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Original Articles

Acid-Catalyzed Cleavage Of 2-Pyridyl and 4-Pyridyl Derivatives Of Aminomethylphosphonic Acid. Kinetic And Chemical Arguments For A Mechanism With A-SE2 Character

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Pages 53-75 | Received 16 May 2000, Published online: 19 Dec 2006

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Read on this site (5)

Waldemar Goldeman & Bogdan Boduszek. (2009) Aminophosphinic Acids in a Pyridine Series, Part 2: Synthesis of 2-, 3-, and 4-Pyridyl Derivatives of 1-(Benzylamino)-methyl-H-phosphinic Acids. Phosphorus, Sulfur, and Silicon and the Related Elements 184:6, pages 1413-1425.
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GeorgiyO. Kachkovskyi & OlegI. Kolodiazhnyi. (2009) Synthesis of Phosphonic Acids Possessing Isoindolin-1-one Moiety: Unexpected Acid-Catalyzed C-P-Bond Cleavage. Phosphorus, Sulfur, and Silicon and the Related Elements 184:4, pages 890-907.
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Bogdan Boduszek, Tomasz Olszewski, Waldemar Goldeman & Magdalena Konieczna. (2006) Aminophosphinic Acids in a Pyridine Series: Cleavage of Pyridine-2- and Pyridine-4-methyl(amino)phosphinic Acids in Acidic Solutions. Phosphorus, Sulfur, and Silicon and the Related Elements 181:4, pages 787-795.
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Bogdan Boduszek, Anna Koreňova, Michal Uher & Daniel Végh. (2003) Synthesis and Cleavage of Pyridone-4 Aminophosphonic Acids. Phosphorus, Sulfur, and Silicon and the Related Elements 178:5, pages 1047-1053.
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Articles from other publishers (7)

Bogdan Boduszek, Tomasz K. Olszewski, Waldemar Goldeman, Kamila Grzegolec & Patrycja Blazejewska. (2012) Preparation of new imidazol-2-yl-(amino)methylphosphonates, phosphinates and phosphine oxides and their unexpected cleavage under acidic conditions. Tetrahedron 68:4, pages 1223-1229.
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Joanna Michalska, Bogdan Boduszek & Tomasz K. Olszewski. (2011) New quinoline‐2, ‐3, and 4‐yl‐(amino) methylphosphonates: Synthesis and study on the CP bond cleavage in quinoline‐2 and ‐4 derivatives under acidic conditions. Heteroatom Chemistry 22:5, pages 617-624.
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Waldemar Goldeman, Monika Pyrkosz, Elżbieta Gumienna-Kontecka & Bogdan Boduszek. (2011) Synthesis and solution studies of Cu(II) complexes with pyridine derivatives of iminobisphosphonic acids. Inorganica Chimica Acta 365:1, pages 391-399.
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Tomasz Krzysztof Olszewski & Bogdan Boduszek. (2010) Synthesis of new thiazole-2, -4, and -5-yl-(amino)methylphosphonates and phosphinates: unprecedented cleavage of thiazole-2 derivatives under acidic conditions. Tetrahedron 66:45, pages 8661-8666.
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Marek Doskocz, Szczepan Roszak & Roman Gancarz. (2008) The decomposition of α-aminophosphine oxides to phosphonic acid derivatives (PIII). Journal of Molecular Modeling 14:5, pages 435-440.
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Waldemar Goldeman, Tomasz K. Olszewski, Bogdan Boduszek & Wanda Sawka-Dobrowolska. (2006) Aminophosphine oxides in a pyridine series. Studies on the cleavage of pyridine-2- and pyridine-4-yl-(N-benzylamino)-methyldiphenylphosphine oxides in acidic solutions. Tetrahedron 62:18, pages 4506-4518.
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Marcin Drąg, Adam Jezierski & Pawel Kafarski. (2004) First example of the chemical, oxidative cleavage of the C–P bond in aminophosphonate chemistry. The oxidation of 1-amino-1-(3,4-dihydroxyphenyl)methylphosphonic acid by NaIO 4 . Chem. Commun.:9, pages 1132-1133.
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