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Integrated Ferroelectrics
An International Journal
Volume 4, 1994 - Issue 2
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Original Articles

Defect chemistry and transport properties of Pb(Zr1/2Ti1/2)O3

M. V. Raymond Materials Research Center, Lehigh University, 5 E. Packard Ave., Bethlehem, PA, 18015, USA
&
D. M. Smyth Materials Research Center, Lehigh University, 5 E. Packard Ave., Bethlehem, PA, 18015, USA
Pages 145-154 | Received 01 Sep 1993, Published online: 19 Aug 2006

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L. A. Delimova, E. V. Guschina, V. S. Yuferev, I. V. Grekhov, D. S. Seregin, K. A. Vorotilov & A. S. Sigov. (2015) Electrophysical Properties of Integrated Ferroelectric Capacitors Based on Sol-Gel PZT Films. Ferroelectrics 484:1, pages 32-42.
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Fengxia Ma, MarkV. Raymond & DonaldM. Smyth. (2006) Hole-Trapping in ATiO3, (A = Ba, Sr, Ca). Ferroelectrics 331:1, pages 43-51.
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Eric Paton, Mark Brazier, Said Mansour & Arden Bement. (1997) A critical study of defect migration and ferroelectric fatigue in lead zirconate titanate thin film capacitors under extreme temperatures. Integrated Ferroelectrics 18:1-4, pages 29-37.
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Cheol Seong Hwang, Byoung Taek Lee, Soon Oh Park, Jin Won Kim, Hag-Ju Cho, Chang Seok Kang, Hideki Horii, Sang In Lee & Moon Yong Lee. (1996) Interface potential barrier height and leakage current behavior of Pt/(Ba, Sr)TiO3/Pt capacitors fabricated by sputtering process. Integrated Ferroelectrics 13:1-3, pages 157-177.
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D.J. Keeble, A. Krishnan, M.T. Umlor, K.G. Lynn, W.L. Warren, D. Dimos, B.A. Tuttle, R. Ramesh & E.H. Poindexter. (1995) Positron annihilation studies of vacancy related defects in ceramic and thin film Pb(Zr,Ti)O3 materials. Integrated Ferroelectrics 8:1-2, pages 121-128.
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Articles from other publishers (38)

Yuji Noguchi & Hiroki Matsuo. (2021) Ferroelectric photovoltaic tensor in visible-light-active Fe-doped BaTiO 3 single crystals . Japanese Journal of Applied Physics 60:SF, pages SFFA01.
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Wanlin Zhu, Betul Akkopru-Akgun, Jung In Yang, Charalampos Fragkiadakis, Ke Wang, Song Won Ko, Peter Mardilovich & Susan Trolier-McKinstry. (2021) Influence of graded doping on the long-term reliability of Nb-doped lead zirconate titanate films. Acta Materialia 219, pages 117251.
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Yuji NOGUCHI. (2021) Defect chemistry in perovskite ferroelectrics—History, present status, and future prospects—. Journal of the Ceramic Society of Japan 129:6, pages 271-285.
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Betul Akkopru-Akgun, Wanlin Zhu, Clive A. Randall, Michael T. Lanagan & Susan Trolier-McKinstry. (2019) Polarity dependent DC resistance degradation and electrical breakdown in Nb doped PZT films. APL Materials 7:12.
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Tsvetkov, Ivanov, Malyshkin, Sereda & Zuev. (2019) Thermoelectric Behavior of BaZr0.9Y0.1O3−d Proton Conducting Electrolyte. Membranes 9:9, pages 120.
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Dmitry S. Tsvetkov, Ivan L. Ivanov, Dmitry A. Malyshkin, Vladimir V. Sereda & Andrey Yu. Zuev. (2019) Red-Ox Energetics and Holes Trapping in Yttrium-Substituted Barium Zirconate BaZr 0.9 Y 0.1 O 2.95 . Journal of The Electrochemical Society 166:4, pages F232-F238.
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Giuliano Gregori, Rotraut Merkle & Joachim Maier. (2017) Ion conduction and redistribution at grain boundaries in oxide systems. Progress in Materials Science 89, pages 252-305.
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Nitish Kumar, Eric A. Patterson, Till Frömling & David P. Cann. (2016) Conduction Mechanisms in BaTiO 3 –Bi(Zn 1/2 Ti 1/2 )O 3 Ceramics . Journal of the American Ceramic Society 99:9, pages 3047-3054.
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D. M. Marincel, S. Jesse, A. Belianinov, M. B. Okatan, S. V. Kalinin, T. N. Jackson, C. A. Randall & S. Trolier-McKinstry. (2015) A-site stoichiometry and piezoelectric response in thin film PbZr1−xTixO3. Journal of Applied Physics 117:20.
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Christoph Slouka, Lukas Andrejs & Jürgen Fleig. (2014) Defect chemistry and transport properties of Nd-doped Pb(ZrxTi1−x)O3. Journal of Electroceramics 33:3-4, pages 221-229.
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L. Andrejs & J. Fleig. (2013) Resistance degradation in donor-doped PZT ceramic stacks with Ag/Pd electrodes: I. Phenomenology of processes. Journal of the European Ceramic Society 33:4, pages 779-794.
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S. Schaab, M. Schulz, H. Fritze, R.-A. Eichel, E. Erdem, C.H. Rüscher, S. Hummelt & T. Granzow. (2012) Influence of reducing atmosphere on the defect chemistry of lead lanthanum zirconate titanate (8/65/35). Solid State Ionics 228, pages 56-63.
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Elmar Völkl, Philipp Hillebrand & Juergen Fleig. (2011) Resistance variation in donor-doped PZT stacks with Cu inner electrodes under high field stress. Journal of Electroceramics 27:2, pages 66-77.
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Yoshiki IwazakiTatsuo SakashitaToshimasa SuzukiYouichi MizunoShinji Tsuneyuki. (2011) First-Principles Calculations of Structural Changes Induced by Oxygen Vacancies in Tetragonal Phase BaTiO<sub>3</sub>. Key Engineering Materials 485, pages 19-22.
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Robert Schafranek, Shunyi Li, Feng Chen, Wenbin Wu & Andreas Klein. (2011) PbTiO /SrTiO interface: Energy band alignment and its relation to the limits of Fermi level variation . Physical Review B 84:4.
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S. Habouti, C-H. Solterbeck, M. Es-Souni & V. Zaporojtchenko. (2008) On PbTiO3-(111)-Pt interfacial layers and their x-ray photoelectron spectroscopy signature. Journal of Applied Physics 104:10.
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Katsuya Yamamoto, Muneyasu Suzuki, Yuji Noguchi & Masaru Miyayama. (2008) High-Performance Bi 0.5 Na 0.5 TiO 3 Single Crystals Grown by High-Oxygen-Pressure Flux Method . Japanese Journal of Applied Physics 47:9S, pages 7623.
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Y. Noguchi & M. Miyayama. 2008. Handbook of Advanced Dielectric, Piezoelectric and Ferroelectric Materials. Handbook of Advanced Dielectric, Piezoelectric and Ferroelectric Materials 1006 1032 .
L. Delimova, I. Grekhov, D. Mashovets, S. Shin, J. -M. Koo, S. -P. Kim & Y. Park. (2006) A method of determining the charge trapped at the interfaces of a metal/ferroelectric/metal thin-film structure. Physics of the Solid State 48:6, pages 1182-1185.
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L. A. Delimova, I. V. Grekhov, D. V. Mashovets, S. E. Tyaginov, Sangmin Shin, June-Moo Koo, Suk-Pil Kim & Youngsoo Park. (2005) Transient-current measurement of the trap charge density at interfaces of a thin-film metal∕ferroelectric∕metal structure. Applied Physics Letters 87:19.
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Lyuba A. Delimova, I. V. Grekhov, D. V. Mashovets, Sangmin Shin, June-Mo Koo, Suk-Pil Kim, Youngsoo Park, V. P. Afanasjev, P. V. Afanasjev & A. A. Petrov. (2011) Trap Charge Density at Interfaces of MOCVD Pt(Ir)/PZT/Ir(Ti/SiO 2 /Si) Structures . MRS Proceedings 902.
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H.-I. Yoo & K. D. Becker. (2005) Effect of hole-trapping on mass/charge transport properties in acceptor-doped BaTiO3. Physical Chemistry Chemical Physics 7:9, pages 2068.
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Kyoung Bo Han, Cheol Su Kim, Chang Hoon Jeon, Hee Sauk Jhon & Sang Yeol Lee. (2004) Hydrogen post-annealing effect of the ferroelectric properties of (Pb0.72La0.28)Ti0.93O3 films fabricated by pulsed laser deposition. Materials Science and Engineering: B 109:1-3, pages 170-173.
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S. S. N. Bharadwaja, P. Victor, P. Venkateswarulu & S. B. Krupanidhi. (2002) ac transport studies of La-modified antiferroelectric lead zirconate thin films. Physical Review B 65:17.
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D. P. Chu, B. M. McGregor, P. Migliorato, C. Durkan, M. E. Welland, K. Hasegawa & T. Shimoda. (2001) Temperature dependence of the ohmic conductivity and activation energy of Pb1+y(Zr0.3Ti0.7)O3 thin films. Applied Physics Letters 79:4, pages 518-520.
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Wanda C Las, Priscila D Spagnol, Maria A Zaghete & Mario Cilense. (2001) Electrical characterization of lead zirconate titanate prepared by organic solution route. Ceramics International 27:4, pages 367-372.
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S. Aggarwal, S. R. Perusse, C. J. Kerr, R. Ramesh, D. B. Romero, J. T. EvansJr.Jr., L. Boyer & G. Velasquez. (2000) Recovery of forming gas damaged Pb(Nb, Zr, Ti)O3 capacitors. Applied Physics Letters 76:7, pages 918-920.
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B. Nagaraj, S. Aggarwal, T. K. Song, T. Sawhney & R. Ramesh. (1999) Leakage current mechanisms in lead-based thin-film ferroelectric capacitors. Physical Review B 59:24, pages 16022-16027.
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Cheol Seong Hwang, Byoung Taek Lee, Chang Seok Kang, Ki Hoon Lee, Hag-Ju Cho, Horii Hideki, Wan Don Kim, Sang In Lee & Moon Yong Lee. (1999) Depletion layer thickness and Schottky type carrier injection at the interface between Pt electrodes and (Ba, Sr)TiO3 thin films. Journal of Applied Physics 85:1, pages 287-295.
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Sanjeev AggarwalR. Ramesh. (1998) POINT DEFECT CHEMISTRY OF METAL OXIDE HETEROSTRUCTURES. Annual Review of Materials Science 28:1, pages 463-499.
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Husam N. Al‐Shareef & Duane Dimos. (2005) Leakage and Reliability Characteristics of Lead Zirconate Titanate Thin‐Film Capacitors. Journal of the American Ceramic Society 80:12, pages 3127-3132.
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Donald M Smyth. (1996) Defect structure in perovskite titanates. Current Opinion in Solid State and Materials Science 1:5, pages 692-697.
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M.V. Raymond & D.M. Smyth. (1996) Defects and charge transport in perovskite ferroelectrics. Journal of Physics and Chemistry of Solids 57:10, pages 1507-1511.
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E.N. Paton, S.A. Mansour & A. Bement. (1996) Temperature dependent fatigue in ferroelectric PZT thin films. Temperature dependent fatigue in ferroelectric PZT thin films.
H. Al-Shareef & D. Dimes. (1996) Accelerated life-time testing and resistance degradation of thin-film decoupling capacitors. Accelerated life-time testing and resistance degradation of thin-film decoupling capacitors.
J. Robertson, W. L. Warren & B. A. Tuttle. (1995) Band states and shallow hole traps in Pb(Zr,Ti)O 3 ferroelectrics . Journal of Applied Physics 77:8, pages 3975-3980.
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Veerabhadrarao Bheemineni, Edward K. Chang, Misri Lal, Martin P. Harmer & Donald M. Smyth. (2005) Suppression of Acceptor Solubilities in BaTiO 3 Densified in Highly Reducing Atmospheres . Journal of the American Ceramic Society 77:12, pages 3173-3176.
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