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Original Articles

Kinetics of Long-Chain Branching via Chain Transfer to Polymer: II. New Theory to Predict Molecular Weight Distribution

Pages 379-405 | Published online: 04 Oct 2013

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Read on this site (2)

N. C. Miller, R. W. Toffolo, K. B. McAuley & P. J. McLellan. (1996) Determining Polymer Chain Length Distributions Using Numerical Inversion of Laplace Transforms. Polymer Reaction Engineering 4:4, pages 279-301.
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Reinaldo Giudici & Archie E. Hamielec. (1996) A Simulation Study on Random Scission of Branched Chains. Polymer Reaction Engineering 4:1, pages 73-101.
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Articles from other publishers (23)

K. De Smit, M. Edeleva, A. D. Trigilio, Y. W. Marien, P. H. M. Van Steenberge & D. R. D'hooge. (2023) Kinetic Monte Carlo residence time distributions and kinetics in view of extrusion-based polymer modification and recycling. Reaction Chemistry & Engineering 8:3, pages 563-576.
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Nazila Yaghini & Jaap den Doelder. (2023) Simulations mapping the influence of oxygen, extruder residence time, and mechanical shear on low-density polyethylene structure during recycling. Polymer 265, pages 125596.
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Enrique Saldívar‐Guerra. (2020) Numerical Techniques for the Solution of the Molecular Weight Distribution in Polymerization Mechanisms, State of the Art. Macromolecular Reaction Engineering 14:4, pages 2000010.
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Klaus-Dieter Hungenberg & Michael Wulkow. 2018. Modeling and Simulation in Polymer Reaction Engineering. Modeling and Simulation in Polymer Reaction Engineering 269 276 .
Amanda L. T. Brandão, João B. P. Soares, José Carlos Pinto & André L. Alberton. (2015) When Polymer Reaction Engineers Play Dice: Applications of Monte Carlo Models in PRE. Macromolecular Reaction Engineering 9:3, pages 141-185.
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Nazila Yaghini & Piet D. Iedema. (2014) Molecular weight/branching distribution modeling of low-density-polyethylene accounting for topological scission and combination termination in continuous stirred tank reactor. Chemical Engineering Science 116, pages 144-160.
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Nazila Yaghini & Piet D. Iedema. (2014) Molecular Weight and Branching Distribution Modeling in Radical Polymerization with Transfer to Polymer and Scission Under Gel Conditions and Allowing for Multiradicals. Macromolecules 47:15, pages 4851-4863.
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Julio César Hernández‐Ortiz & Eduardo Vivaldo‐Lima. 2013. Handbook of Polymer Synthesis, Characterization, and Processing. Handbook of Polymer Synthesis, Characterization, and Processing 187 204 .
Christof Schütte & Michael Wulkow. (2010) A Hybrid Galerkin-Monte-Carlo Approach to Higher-Dimensional Population Balances in Polymerization Kinetics. Macromolecular Reaction Engineering 4:9-10, pages 562-577.
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Bibiana Alejandra Yáñez-Martínez, Gabriel Luna-Bárcenas & Eduardo Vivaldo-Lima. (2009) Sol MWD During Styrene, Vinyl Acetate, Methyl Methacrylate, and Butyl Acrylate Homopolymerization: A Numerical Study Using the NFT Approach. Macromolecular Theory and Simulations 18:3, pages 171-194.
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Michael Wulkow. (2008) Computer Aided Modeling of Polymer Reaction Engineering—The Status of Predici, I‐Simulation. Macromolecular Reaction Engineering 2:6, pages 461-494.
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Piet D. Iedema, Michael Wulkow & Huub C.J. Hoefsloot. (2007) Conditional Monte Carlo sampling to find branching architectures of polymers from radical polymerizations with transfer to polymer and recombination termination. Polymer 48:6, pages 1770-1784.
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Piet D. Iedema & Huub C. J. Hoefsloot. (2006) Conditional Monte Carlo Sampling To Find Branching Architectures of Polymers from Radical Polymerizations with Transfer to Polymer. Macromolecules 39:8, pages 3081-3088.
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Eduardo Vivaldo-Lima, Martha Roa-Luna & Enrique Saldívar-Guerra. (2005) Development of a Kinetic Model for Thermal Crosslinking of Rubbery Polymers. Macromolecular Theory and Simulations 14:9, pages 539-553.
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Piet D. Iedema & Huub C. J. Hoefsloot. (2005) Computing the Trivariate Chain Length/Degree of Branching/Number of Combination Points Distribution for Radical Polymerization with Transfer to Polymer and Recombination Termination. Macromolecular Theory and Simulations 14:8, pages 505-518.
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Piet D. Iedema & Huub C. J. Hoefsloot. (2004) Role of Polyradicals in Predicting Chain Length Distribution and Gelation for Radical Polymerization with Transfer to Polymer. Macromolecules 37:26, pages 10155-10164.
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S.M. Ghafelebashi Zarand, S. Pourmahdian, F. Afshar Taromi, E. Jabbari & B. Dabir. (2003) Modeling of Styrene/Butadiene Co‐polymerization in Emulsion with Monte Carlo Simulation. Chemical Engineering & Technology 26:9, pages 969-974.
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E. Jabbari. (2001) Monte Carlo simulation of tri-functional branching and tetra-functional crosslinking in emulsion polymerization of butadiene. Polymer 42:11, pages 4873-4884.
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Apostolis Baltsas, Dimitris S. Achilias & Costas Kiparissides. (2003) A theoretical investigation of the production of branched copolymers in continuous stirred tank reactors. Macromolecular Theory and Simulations 5:3, pages 477-497.
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Hidetaka Tobita. (1994) Kinetics of long-chain branching in emulsion polymerization: 2. Vinyl acetate polymerization. Polymer 35:14, pages 3032-3038.
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Hidetaka Tobita. (1994) Kinetics of long-chain branching in emulsion polymerization: 1. Chain transfer to polymer. Polymer 35:14, pages 3023-3031.
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Hidetaka Tobita. (2003) A simulation model for long‐chain branching in vinyl acetate polymerization: 2. Continuous polymerization in a stirred tank reactor. Journal of Polymer Science Part B: Polymer Physics 32:5, pages 911-919.
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Hidetaka Tobita. (2003) A simulation model for long‐chain branching in vinyl acetate polymerization: 1. Batch polymerization. Journal of Polymer Science Part B: Polymer Physics 32:5, pages 901-910.
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