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Original Articles

The Chemistry of Antiwear Films Generated by the Combination of ZDDP and MoDTC Examined by X-ray Absorption Spectroscopy

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Pages 69-77 | Published online: 25 Mar 2008

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Read on this site (11)

Hikaru Okubo, Misa Yonehara & Shinya Sasaki. (2018) In Situ Raman Observations of the Formation of MoDTC-Derived Tribofilms at Steel/Steel Contact Under Boundary Lubrication. Tribology Transactions 61:6, pages 1040-1047.
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Sujay Bagi, Kimaya Vyavhare & Pranesh B. Aswath. (2018) Tribological characteristics of greases with and without metallo-organic friction-modifiers. Tribology - Materials, Surfaces & Interfaces 12:4, pages 223-236.
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D. Zhao, T-K. Sham, M. Kasrai, Z. Bai & F. Zhao. (2014) Tribological properties of Mg/Al–CO3 layered double hydroxide as additive in base oil. Tribology - Materials, Surfaces & Interfaces 8:4, pages 222-234.
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Z. Zhang, E.S. Yamaguchi, L. Yu, M. Kasrai & G.M. Bancroft. (2007) Effects of Mo-Containing Dispersants on the Function of ZDDP: Chemistry and Tribology. Tribology Transactions 50:1, pages 58-67.
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G. Pereira, A. Lachenwitzer, M. Kasrai, G. M. Bancroft, P. R. Norton, M. Abrecht, P. U. P. A. Gilbert, T. Regier, R. I. R. Blyth & J. Thompson. (2007) Chemical and mechanical analysis of tribofilms from fully formulated oils Part 1 – Films on 52100 steel. Tribology - Materials, Surfaces & Interfaces 1:1, pages 48-61.
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G. Pereira, A. Lachenwitzer, D. Munoz-Paniagua, M. Kasrai, P. R. Norton, T. W. Capehart, T. A. Perry & Y.-T. Cheng. (2007) Nanoscale chemistry and mechanical properties of tribofilms on Al–Si alloy (A383): interaction of ZDDP, calcium detergent and molybdenum friction modifier. Tribology - Materials, Surfaces & Interfaces 1:1, pages 4-17.
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DALIAG. YABLON, PATRICIAH. KALAMARAS, DouglasE. Deckman & MartinN. Webster. (2006) Atomic Force Microscopy and Raman Spectroscopy Investigation of Additive Interactions Responsible for Anti-Wear Film Formation in a Lubricated Contact. Tribology Transactions 49:1, pages 108-116.
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E.S. Yamaguchi, S.H. Roby & S.W. Yeh. (2005) Time-Dependent Film Formation from ZnDTPs and Nonphosphorus Antiwear Agents. Tribology Transactions 48:1, pages 57-68.
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Jocelyn Graham, Hugh Spikes & Stefan Korcek. (2001) The Friction Reducing Properties of Molybdenum Dialkyldithiocarbamate Additives: Part I — Factors Influencing Friction Reduction. Tribology Transactions 44:4, pages 626-636.
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Articles from other publishers (78)

Carly S. Hanson, Michael Donohoe & Derek A. Pratt. (2023) Enhancement of Diarylamine Antioxidant Activity by Molybdenum Dithiocarbamates. The Journal of Organic Chemistry.
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Yan Chen, Peter Renner & Hong Liang. (2022) A review of current understanding in tribochemical reactions involving lubricant additives. Friction 11:4, pages 489-512.
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Yanshuang Wang, Pu Zhang, Xudong Gao & Yongjie Cheng. (2023) Rheological and tribological properties of polyurea greases containing additives of MoDDP and PB. Tribology International 180, pages 108291.
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Mukesh Kumar Dubey, Rameshwar Chaudhary, Ramu Emmandi, Sarita Seth, Rajendra Mahapatra, A.K. Harinarain & S.S.V. Ramakumar. (2022) Tribological evaluation of passenger car engine oil: Effect of friction modifiers. Results in Engineering 16, pages 100727.
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Stefan Peeters, Gabriele Losi, Paolo Restuccia & M.C. Righi. (2022) Unraveling the mechanism to form MoS lubricant layers from MoDTC by ab initio simulations . Applied Surface Science 606, pages 154880.
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Weiqi Shen, Dongjiang Han, Tomoko Hirayama, Naoki Yamashita, Tadashi Oshio, Hideo Tsuneoka, Kazuo Tagawa & Kazuhiro Yagishita. (2022) N-Oleoyl Sarcosine as an Engine Oil Friction Modifier, Part 1: Tribological Performance of NOS+ZDDP Mixture at 100°C. Tribology Online 17:3, pages 216-226.
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Yu Min Kiw, Pierre Adam, Philippe Schaeffer, Benoît Thiébaut & Chantal Boyer. (2022) Molecular evidence for sulfurization of molybdenum dithiocarbamates (MoDTC) by zinc dithiophosphates: a key process in their synergetic interactions and the enhanced preservation of MoDTC in formulated lubricants?. RSC Advances 12:6, pages 3542-3553.
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J. Crepaldi, E Tomanik, R. M. Souza, R. Balarini, F. Profito, H. Fujita & J.L. do Vale. Impact of ethanol on lubricant additive performance at Piston Ring-Cylinder Liner Interface. Impact of ethanol on lubricant additive performance at Piston Ring-Cylinder Liner Interface.
J. Umer, N. J. Morris, R. Rahmani, H. Rahnejat, S. Howell-Smith & S. Balakrishnan. (2021) Effect of Dispersant Concentration With Friction Modifiers and Anti-Wear Additives on the Tribofilm Composition and Boundary Friction. Journal of Tribology 143:11.
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Priya Pandey, Anthony E. Somers, Samik K. Hait, Maria Forsyth & S. S. V. Ramakumar. (2021) Short Chain Imidazolium Ionic Liquids: Synthesis and Oil Miscibility in Various Base Oil by use of Surfactant as High Performance Friction and Antiwear Lubricant Additive. Tribology Letters 69:3.
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S. Peeters, C. Charrin, I. Duron, S. Loehlé, B. Thiebaut & M.C. Righi. (2021) Importance of the catalytic effect of the substrate in the functionality of lubricant additives: the case of molybdenum dithiocarbamates. Materials Today Chemistry 21, pages 100487.
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Prashant Mittal, Himanshu Rai & Nitya Nand Gosvami. (2021) Microscopic Tribology of ADC12 Alloy Under Lubricant Containing ZDDP and MoDTC Using In Situ AFM. Tribology Letters 69:2.
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Gabriele Losi, Stefan Peeters, Franck Delayens, Hervé Vezin, Sophie Loehlé, Benoit Thiebaut & Maria Clelia Righi. (2021) Experimental and Ab Initio Characterization of Mononuclear Molybdenum Dithiocarbamates in Lubricant Mixtures. Langmuir 37:16, pages 4836-4846.
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Deepak Kumar, Jayant Jain & Nitya Nand Gosvami. (2020) Nanometer-Thick Base Oil Tribofilms with Acrylamide Additive as Lubricants for AZ91 Mg Alloy. ACS Applied Nano Materials 3:10, pages 10551-10559.
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Stefan Peeters, Paolo Restuccia, Sophie Loehlé, Benoit Thiebaut & M. C. Righi. (2020) Tribochemical Reactions of MoDTC Lubricant Additives with Iron by Quantum Mechanics/Molecular Mechanics Simulations. The Journal of Physical Chemistry C 124:25, pages 13688-13694.
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Hikaru Okubo, Chiharu Tadokoro & Shinya Sasaki. (2020) <i>In Situ</i> Raman-SLIM Monitoring for the Formation Processes of MoDTC and ZDDP Tribofilms at Steel/Steel Contacts under Boundary Lubrication. Tribology Online 15:3, pages 105-116.
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Weimin Li, Chanaka Kumara, Huimin Luo, Harry M. MeyerIIIIII, Xin He, Dien Ngo, Seong H. Kim & Jun Qu. (2020) Ultralow Boundary Lubrication Friction by Three-Way Synergistic Interactions among Ionic Liquid, Friction Modifier, and Dispersant. ACS Applied Materials & Interfaces 12:14, pages 17077-17090.
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Wenjuan Huai, Xinchun Chen, Fei Lu, Chenhui Zhang, Liran Ma & Shizhu Wen. (2020) Tribological properties of sulfur- and phosphorus-free organic molybdenum compound as additive in oil. Tribology International 141, pages 105944.
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Zhenqi Guo, Yujuan Zhang, Jucai Wang, Chuanping Gao, Shengmao Zhang, Pingyu Zhang & Zhijun Zhang. (2020) Interactions of Cu nanoparticles with conventional lubricant additives on tribological performance and some physicochemical properties of an ester base oil. Tribology International 141, pages 105941.
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Weimin Li, Chanaka Kumara, Harry M. MeyerIIIIII, Huimin Luo & Jun Qu. (2018) Compatibility between Various Ionic Liquids and an Organic Friction Modifier as Lubricant Additives. Langmuir 34:36, pages 10711-10720.
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Yasir Al-Jeboori, Shahriar Kosarieh, Ardian Morina & Anne Neville. (2018) Investigation of pure sliding and sliding/rolling contacts in a DLC/Cast iron system when lubricated in oils containing MoDTC-Type friction modifier. Tribology International 122, pages 23-37.
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Yasir Al-Jeboori, Shahriar Kosarieh, MacDonald Ofune, Ardian Morina & Anne Neville. (2018) Measuring tappet rotation in a valvetrain rig when lubricated in a fully formulated oil containing MoDTC-type friction modifier. Tribology International 121, pages 442-449.
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Samira Bagheri, Nadia Jamal, Ahmed Halilu & Amin TermehYousefi. (2018) Novel rGO-T-C(n) Nanosheets developed via click chemistry as a lubricant anti-wear additive. Scientific Reports 8:1.
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Takefumi Otsu. (2017) Effect of phosphorus film on frictional properties of molybdenum dithiocarbamate. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 232:4, pages 369-379.
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Ju Shu, Kathryn Harris, Bulat Munavirov, Rene Westbroek, Johan Leckner & Sergei Glavatskih. (2018) Tribology of polypropylene and Li-complex greases with ZDDP and MoDTC additives. Tribology International 118, pages 189-195.
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Misa Yonehara, Hikaru Okubo, Chiharu Tadokoro, Shinya Sasaki & Braham Prakash. (2018) Proposal of Biomimetic Tribological System to Control Friction Behavior under Boundary Lubrication by Applying 3D Metal Printing Process. Tribology Online 13:1, pages 8-14.
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T.W. Scharf. 2017. Friction, Lubrication, and Wear Technology. Friction, Lubrication, and Wear Technology 583 596 .
O. P. Parenago, G. N. Kuz’mina & T. A. Zaimovskaya. (2017) Sulfur-containing molybdenum compounds as high-performance lubricant additives (Review). Petroleum Chemistry 57:8, pages 631-642.
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Y. Rai, A. Neville & A. Morina. (2016) Transient processes of MoS 2 tribofilm formation under boundary lubrication . Lubrication Science 28:7, pages 449-471.
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O. Gorbatchev, M.I. De Barros Bouchet, J.M. Martin, D. Léonard, T. Le-Mogne, R. Iovine, B. Thiebaut & C. Héau. (2016) Friction reduction efficiency of organic Mo-containing FM additives associated to ZDDP for steel and carbon-based contacts. Tribology International 99, pages 278-288.
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Doris N. Khaemba, Anne Neville & Ardian Morina. (2016) New insights on the decomposition mechanism of Molybdenum DialkyldiThioCarbamate (MoDTC): a Raman spectroscopic study. RSC Advances 6:45, pages 38637-38646.
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Michael L. Greenfield, Michael Byrne, Sudipa Mitra-Kirtley, Eric M. Kercher, Trudy B. Bolin, Tianpin Wu, Paul R. Craddock, Kyle D. Bake & Andrew E. Pomerantz. (2015) XANES measurements of sulfur chemistry during asphalt oxidation. Fuel 162, pages 179-185.
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Hugh Spikes. (2015) Friction Modifier Additives. Tribology Letters 60:1.
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Xiaoqiang Fan, Liping Wang, Wen Li & Shanhong Wan. (2015) Improving Tribological Properties of Multialkylated Cyclopentanes under Simulated Space Environment: Two Feasible Approaches. ACS Applied Materials & Interfaces 7:26, pages 14359-14368.
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Sarah M. Lundgren, Katja Eriksson & Brenda Rossenaar. (2015) Boosting the Friction Performance of Amine Friction Modifiers with MoDTC. SAE International Journal of Fuels and Lubricants 8:1, pages 27-30.
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D. Lützenkirchen-Hecht, L. Müller, L. Hoffmann & R. Wagner. (2014) Analysis of engine motor oils by X-ray absorption and X-ray fluorescence spectroscopies. X-Ray Spectrometry 43:4, pages 221-227.
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Ardian Morina, Hongyuan Zhao & J. Fred W. Mosselmans. (2014) In-situ reflection-XANES study of ZDDP and MoDTC lubricant films formed on steel and diamond like carbon (DLC) surfaces. Applied Surface Science 297, pages 167-175.
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Balasubramaniam Vengudusamy, Alexander Grafl, Franz Novotny-Farkas, Thomas Schimmel & Karl Adam. (2013) Tribological behaviour of antiwear additives used in hydraulic applications: Synergistic or antagonistic with other surface-active additives?. Tribology International 67, pages 199-210.
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