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Original Articles

Chemoselective Synthesis of Stable Phosphorus Ylides from 6-Azauracil and Mechanistic Investigation of the Reaction by UV Spectrophotometry

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Pages 2959-2979 | Received 11 Jul 2008, Accepted 13 Nov 2008, Published online: 03 Nov 2009

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (2)

Ghasem Marandi, Malek Taher Maghsoodlou, Hamideh Saravani, Maryam Shokouhian & Eideh Mofarrah. (2015) Synthesis of Stable Carbamate Phosphorus Ylides by a Four-Component Reaction And Dynamic 1H-Nmr Study of the Energy Barriers for the Rotation around the Carbon–Nitrogen Single Bond and the Carbon–Carbon Double Bond. Phosphorus, Sulfur, and Silicon and the Related Elements 190:9, pages 1410-1421.
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Sayyed M. Habibi Khorassani, Ali Ebrahimi, Malek T. Maghsoodlou, Zahra Ghahghayi, Hojjat Ghasempour & Mohammad A. Kazemian. (2010) NMR study and AIM analysis for the ylide rotamers from the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates in the presence of 2-mercapto-1-methylimidazole. Journal of Sulfur Chemistry 31:3, pages 153-160.
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Articles from other publishers (21)

Mohammad Zakarianezhad, Batoul Makiabadi & Seyede Samira Hosseini. (2021) Theoretical study of the reaction mechanism between triphenylphosphine with dialkyl acetylenedicarboxylates in the presence of benzotriazole. Theoretical Chemistry Accounts 140:2.
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Sayyed Mostafa Habibi-Khorassani, Mehdi Shahraki & Bahareh Mostafa. (2018) Kinetics and Mechanism of the Formation of Ylides, 1, 4 or 1, 5-Diionic Organophosphorus and Phosphonate Esters: A Review. Mini-Reviews in Organic Chemistry 16:1, pages 59-77.
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M. Zakarianezhad, S.M. Habibi-Khorassani, M.T. Maghsoodlou, H. Ghasempour & B. Makiabadi. (2017) Mechanism investigation of the reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and 2-hydroxybenzimidazole: Experimental and theoretical study. Arabian Journal of Chemistry 10, pages S814-S824.
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Sayyed Mostafa Habibi-Khorassani, Mehdi Shahraki, Malek Taher Maghsoodlou & Susan Erfani. (2015) Dynamic 1 H NMR studies of hindered internal rotations in the synthesized particular phosphorus ylide: Experimental and theoretical approaches. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 145, pages 410-416.
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Nadezhda Markova, Ljupco Pejov & Venelin Enchev. (2015) A Hybrid statistical mechanics-quantum chemical model for proton transfer in 5-azauracil and 6-azauracil in water solution. International Journal of Quantum Chemistry 115:8, pages 477-485.
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M. Kumar. 2014. Chemical Shifts and Coupling Constants for Phosphorus-31. Chemical Shifts and Coupling Constants for Phosphorus-31 550 550 .
M. Kumar. 2014. Chemical Shifts and Coupling Constants for Phosphorus-31. Chemical Shifts and Coupling Constants for Phosphorus-31 549 549 .
M. Kumar. 2014. Chemical Shifts and Coupling Constants for Phosphorus-31. Chemical Shifts and Coupling Constants for Phosphorus-31 225 225 .
M. Kumar. 2014. Chemical Shifts and Coupling Constants for Phosphorus-31. Chemical Shifts and Coupling Constants for Phosphorus-31 224 224 .
M. Kumar. 2014. Chemical Shifts and Coupling Constants for Phosphorus-31. Chemical Shifts and Coupling Constants for Phosphorus-31 1080 1080 .
Jing Chen, Angela Buonaugurio, Olga Dolgounitcheva, V. G. Zakrzewski, Kit H. Bowen & J. V. Ortiz. (2012) Photoelectron Spectroscopy of the 6-Azauracil Anion. The Journal of Physical Chemistry A 117:6, pages 1079-1082.
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Morteza Ziyaadini, Malek Taher Maghsoodlou, Nourollah Hazeri & Sayyed Mostafa Habibi-Khorassani. (2013) Synthesis of New Stable Phosphorus Ylides and 1,4-Diionic Organophosphorus Compound from a Reaction between Hexamethyl Phosphorous Triamide and Dimethyl Acetylenedicarboxylate in the Presence of CH-Acids. Heteroatom Chemistry 24:1, pages 84-89.
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Morteza Ziyaadini, Malek Taher Maghsoodlou, Nourallah Hazeri & Sayyed Mostafa Habibi-Khorassani. (2012) Novel synthesis of stable 1,5-diionic organophosphorus compounds from the reaction between triphenylphosphine and acetylenedicarboxylic acid in the presence of N–H heterocyclic compounds. Monatshefte für Chemie - Chemical Monthly 143:12, pages 1681-1685.
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Sayyed Mostafa Habibi‐Khorassani, Malek Taher Maghsoodlou, Ali Ebrahimi, Marzyeh Mohammadi, Mehdi Shahraki & Elham Aghdaei. (2013) Dynamic 1 H NMR investigation along with a theoretical study around the C–C and C = C bonds in a particular phosphorus ylide . Journal of Physical Organic Chemistry 25:12, pages 1328-1335.
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Mehdi Shahraki, Sayyed Mostafa Habibi Khorassani, Ali Ebrahimi, Malek Taher Maghsoodlou & Ali Paknahad. (2012) Theoretical, Kinetic and Mechanistic Studies of the Reaction between Dialkyl Acetylenedicarboxylates, Triphenylphosphine and Pyrrole in Organic Solvents. Progress in Reaction Kinetics and Mechanism 37:4, pages 321-343.
Crossref
Sayyed Mostafa Habibi Khorassani, Malek Taher Maghsoodlou, Elham Aghdaei & Mehdi Shahraki. (2012) 1 H Nmr Technique for Kinetic Investigation of Equilibrium between the Z - and E -Isomers in a Stable Phosphorus Ylide Involving a 2-Indolinone . Progress in Reaction Kinetics and Mechanism 37:3, pages 301-310.
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Sayyed Mostafa Habibi-Khorassani, Ali Ebrahimi, Malek Taher Maghsoodlou, Zahra Ghahghayi & Hojjat Ghasempour. (2012) NMR study and AIM analysis for assignment of the two Z- and E-isomers in phosphorane containing a 2-thiazoline-2-thiol. Arabian Journal of Chemistry 5:1, pages 55-61.
Crossref
Morteza Ziyaadini, Malek Taher Maghsoodlou, Nourollah Hazeri & Sayyed Mostafa Habibi‐Khorassani. (2011) Synthesis and dynamic 1 H NMR study around the carbon–carbon double bond in the new stable phosphorus ylides derived from the reaction between hexamethyl phosphorous triamide and dimethyl acetylenedicarboxylate in the presence of NH‐heterocyclic compounds . Heteroatom Chemistry 23:2, pages 131-137.
Crossref
S.M. Habibi-Khorassani, A. Ebrahimi, M.T. Maghsoodlou, Z. Khajehali & M. Zakarianezhad. (2011) Theoretical, NMR study, kinetics and a mechanistic investigation of the reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and acetyl acetone. Scientia Iranica 18:6, pages 1332-1342.
Crossref
Sayyed Mostafa Habibi-Khorassani, Ali Ebrahimi, Malek Taher Maghsoodlou, Sara Same-Salari, Shahin Nasiri & Hojjat Ghasempour. (2011) Dynamic 1 H NMR study around the carbon-carbon single bond and partial carbon-carbon double bond in the two particular phosphorus ylides and in an enaminoester . Magnetic Resonance in Chemistry 49:5, pages 213-220.
Crossref
Gyorgy Keglevich, Irina Odinets, M Migaud, Gerd-Volker Roeschenthaler, Piotr Balczewski, Frederick Stewart & Robert SlinnD. W. Allen. 2011. Organophosphorus Chemistry. Organophosphorus Chemistry 1 51 .

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