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Natural Product Letters Volume 5, 1994 - Issue 3
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Original Articles

Highly Regioselective Elimination of a Ring—attached Acetoxy Group: Methyl Ent—Isocopalate from Sclareol

Julio G. Urones Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
,
Isidro S. Marcos Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
,
Pilar Basabe Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
,
Antonio Gomez Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
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Antonio Estrella Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
&
Anna M. Lithgow Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008, Salamanca, SPAIN Fax:
Pages 217-220 | Received 16 Sep 1994, Published online: 04 Oct 2006

Citations (14)

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Leticia Ferreiro-Mederos, Steve Lanners, Hichem Henchiri, Abdelwaheb Fekih & Gilles Hanquet. (2009) Hemisynthesis of two marine cheilanthane sesterterpenes from (−)-sclareol: First enantioselective synthesis of petrosaspongiolide R. Natural Product Research 23:3, pages 256-263.
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Articles from other publishers (13)

Florian Bartels, Manuela Weber & Mathias Christmann. (2019) Synthesis of Spongidine A and D and Petrosaspongiolide L Methyl Ester Using Pyridine C–H Functionalization. Organic Letters 22:2, pages 552-555.
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Xiong Xiao, ZhongYu Xu, Qian-Ding Zeng, Xi-Bo Chen, Wen-Hao Ji, Ying Han, PeiYing Wu, Jiangmeng Ren & Bu-Bing Zeng. (2015) Construction of the Isocopalane Skeleton: Application of a Desulfinylative 1,7-Hydrogen Atom Transfer Strategy. Chemistry - A European Journal 21:23, pages 8351-8354.
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Wen-Yuan Fan, Zheng-Lin Wang, Zi-Gang Zhang, Hong-Chang Li & Wei-Ping Deng. (2011) Stereoselective synthesis of marine sesterterpenes, 16-deacetoxy-scalarafuran, (+)-scalarolide and their analogs. Tetrahedron 67:31, pages 5596-5603.
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Si-Kai Hua, Jing Wang, Xi-Bo Chen, Zhong-Yu Xu & Bu-Bing Zeng. (2011) Scalable synthesis of methyl ent-isocopalate and its derivatives. Tetrahedron 67:6, pages 1142-1144.
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Wen-Yuan Fan, Zheng-Lin Wang, Hong-Chang Li, John S. Fossey & Wei-Ping Deng. (2011) A straightforward and efficient synthetic access to biologically active marine sesterterpenoids, sesterstatins 4 and 5. Chemical Communications 47:10, pages 2961.
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P. Basabe, M. Martín, O. Bodero, A. Blanco, I.S. Marcos, D. Díez & J.G. Urones. (2010) Synthesis of (+)-makassaric acid, a protein kinase MK2 inhibitor. Tetrahedron 66:32, pages 6008-6012.
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P. Basabe, A. Blanco, O. Bodero, M. Martín, I.S. Marcos, D. Díez, F. Mollinedo & J.G. Urones. (2010) Expeditious synthesis of nitrogenated spongianes: 4-methyldecarboxyspongolactams. Tetrahedron 66:13, pages 2422-2426.
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Xiang-Jian Meng, Yang Liu, Wen-Yuan Fan, Bin Hu, Wenting Du & Wei-Ping Deng. (2009) The first synthesis of marine sesterterpene (+)-scalarolide. Tetrahedron Letters 50:35, pages 4983-4985.
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Miguel A. González. (2008) Total syntheses and synthetic studies of spongiane diterpenes. Tetrahedron 64:3, pages 445-467.
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Pilar Basabe, Olga Bodero, Isidro S. Marcos, David Diez, Mónica de Román, Araceli Blanco & Julio G. Urones. (2007) Synthesis of (+)-lagerstronolide from (+)-sclareol. Tetrahedron 63:48, pages 11838-11843.
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Pilar Basabe, Sergio Delgado, Isidro S. Marcos, David Diez, Alberto Diego, Mónica de Román, Francisca Sanz & J.G. Urones. (2007) Nor-limonoid and homoisoanticopalane lactones from methyl isoanticopalate. Tetrahedron 63:36, pages 8939-8948.
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Pilar Basabe, Alberto Diego, Sergio Delgado, David D??ez, Isidro S Marcos & Julio G Urones. (2003) Short and efficient synthesis of (+)-subersic acids. Tetrahedron 59:46, pages 9173-9177.
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P Basabe, A Gómez, I.S Marcos, D.Diez Martín, H.B Broughton & J.G Urones. (1999) Towards the synthesis of 9,11-secospongianes. Tetrahedron Letters 40:37, pages 6857-6860.
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