-713.
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Andreas Geist & Petra J. Panak. (2021) Recent Progress in Trivalent Actinide and Lanthanide Solvent Extraction and Coordination Chemistry with Triazinylpyridine N Donor Ligands. Solvent Extraction and Ion Exchange 39:2, pages 128-151.
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Peter Zsabka, Karen Van Hecke, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2020) Selective Extraction of Americium from Curium and the Lanthanides by the Lipophilic Ligand CyMe4BTPhen Dissolved in Aliquat-336 Nitrate Ionic Liquid. Solvent Extraction and Ion Exchange 38:2, pages 194-211.
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Petr Distler, Miriam Mindová, Jan John, Vasilij A. Babain, Mikhail Yu. Alyapyshev, Lyudmila I. Tkachenko, Ekaterina V. Kenf, Laurence M. Harwood & Ashfaq Afsar. (2020) Fluorinated Carbonates as New Diluents for Extraction and Separation of f-Block Elements. Solvent Extraction and Ion Exchange 38:2, pages 180-193.
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Łukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel & Philippe Moisy. (2019) Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO3-Ph-BTP and SO3-Ph-BTBP Ligands. Solvent Extraction and Ion Exchange 37:3-4, pages 259-268.
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Articles from other publishers (13)

P. Zsabka, A. Wilden, K. Van Hecke, G. Modolo, M. Verwerft & T. Cardinaels. (2023) Beyond U/Pu separation: Separation of americium from the highly active PUREX raffinate. Journal of Nuclear Materials 581, pages 154445.
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Hideya Suzuki & Yasutoshi Ban. (2023) Efficient separation of americium by a mixed solvent of two extractants, a diamideamine and a nitrilotriacetamide. Analytical Sciences 39:8, pages 1341-1348.
Crossref
Izaak Fryer-Kanssen, Thomas Malcomson, Jonathan Austin & Andrew Kerridge. (2023) The role of covalency in enhancing stability of Eu and Am complexes: a DFT comparison of BTP and BTPhen. Physical Chemistry Chemical Physics 25:29, pages 19453-19461.
Crossref
Miriam Mindova, Petr Distler, Jan John, Karel Stamberg, Dmytro Bavol, Suzan El Anwar & Bohumir Gruner. (2023) Extraction characteristics and radiation stability of the CHALMEX process for separation of Am(III) and Eu(III) at different temperatures. Separation and Purification Technology 314, pages 123534.
Crossref
Petr Distler, Miriam Mindova, Jan Sebesta, Bohumir Gruner, Dmytro Bavol, Richard J. M. Egberink, Willem Verboom, Vasily A. Babain & Jan John. (2021) Stability of Different BTBP and BTPhen Extracting or Masking Compounds against γ Radiation. ACS Omega 6:40, pages 26416-26427.
Crossref
Péter Zsabka, Karen Van Hecke, Lesley Adriaensen, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2021) Selective extraction of trivalent actinides using CyMe 4 BTPhen in the ionic liquid Aliquat-336 nitrate . RSC Advances 11:11, pages 6014-6021.
Crossref
Petr Distler, Karel Stamberg, Jan John, Laurence M. Harwood & Frank W. Lewis. (2020) Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions. The Journal of Chemical Thermodynamics 141, pages 105955.
Crossref
Andrey V. Zaytsev, Rachel Bulmer, Valery N. Kozhevnikov, Mark Sims, Giuseppe Modolo, Andreas Wilden, Paul G. Waddell, Andreas Geist, Petra J. Panak, Patrik Wessling & Frank W. Lewis. (2019) Exploring the Subtle Effect of Aliphatic Ring Size on Minor Actinide‐Extraction Properties and Metal Ion Speciation in Bis‐1,2,4‐Triazine Ligands. Chemistry – A European Journal 26:2, pages 428-437.
Crossref
Laurence M. Harwood, Jan John, Ashfaq Afsar, Jasraj S. Babra, Petr Distler, Iain Hopkins, James Westwood & Zoe Y. Selfe. (2020) Extraction Properties of 4-Tetra(hydroxyphenyl)BTPhen in Liquid-Liquid Extraction Systems with Cyclohexanone/Octanol or in a Solid-Phase Extraction System. HETEROCYCLES 101:1, pages 209.
Crossref
Jerzy Narbutt. 2020. Liquid-Phase Extraction. Liquid-Phase Extraction 725 744 .
Fangfang Wu, Hongbin Lv, Xihong He, Zhongping Cheng, Hongwei Jia, Shubao Xie, Yuekun Liu, Guoan Ye & Hui He. (2019) Selective Am(III) stripping with water-soluble PyTri-Diol in nitric acid from HDEHP organic phase. Journal of Radioanalytical and Nuclear Chemistry 323:1, pages 283-289.
Crossref
Laurence Whitty-Léveillé, Nicolas Reynier & Dominic Larivière. (2018) Selective Removal of Uranium from Rare Earth Leachates via Magnetic Solid-Phase Extraction Using Schiff Base Ligands. Industrial & Engineering Chemistry Research 58:1, pages 306-315.
Crossref
Frankie D. White & Matthew L. Marsh. 2019. Including Actinides. Including Actinides 123 158 .

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