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Original Articles

Aryl, hetaryl, and ferrocenyl thioketones as versatile building blocks for exploration in the organic chemistry of sulfur

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Pages 204-211 | Received 20 Oct 2016, Accepted 20 Oct 2016, Published online: 28 Oct 2016

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (4)

Grzegorz Mlostoń & Heinz Heimgartner. (2020) Reactions of thiocarbonyl compounds with electrophilic and nucleophilic carbenes as well as with their metal complexes. Journal of Sulfur Chemistry 41:6, pages 672-700.
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Grzegorz Mlostoń, Róża Hamera-Fałdyga & Heinz Heimgartner. (2018) Silylated thiocarbonyl S-methanides as key intermediates in one-pot olefination reactions leading to ferrocenyl-substituted ethenes and dibenzofulvenes. Journal of Sulfur Chemistry 39:3, pages 267-278.
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Grzegorz Mlostoń, Róża Hamera-Fałdyga, Małgorzata Jeske, Magdalena Godziszewska, Katarzyna Urbaniak & Heinz Heimgartner. (2018) Microwave-assisted reactions of α-diazoketones with hetaryl and ferrocenyl thioketones. Journal of Sulfur Chemistry 39:1, pages 47-63.
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Korany A. Ali, Grzegorz Mlostoń, Katarzyna Urbaniak, Anthony Linden & Heinz Heimgartner. (2017) [3+2]-Cycloadditions of nitrilimines with heteroaryl thioketones. Journal of Sulfur Chemistry 38:6, pages 604-613.
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Articles from other publishers (27)

Sebastian Seidenath, Phillip Seeber, Stephan Kupfer, Stefanie Grӓfe, Wolfgang Weigand, Grzegorz Mlostoń & Piotr Matczak. (2023) Theoretical insights into the spectroscopic properties of ferrocenyl hetaryl ketones. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 296, pages 122635.
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Piotr Matczak, Sławomir Domagała, Wolfgang Weigand & Grzegorz Mlostoń. (2023) A comparative analysis of UV–vis transitions in hetaryl and ferrocenyl thioketones. Chemical Physics 570, pages 111901.
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Kusum Ucheniya, Amreen Chouhan, Lalit Yadav, Pooja Kumari Jat & Satpal Singh Badsara. (2023) Electrochemical, Regioselective, and Stereoselective Synthesis of Allylic Thioethers and Selenoethers under Transition-Metal-Free and Oxidant-Free Conditions. The Journal of Organic Chemistry 88:9, pages 6096-6107.
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Piotr Matczak, Stephan Kupfer, Grzegorz Mlostoń, Philipp Buday, Helmar Görls & Wolfgang Weigand. (2022) Metal–ligand bonding in tricarbonyliron(0) complexes bearing thiochalcone ligands. New Journal of Chemistry 46:27, pages 12924-12933.
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Ahmad Q. Daraosheh, Hassan Abul-Futouh, Natsuki Murakami, Karl Michael Ziems, Helmar Görls, Stephan Kupfer, Stefanie Gräfe, Akihiko Ishii, Małgorzata Celeda, Grzegorz Mlostoń & Wolfgang Weigand. (2022) Novel [FeFe]-Hydrogenase Mimics: Unexpected Course of the Reaction of Ferrocenyl α-Thienyl Thioketone with Fe3(CO)12. Materials 15:8, pages 2867.
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Grzegorz Mlostoń, Katarzyna Urbaniak, Malwina Sobiecka, Heinz Heimgartner, Ernst-Ulrich Würthwein, Reinhold Zimmer, Dieter Lentz & Hans-Ulrich Reissig. (2021) Hetero-Diels-Alder Reactions of In Situ-Generated Azoalkenes with Thioketones; Experimental and Theoretical Studies. Molecules 26:9, pages 2544.
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Dirk Buddensiek, Grzegorz Mlostoń, Piotr Matczak & Jürgen Voss. (2020) A DFT study on the mechanism of the formation of 1,4,2,3‐dithiadiazinanes by head‐to‐head [3 + 3] cyclodimerization of thiocarbonyl S ‐imides . Journal of Physical Organic Chemistry 34:4.
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George Baffour Pipim & Ernest Opoku. (2021) Unveiling the molecular mechanisms of the cycloaddition reactions of aryl hetaryl thioketones and C,N-disubstituted nitrilimines. Journal of Molecular Modeling 27:3.
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Hadi Dolati, Lars Denker, Bartosz Trzaskowski & René Frank. (2021) Superseding β‐Diketiminato Ligands: An Amido Imidazoline‐2‐Imine Ligand Stabilizes the Exhaustive Series of B=X Boranes (X=O, S, Se, Te). Angewandte Chemie International Edition 60:9, pages 4633-4639.
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Hadi Dolati, Lars Denker, Bartosz Trzaskowski & René Frank. (2021) Superseding β‐Diketiminato Ligands: An Amido Imidazoline‐2‐Imine Ligand Stabilizes the Exhaustive Series of B=X Boranes (X=O, S, Se, Te). Angewandte Chemie 133:9, pages 4683-4689.
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Greta Utecht-Jarzyńska, Sergiy S. Mykhaylychenko, Eduard B. Rusanov, Yuriy G. Shermolovich, Marcin Jasiński & Grzegorz Mlostoń. (2021) Highly fluorinated 2,3-dihydro-1,3,4-thiadiazole derivatives via [3+2]-cycloadditions of tertiary thioamides with nitrile imines derived from trifluoroacetonitrile. Journal of Fluorine Chemistry 242, pages 109702.
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Philipp Buday, Phillip Seeber, Clara Zens, Hassan Abul‐Futouh, Helmar Görls, Stefanie Gräfe, Piotr Matczak, Stephan Kupfer, Wolfgang Weigand & Grzegorz Mloston. (2020) Iron(0)‐Mediated Stereoselective (3+2)‐Cycloaddition of Thiochalcones via a Diradical Intermediate. Chemistry – A European Journal 26:50, pages 11412-11416.
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Grzegorz Mlostoń, Katarzyna Urbaniak, Marcin Jasiński, Ernst‐Ulrich Würthwein, Heinz Heimgartner, Reinhold Zimmer & Hans‐Ulrich Reissig. (2019) The [4+2]‐Cycloaddition of α‐Nitrosoalkenes with Thiochalcones as a Prototype of Periselective Hetero‐Diels–Alder Reactions—Experimental and Computational Studies. Chemistry – A European Journal 26:1, pages 237-248.
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Heinz Heimgartner, Marcin Jasiński, Greta Utecht-Jarzyńska, Kamil Świątek & Grzegorz Mlostoń. (2020) Novel Trifluoromethylated Spiro-1,3,4-thiadiazoles via [3+2]-Cycloadditions of 2,3-Diphenylcyclopropenethione with Selected in situ-Generated Nitrile Imines Derived from Trifluoroacetonitrile. HETEROCYCLES 101:1, pages 251.
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Piotr Matczak, Grzegorz Mlostoń & Wolfgang Weigand. (2019) Ferrocenyl hetaryl thioketones: A computational study of their conformational stability. International Journal of Quantum Chemistry 119:24.
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Matczak, Mlostoń, Hamera-Fałdyga, Görls & Weigand. (2019) Structure of Diferrocenyl Thioketone: From Molecule to Crystal. Molecules 24:21, pages 3950.
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Sebastian Gröber, Piotr Matczak, Sławomir Domagała, Thomas Weisheit, Helmar Görls, Annika Düver, Grzegorz Mlostoń & Wolfgang Weigand. (2019) Diferrocenyl Thioketone: Reactions with (Bisphosphane)Pt(0) Complexes—Electrochemical and Computational Studies. Materials 12:17, pages 2832.
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Grzegorz Mlostoń, Małgorzata Celeda, Radomir Jasiński & Heinz Heimgartner. (2018) Experimental and Computational Studies on Stepwise [3+2]‐Cycloadditions of Diaryldiazomethanes with Electron‐Deficient Dimethyl ( E )‐ and ( Z )‐2,3‐Dicyanobutenedioates . European Journal of Organic Chemistry 2019:2-3, pages 422-431.
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Grzegorz Mlostoń, Katarzyna Urbaniak, Reinhold Zimmer, Hans‐Ulrich Reissig & Heinz Heimgartner. (2018) Hetero‐Diels‐Alder Reactions of α‐Nitrosoalkenes with Ferrocenyl, Hetaryl and Cycloaliphatic Thioketones. ChemistrySelect 3:42, pages 11724-11728.
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Ting Zhu, Xiaoxi Wu, Xinzheng Yang, Bigyan Sharma, Na Li, Jiaming Huang, Wentao Wang, Wang Xing, Zhenwen Zhao & Hui Huang. (2018) One-Pot Catalytic Cleavage of C═S Double Bonds by Pd Catalysts at Room Temperature. Inorganic Chemistry 57:15, pages 9266-9273.
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Yohei Matsumoto, Daiki Nakatake, Ryo Yazaki & Takashi Ohshima. (2018) An Expeditious Route to trans ‐Configured Tetrahydrothiophenes Enabled by Fe(OTf) 3 ‐Catalyzed [3+2] Cycloaddition of Donor–Acceptor Cyclopropanes with Thionoesters . Chemistry – A European Journal 24:23, pages 6062-6066.
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André U. Augustin, Maximilian Sensse, Peter G. Jones & Daniel B. Werz. (2017) Stereospecific Reactions of Donor-Acceptor Cyclopropanes with Thioketones: Access to Highly Substituted Tetrahydrothiophenes. Angewandte Chemie International Edition 56:45, pages 14293-14296.
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André U. Augustin, Maximilian Sensse, Peter G. Jones & Daniel B. Werz. (2017) Stereospezifische Reaktion von Donor-Akzeptor-Cyclopropanen mit Thioketonen: ein Zugang zu hoch substituierten Tetrahydrothiophenen. Angewandte Chemie 129:45, pages 14481-14485.
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Grzegorz Mlostoń, Paulina Pipiak, Róża Hamera-Fałdyga & Heinz Heimgartner. (2017) A novel application of 2-silylated 1,3-dithiolanes for the synthesis of aryl/hetaryl-substituted ethenes and dibenzofulvenes. Beilstein Journal of Organic Chemistry 13, pages 1900-1906.
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Greta Utecht, Justyna Sioma, Marcin Jasiński & Grzegorz Mlostoń. (2017) Expected and unexpected results in reactions of fluorinated nitrile imines with (cyclo)aliphatic thioketones. Journal of Fluorine Chemistry 201, pages 68-75.
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Grzegorz Mlostoń, Marcin K. Kowalski, Emilia Obijalska & Heinz Heimgartner. (2017) Efficient synthesis of fluoroalkylated 1,4,2-oxathiazoles via regioselective [3 + 2]-cycloaddition of fluorinated nitrile oxides with thioketones. Journal of Fluorine Chemistry 199, pages 92-96.
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Grzegorz Mlostoń, Paulina Grzelak, Anthony Linden & Heinz Heimgartner. (2017) Thia-Diels–Alder reactions of hetaryl thioketones with nonactivated 1,3-dienes leading to 3,6-dihydro-2H-pyrans: evidence for a diradical mechanism. Chemistry of Heterocyclic Compounds 53:5, pages 518-525.
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