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Original Articles

Cyclotrigermenium Ion, a Free Germyl Cation with 2π-Electron System

Pages 323-329 | Published online: 02 Apr 2008

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Thomas Müller. 2023. Organogermanium Compounds. Organogermanium Compounds 299 338 .
Yoshiyuki Mizuhata and & Norihiro Tokitoh. 2023. Organogermanium Compounds. Organogermanium Compounds 477 506 .
Bin Li, Christoph Wölper, Gebhard Haberhauer & Stephan Schulz. (2020) Synthesis and Reactivity of Heteroleptic Ga‐P‐C Allyl Cation Analogues. Angewandte Chemie International Edition 60:4, pages 1986-1991.
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Bin Li, Christoph Wölper, Gebhard Haberhauer & Stephan Schulz. (2020) Synthesis and Reactivity of Heteroleptic Ga‐P‐C Allyl Cation Analogues. Angewandte Chemie 133:4, pages 2014-2019.
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Andreas Rammo & David Scheschkewitz. (2018) Functional Disilenes in Synthesis. Chemistry – A European Journal 24:27, pages 6866-6885.
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T. A. Kochina, D. L. Myalochkin, V. V. Avrorin & E. N. Sinotova. (2016) Germanium analogs of carbenium ions. Russian Chemical Bulletin 65:3, pages 597-620.
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Israel Fernández, Matthew Duvall, Judy I‐Chia Wu, Paul von Ragué Schleyer & Gernot Frenking. (2011) Aromaticity in Group 14 Homologues of the Cyclopropenylium Cation. Chemistry – A European Journal 17:7, pages 2215-2224.
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Vladimir Ya. Lee & Akira Sekiguchi. 2009. PATAI'S Chemistry of Functional Groups. PATAI'S Chemistry of Functional Groups.
Ilya Zharov & Josef Michl. 2009. PATAI'S Chemistry of Functional Groups. PATAI'S Chemistry of Functional Groups.
Vladimir Ya. Lee & Akira Sekiguchi. (2007) Aromaticity of Group 14 Organometallics: Experimental Aspects. Angewandte Chemie International Edition 46:35, pages 6596-6620.
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Vladimir Ya. Lee & Akira Sekiguchi. (2007) Aromatizität von metallorganischen Verbindungen mit Gruppe‐14‐Elementen: experimentelle Aspekte. Angewandte Chemie 119:35, pages 6716-6740.
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Akira Sekiguchi & Vladimir Ya. Lee. (2003) Heavy Cyclopropenes of Si, Ge, and SnA New Challenge in the Chemistry of Group 14 Elements. Chemical Reviews 103:4, pages 1429-1448.
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Akira Sekiguchi, Tadahiro Matsuno & Masaaki Ichinohe. (2000) The Homocyclotrisilenylium Ion:  A Free Silyl Cation in the Condensed Phase. Journal of the American Chemical Society 122:45, pages 11250-11251.
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Masaaki Ichinohe, Hiroshi Sekiyama, Norihisa Fukaya & Akira Sekiguchi. (2000) On the Role of cis,trans -( t -Bu 3 SiGeCl) 3 in the Reaction of GeCl 2 ·Dioxane with Tri- tert -butylsilylsodium:  Evidence for Existence of Digermanylsodium t -Bu 3 SiGe(Cl) 2 Ge(Cl)(Na)Si t -Bu 3 and Digermene t -Bu 3 Si(Cl)GeGe(Cl)Si t -Bu 3 . Journal of the American Chemical Society 122:28, pages 6781-6782.
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Masaaki Ichinohe, Hiroshi Fukui & Akira Sekiguchi. (2000) Synthesis of t Bu 3 E + Nitrile Complexes by Oxidative Cleavage of t Bu 3 E-E t Bu 3 (E = Si, Ge, Sn) . Chemistry Letters 29:6, pages 600-601.
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Masaaki Ichinohe, Tadahiro Matsuno & Akira Sekiguchi. (1999) Synthese, Charakterisierung und Kristallstruktur von Cyclotrisilen: ein dreigliedriger Ring mit einer Si-Si-Doppelbindung. Angewandte Chemie 111:15, pages 2331-2333.
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Masaaki Ichinohe, Nobuyuki Takahashi & Akira Sekiguchi. (1999) Formation and Structure of Protonated Tetrasilatetrahedrane-monooxide, ( tert -Bu 3 Si) 4 Si 4 OH + . Chemistry Letters 28:7, pages 553-554.
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Masaaki Ichinohe, Norihisa Fukaya & Akira Sekiguchi. (1998) Synthesis and Structure of Cyclotrigermenium Salt of the Tetrakis{3,5-bis(trifluoromethyl)phenyl}borate Anion. A Stable Free Germyl Cation in the Condensed Phase. Chemistry Letters 27:10, pages 1045-1046.
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