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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 187, 2012 - Issue 10
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Original Articles

Kinetics of Alkaline Hydrolysis of Quaternary Phosphonium Salts. The Influence of Protic and Aprotic Solvents on the Hydrolysis of Alkyl Phenylphosphonium Salts

J. Graham Dawber Staffordshire University, Stoke-on-Trent, U.K., ST4 2DE
,
R. Glynn Skerratt Staffordshire University, Stoke-on-Trent, U.K., ST4 2DE
,
John C. Tebby Staffordshire University, Stoke-on-Trent, U.K., ST4 2DE
&
Albert A. C. Waite Staffordshire University, Stoke-on-Trent, U.K., ST4 2DE
Pages 1261-1268 | Received 21 Feb 2012, Accepted 26 Mar 2012, Published online: 20 Jul 2012

Citations (10)

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Chun-Hong Zhong & Wenhua Huang. (2021) Synthesis of tertiary phosphine oxides by alkaline hydrolysis of quaternary phosphonium zwitterions using excess t-BuOK and stoichiometric water. Synthetic Communications 51:10, pages 1537-1546.
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Articles from other publishers (9)

Megan Treichel, Ruiran Xun, Camille F. Williams, Jamie C. Gaitor, Samantha N. MacMillan, Jessica L. Vinskus, C. Tyler Womble, Tomasz Kowalewski & Kevin J. T. Noonan. (2022) Examining the Alkaline Stability of Tris(dialkylamino)sulfoniums and Sulfoxoniums. The Journal of Organic Chemistry 87:23, pages 15732-15743.
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Chun-Hong Zhong & Wenhua Huang. (2020) Synthesis of Aryldiphenylphosphine Oxides by Quaternization of Tertiary Diphenylphosphines with Aryl Bromides Followed by the Wittig Reaction. ACS Omega 5:26, pages 16010-16020.
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Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Sergiu Shova, Francesc Lloret & Miguel Julve. (2019) In situ generation of Ph 3 PO in cyanido-bridged heterometallic {Fe III Ln III } 2 molecular squares (Ln = Eu, Sm) . Dalton Transactions 48:22, pages 7532-7536.
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Zhe Sun, Ji Pan, Jiangna Guo & Feng Yan. (2018) The Alkaline Stability of Anion Exchange Membrane for Fuel Cell Applications: The Effects of Alkaline Media. Advanced Science 5:8, pages 1800065.
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C. Tyler Womble, Jamie Kang, Kristina M. Hugar, Geoffrey W. Coates, Stefan Bernhard & Kevin J. T. Noonan. (2017) Rapid Analysis of Tetrakis(dialkylamino)phosphonium Stability in Alkaline Media. Organometallics 36:20, pages 4038-4046.
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Peter A. Byrne & Declan G. Gilheany. (2016) The Mechanism of Phosphonium Ylide Alcoholysis and Hydrolysis: Concerted Addition of the O−H Bond Across the P=C Bond. Chemistry - A European Journal 22:27, pages 9140-9154.
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Zuyong Deng, Jin-Hong Lin & Ji-Chang Xiao. (2016) Nucleophilic arylation with tetraarylphosphonium salts. Nature Communications 7:1.
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K. C. Westaway. 2015. Organic Reaction Mechanisms • 2012. Organic Reaction Mechanisms • 2012 267 306 .
Peter A. Byrne, Yannick Ortin & Declan G. Gilheany. (2015) First ever observation of the intermediate of phosphonium salt and ylide hydrolysis: P-hydroxytetraorganophosphorane. Chemical Communications 51:6, pages 1147-1150.
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