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Solvent Extraction and Ion Exchange Volume 16, 1998 - Issue 6
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Original Articles

THERMODYNAMICS OF EXTRACTION OF Am(III) AND Eu(III) FROM NITRATE AND THIOCYANATE MEDIA WITH OCTYL(PHENYL)-N,N-DIISOBUTYLCARBAMOYLMETHYLPHOSPHINE OXIDE

J. N. Mathur Chemistry Division, Argonne National Laboratory, 9700 S. Cass Ave. Argonne, Illinois, 60439-4831
&
K. L. Nash Chemistry Division, Argonne National Laboratory, 9700 S. Cass Ave. Argonne, Illinois, 60439-4831View further author information
Pages 1341-1356 | Received 21 Jan 1998, Published online: 10 May 2007

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Andrew W. Knight, Renato Chiarizia & L. Soderholm. (2017) Extraction Selectivity of a Quaternary Alkylammonium Salt for Trivalent Actinides over Trivalent Lanthanides: Does Extractant Aggregation Play a Role?. Solvent Extraction and Ion Exchange 35:4, pages 266-279.
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J. Sulakova, R.T. Paine, M. Chakravarty & K.L. Nash. (2012) Extraction of Lanthanide and Actinide Nitrate and Thiocyanate Salts by 2:6-Bis[(bis(2-n-Octyl)phosphino)methyl]pyridine N:P:P′-trioxide in Toluene. Separation Science and Technology 47:14-15, pages 2015-2023.
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Derek Brigham, Coralie Badajoz, Gerard Cote & Kenneth L. Nash. (2011) Extraction of Trivalent Lanthanides and Americium by Tri-n-octylphosphine Oxide from Ammonium Thiocyanate Media. Solvent Extraction and Ion Exchange 29:2, pages 270-291.
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Makoto Arisaka & Takaumi Kimura. (2011) Thermodynamic and Spectroscopic Studies on Am(III) and Eu(III) in the Extraction System of N,N,N',N'-Tetraoctyl-3-Oxapentane-1,5-Diamide in n-Dodecane/Nitric Acid. Solvent Extraction and Ion Exchange 29:1, pages 72-85.
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P. R. Zalupski & K. L. Nash. (2008) Two‐Phase Calorimetry. I. Studies on the Thermodynamics of Lanthanide Extraction by Bis(2‐EthylHexyl) Phosphoric Acid. Solvent Extraction and Ion Exchange 26:5, pages 514-533.
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R. D. Ambashta, P. K. Wattal, S. Singh & D. Bahadur. (2006) Magnetic Carrier for Radionuclide Removal from Aqueous Wastes: Parameters Investigated in the Development of Nanoscale Magnetite Based Carbamoyl Methyl Phosphine Oxide. Separation Science and Technology 41:5, pages 925-942.
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Anyun Zhang, Yuezhou Wei, Harutaka Hoshi & Mikio Kumagai. (2005) Synthesis of a Novel Silica‐Based Macroporous Polymer Containing TODGA Chelating Agent and Its Application in the Chromatographic Separation of Mo(VI) and Zr(IV) from Diethylenetriaminepentaacetic Acid. Separation Science and Technology 40:4, pages 811-827.
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Shoichi Tachimori, Yuji Sasaki & Shin-ichi Suzuki. (2002) MODIFICATION OF TODGA- -DODECANE SOLVENT WITH A MONOAMIDE FOR HIGH LOADING OF LANTHANIDES(III) AND ACTINIDES(III). Solvent Extraction and Ion Exchange 20:6, pages 687-699.
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E. O. Otu, R. Chiarizia, P. G. Rickert & K. L. Nash. (2002) THE EXTRACTION OF AMERICIUM AND STRONTIUM BY P,P′-DI(2-ETHYLHEXYL) BENZENE-1,2-DIPHOSPHONIC ACID*. Solvent Extraction and Ion Exchange 20:6, pages 607-632.
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G. Suresh, M. S. Murali & J. N. Mathur. (2001) EFFECT OF ANIONS ON THERMODYNAMICS OF EXTRACTION OF Am(III) AND Eu(III) WITH OCTYL(PHENYL)-N,N-DIISOBUTYL-CARBAMOYLMETHYLPHOSPHINE OXIDE. Solvent Extraction and Ion Exchange 19:6, pages 947-964.
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G. Ionova, S. Ionov, C. Rabbe, C. Hill, C. Madic, R. Guillaumont & J. C. Krupa. (2001) MECHANISM OF TRIVALENT ACTINIDE/LANTHANIDE SEPARATION USING BIS(2,4,4-TRIMETHYLPENTYL) DITHIOPHOSPHINIC ACID (CYANEX 301) AND NEUTRAL O-BEARING CO-EXTRACTANT SYNERGISTIC MIXTURES. Solvent Extraction and Ion Exchange 19:3, pages 391-414.
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KennethL. Nash, RichardE. Barrans, Renato Chiarizia, MarkL. Dietz, MarkP. Jensen, PaulG. Rickert, BruceA. Moyer, PeterV. Bonnesen, JeffreyC. Bryan & RichardA. Sachleben. (2000) FUNDAMENTAL INVESTIGATIONS OF SEPARATIONS SCIENCE FOR RADIOACTIVE MATERIALS. Solvent Extraction and Ion Exchange 18:4, pages 605-631.
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MARTYN S. RAY. (1999) Equilibrium-Staged Separations: A Bibliography Update(1998). Separation Science and Technology 34:16, pages 3305-3321.
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Parveen K. Verma, Rajesh B. Gujar, Seraj A. Ansari, Sk. Musharaf Ali, Richard J. M. Egberink, Jurriaan Huskens, Willem Verboom & Prasanta K. Mohapatra. (2022) Sequestration of Am3+ and Eu3+ into ionic liquid containing Aza-macrocycle based multiple-diglycolamide ligands: Extraction, complexation, luminescence and DFT studies. Journal of Molecular Liquids 347, pages 118291.
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Wenchao Wu, Taoxiang Sun, Ning Pu, Dechao Meng, Youzhen Li, Jiahao Dang, Ying Yang, Jing Chen & Chao Xu. (2018) Thermodynamic and spectroscopic study on the solvation and complexation behavior of Ln( iii ) in ionic liquids: binding of Ln( iii ) with CMPO in C 4 mimNTf 2 . New Journal of Chemistry 42:11, pages 9098-9109.
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Samantha K. Cary, Kevin S. Boland, Justin N. Cross, Stosh A. Kozimor & Brian L. Scott. (2017) Advances in containment methods and plutonium recovery strategies that led to the structural characterization of plutonium(IV) tetrachloride tris-diphenylsulfoxide, PuCl4(OSPh2)3. Polyhedron 126, pages 220-226.
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Maria Atanassova. (2016) Investigation of synergism and selectivity using mixture of two neutral extractants in IL media for lanthanoids extraction. Separation and Purification Technology 169, pages 253-261.
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Thanaporn Wannachod, Thidarat Wongsawa, Prakorn Ramakul, Ura Pancharoen & Soorathep Kheawhom. (2016) The synergistic extraction of uranium ions from monazite leach solution via HFSLM and its mass transfer. Journal of Industrial and Engineering Chemistry 33, pages 246-254.
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Tyler J. Carter & Richard E. Wilson. (2015) Coordination Chemistry of Homoleptic Actinide(IV)–Thiocyanate Complexes. Chemistry – A European Journal 21:44, pages 15575-15582.
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Cong-Zhi Wang, Wei-Qun Shi, Jian-Hui Lan, Yu-Liang Zhao, Yue-Zhou Wei & Zhi-Fang Chai. (2013) Complexation Behavior of Eu(III) and Am(III) with CMPO and Ph 2 CMPO Ligands: Insights from Density Functional Theory . Inorganic Chemistry 52:19, pages 10904-10911.
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R. B. Gujar, S. A. Ansari, M. S. Murali, P. K. Mohapatra & V. K. Manchanda. (2010) Comparative evaluation of two substituted diglycolamide extractants for ‘actinide partitioning’. Journal of Radioanalytical and Nuclear Chemistry 284:2, pages 377-385.
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D. N. Shishkin & Yu. S. Fedorov. (2010) Synergistic extraction of REE and TPE from HNO3 solutions with a mixture of CCD and HDBP ZS (1: 6) in a polar diluent. Radiochemistry 52:1, pages 60-64.
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Kenneth L. Nash, Charles Madic, Jagdish N. Mathur & Jeéroôme Lacquement. 2011. The Chemistry of the Actinide and Transactinide Elements. The Chemistry of the Actinide and Transactinide Elements 2622 2798 .
D. N. Shishkin, B. Ya. Galkin & Yu. S. Fedorov. (2009) Synergistic extraction of REE and TPE from HNO3 solutions with a CCD-HDBP ZS (1: 12) mixture in a polar diluent. Radiochemistry 50:6, pages 621-625.
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D. N. Shishkin, Yu. S. Fedorov & B. Ya. Galkin. (2007) Synergistic extraction of REE and TPE from nitric acid solutions with chlorinated cobalt dicarbollide-dibutyl hydrogen phosphate mixture in a polar diluent. Radiochemistry 49:6, pages 607-612.
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S. A. Ansari, P. N. Pathak, M. Husain, A. K. Prasad, V. S. Parmar & V. K. Manchanda. (2006) Extraction of actinides using N , N , N ′, N ′-tetraoctyl diglycolamide (TODGA): a thermodynamic study . Radiochimica Acta 94:6-7, pages 307-312.
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Anyun Zhang, Yuezhou Wei, Harutaka Hoshi, Mikio Kumagai, Masayoshi Kamiya & Tomozo Koyama. (2005) Resistance properties of a macroporous silica-based N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide-impregnated polymeric adsorption material against nitric acid, temperature and γ-irradiation. Radiation Physics and Chemistry 72:6, pages 669-678.
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Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Yoshikazu Koma & Tomozo Koyama. (2005) Resistant behavior of a novel silica-based octyl(phenyl)-N,N-diisobutyl carbamoylmethylphoshine oxide neutral extraction resin against nitric acid, temperature and γ-radiation. Radiation Physics and Chemistry 72:4, pages 455-463.
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G. Suresh, M. S. Murali & J. N. Mathur. (2003) Thermodynamics of extraction of Am(III) and Eu(III) from different anionic media with Tri- n -octyl phosphine oxide . Radiochimica Acta 91:3, pages 127-134.
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Kenneth L. Nash, Claire Lavallette, Marian Borkowski, Robert T. Paine & Xinmin Gan. (2002) Features of the Thermodynamics of Two-Phase Distribution Reactions of Americium(III) and Europium(III) Nitrates into Solutions of 2,6-Bis[(bis(2-ethylhexyl)phosphino)methyl]pyridine N , P , P  ‘-Trioxide . Inorganic Chemistry 41:22, pages 5849-5858.
Crossref

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