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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Volume 275, 1996 - Issue 1
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Original Articles

Binary Mixtures of n-Alkanes. Phase Diagram Generalization: Intermediate Solid Solutions, Rotator Phases

M. Dirand Ecole Nationale Supérieure des Industries Chimiques, Laboratoire de Thermodynamique Chimique et Appliquée 1, rue Grandville-BP 451, F 54001, Nancy Cédex
,
Z. Achour Ecole Nationale Supérieure des Industries Chimiques, Laboratoire de Thermodynamique Chimique et Appliquée 1, rue Grandville-BP 451, F 54001, Nancy Cédex
,
B. Jouti Ecole Nationale Supérieure des Industries Chimiques, Laboratoire de Thermodynamique Chimique et Appliquée 1, rue Grandville-BP 451, F 54001, Nancy Cédex
,
A. Sabour Ecole Nationale Supérieure des Industries Chimiques, Laboratoire de Thermodynamique Chimique et Appliquée 1, rue Grandville-BP 451, F 54001, Nancy Cédex
&
J.-C. Gachon Laboratoire de Chimie du Solide Minéral, U.R.A.-C.N.R.S. n° 158, Service Themodynamique Métallurgique, Domaine Scientifique Victor Grignard, Université Henri Poincaré, Nancy I, BP, 239-F54506, Vandoeuvre Les Nancy Cédex
Pages 293-304 | Received 19 May 1995, Published online: 24 Sep 2006

Citations (51)

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M. Pierre, D. Petitjean, M. Bouroukba, M. Dirand, D. André & Y. Jolivet. (2003) Isopleth Sections of the Systems: Commercial Multi-alkane Product— -Eicosane or -Pentacontane. Petroleum Science and Technology 21:3-4, pages 333-344.
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V. Chevallier, A.J. Briard, D. Petitjean, N. Hubert, M. Bouroukba & M. Dirand. (2000) Influence of the Distribution General Shape of n-Alkane Molar Concentrations on the Structural State of Multi-Alkane Mixtures. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 350:1, pages 273-291.
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H. Nouar, D. Petitjean, M. Bouroukba & M. Dirand. (1999) Isothermal Sections of Ternary Mixtures: n-docosane + n-tricosane + n-tetracosane. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 326:1, pages 381-394.
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H. Nouar, M. Bouroukba, D. Petitjean & M. Dirand. (1998) Ternary Phase Diagram n-Docosane: n-Tricosane: n-Tetracosane Molecular Alloys at 293 K. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 309:1, pages 273-282.
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Xupeng Wang, Shiyu Li, Haobo Bai & Chang Liu. (2019) New Predictive Nonrandom Two Liquid Equation for Solid–Liquid Phase Equilibrium in n -Alkanes Mixture with Multiple Solid Solutions . Industrial & Engineering Chemistry Research 58:39, pages 18411-18421.
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Diana Cholakova & Nikolai Denkov. (2019) Rotator phases in alkane systems: In bulk, surface layers and micro/nano-confinements. Advances in Colloid and Interface Science 269, pages 7-42.
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Prabir K. Mukherjee. (2015) Phase transitions among the rotator phases of the normal alkanes: A review. Physics Reports 588, pages 1-54.
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Rainer Schmid-Fetzer. (2014) Phase Diagrams: The Beginning of Wisdom. Journal of Phase Equilibria and Diffusion 35:6, pages 735-760.
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B. Zgardzińska & M. Gorgol. (2014) Influence of Pressure on the Size of Free Volumes in Some Waxes. Acta Physica Polonica A 125:3, pages 816-820.
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Xia Gao, Dongsheng Fu, Yunlan Su, Yong Zhou & Dujin Wang. (2013) Phase Transition Behavior of a Series of Even n -Alkane C n /C n +2 Mixtures Confined in Microcapsules: From Total Miscibility to Phase Separation Determined by Confinement Geometry and Repulsion Energy . The Journal of Physical Chemistry B 117:44, pages 13914-13921.
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D. Petitjean, J. F. Schmitt, V. Laine, C. Cunat & M. Dirand. (2010) Influence of the Alkane Molar Distribution on the Physical Properties of Synthetic Waxes. Energy & Fuels 24:5, pages 3028-3033.
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D. Petitjean, J. F. Schmitt, V. Laine, M. Bouroukba, C. Cunat & M. Dirand. (2007) Presence of Isoalkanes in Waxes and Their Influence on Their Physical Properties. Energy & Fuels 22:2, pages 697-701.
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Kazuki Sada, Katsunari Inoue, Tomoyuki Tanaka, Attila Epergyes, Akira Tanaka, Norimitsu Tohnai, Akikazu Matsumoto & Mikiji Miyata. (2005) Multicomponent Organic Alloys Based on Organic Layered Crystals. Angewandte Chemie International Edition 44:43, pages 7059-7062.
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Kazuki Sada, Katsunari Inoue, Tomoyuki Tanaka, Attila Epergyes, Akira Tanaka, Norimitsu Tohnai, Akikazu Matsumoto & Mikiji Miyata. (2005) Multicomponent Organic Alloys Based on Organic Layered Crystals. Angewandte Chemie 117:43, pages 7221-7224.
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Naoko Miyamoto, Junko Morikawa & Toshimasa Hashimoto. (2005) Thermal diffusivity of binary mixture of n-tricosane and n-tetracosane by Fourier transform temperature wave analysis. Thermochimica Acta 431:1-2, pages 62-67.
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H.A.J. Oonk & J.Ll. Tamarit. 2005. Measurement of the Thermodynamic Properties ofMultiple Phases. Measurement of the Thermodynamic Properties ofMultiple Phases 201 274 .
Anne-Julie Briard, Mohammed Bouroukba, D. Petitjean & Michel Dirand. (2004) Thermodynamic Properties of Multialkane Synthetic and Real Petroleum Mixtures. Journal of Chemical & Engineering Data 49:5, pages 1201-1213.
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Anne-Julie Briard, Mohammed Bouroukba & Michel Dirand. (2004) Estimation of the Enthalpy of Formation of Multialkane Synthetic Mixtures: Measurement by Mixing Calorimetry and Modeling by the UNIQUAC Model. Journal of Chemical & Engineering Data 49:4, pages 899-906.
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D. Petitjean, M. Pierre, M. Bouroukba, M. Dirand, D. Andre & Y. Jolivet. (2004) Isopleth section of the system: n-eicosane and a multi-paraffinic wax. Fuel 83:7-8, pages 1079-1084.
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R. Rakotosaona, M. Bouroukba, D. Petitjean, N. Hubert, J.C. Moise & M. Dirand. (2004) Binary phase diagram (C14+C25) and isopleth (C14+wax): comparison of solubility of n-pentacosane and multiparaffinic wax in n-tetradecane. Fuel 83:7-8, pages 851-857.
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P.M. Ghogomu, R. Rakotosaona, M. Bouroukba, D. Petitjean, N. Hubert & M. Dirand. (2004) Isobaric pseudo-binary cross section of mixtures (naphthalene+multiparaffinic wax). Fuel 83:7-8, pages 951-956.
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Bruno Predel, Michael Hoch & Monte PoolBruno Predel, Michael Hoch & Monte Pool. 2004. Phase Diagrams and Heterogeneous Equilibria. Phase Diagrams and Heterogeneous Equilibria 331 339 .
Amy B. Herhold, H. E. KingJr.Jr. & E. B. Sirota. (2002) A vanishing nucleation barrier for the n-alkane rotator-to-crystal transformation. The Journal of Chemical Physics 116:20, pages 9036-9050.
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Michel Dirand, Mohammed Bouroukba, Virginie Chevallier, Dominique Petitjean, Emmanuel Behar & Véronique Ruffier-Meray. (2002) Normal Alkanes, Multialkane Synthetic Model Mixtures, and Real Petroleum Waxes:  Crystallographic Structures, Thermodynamic Properties, and Crystallization. Journal of Chemical & Engineering Data 47:2, pages 115-143.
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D. Petitjean, M. Pierre, P. Goghomu, M. Bouroukba & M. Dirand. (2002) Structural behaviour of molecular alloys: n -pentacontane ( n -C 50 H 102 )– n -pentacosane ( n -C 25 H 52 ); n -pentacontane ( n -C 50 H 102 )– n -tricosane ( n -C 23 H 48 ) at room temperature. Polymer 43:2, pages 345-349.
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D. Petitjean, M. Pierre, N. Hubert, M. Bouroukba & M. Dirand. (2001) Influence of addition of pure components on the structural state of multi-n-alkane mixtures. Fuel 80:14, pages 2007-2011.
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V Chevallier, M Bouroukba, D Petitjean, M Dirand, J Pauly, J.L Daridon & V Ruffier-Meray. (2000) Crystallization of a multiparaffinic wax in normal tetradecane. Fuel 79:14, pages 1743-1750.
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Irena Paunovic & Anil K Mehrotra. (2000) Liquid–solid phase transformation of C16H34, C28H58 and C41H84 and their binary and ternary mixtures. Thermochimica Acta 356:1-2, pages 27-38.
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T. Yamamoto, S. Matsumoto & M. Hirose. (2000) A Monte Carlo study of the pattern formation during transitions in n -alkane crystals . The Journal of Chemical Physics 112:17, pages 7627-7633.
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E. B. Sirota. (2000) Supercooling and transient phase induced nucleation in n -alkane solutions . The Journal of Chemical Physics 112:1, pages 492-500.
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Fazil Rajabalee, Valérie Métivaud, Denise Mondieig, Yvette Haget & Harry A. J. Oonk. (1999) Thermodynamic Analysis of Solid−Solid and Solid−Liquid Equilibria in Binary Systems Composed of n -Alkanes: Application to the System Tricosane (C 23 H 48 ) + Pentacosane (C 25 H 52 ) . Chemistry of Materials 11:10, pages 2788-2795.
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V. Chevallier, D. Petitjean, V. Ruffier-Meray & M. Dirand. (1999) Correlations between the crystalline long c -parameter and the number of carbon atoms of pure n -alkanes. Polymer 40:21, pages 5953-5956.
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Elise Provost, Daniel Balesdent, Mohammed Bouroukba, Dominique Petitjean, Michel Dirand & Véronique Ruffier-Meray. (1999) Phase diagram ofn-hexacosane andn-octacosane: experimental determination and calculation. The Journal of Chemical Thermodynamics 31:9, pages 1135-1149.
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F. Rajabalee, V. Métivaud, D. Mondieig, Y. Haget & M. A. Cuevas-Diarte. (2011) New insights on the crystalline forms in binary systems of n -alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane . Journal of Materials Research 14:6, pages 2644-2654.
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Douglas L. Dorset & Robert G. Snyder. (1999) Phase Separation of a Metastable Three-Component n -Paraffin Solid Solution . The Journal of Physical Chemistry B 103:16, pages 3282-3286.
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V. Chevallier, E. Provost, J.B. Bourdet, M. Bouroukba, D. Petitjean & M. Dirand. (1999) Mixtures of numerous different n-alkanes: 1. Structural studies by X-ray diffraction at room temperature—Correlation between the crystallographic long c parameter and the average composition of multi-alkane phases. Polymer 40:8, pages 2121-2128.
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V. Chevallier, D. Petitjean, M. Bouroukba & M. Dirand. (1999) Mixtures of numerous different n-alkanes: 2. Studies by X-ray diffraction and differential thermal analyses with increasing temperature. Polymer 40:8, pages 2129-2137.
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Valérie Metivaud, Fazil Rajabalee, Denise Mondieig, Yvette Haget & Miguel Angel Cuevas-Diarte. (1998) Solid−Solid and Solid−Liquid Equilibria in the Heneicosane−Docosane Binary System. Chemistry of Materials 11:1, pages 117-122.
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M. Dirand, V. Chevallier, E. Provost, M. Bouroukba & D. Petitjean. (1998) Multicomponent paraffin waxes and petroleum solid deposits: structural and thermodynamic state. Fuel 77:12, pages 1253-1260.
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Elise Provost, Virginie Chevallier, Mohammed Bouroukba, Dominique Petitjean & Michel Dirand. (1998) Solubility of Some n -Alkanes (C 23 , C 25 , C 26 , C 28 ) in Heptane, Methylcyclohexane, and Toluene . Journal of Chemical & Engineering Data 43:5, pages 745-749.
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Hu Gang, Oleg Gang, Henry H. Shao, X. Z. Wu, Jay Patel, C. S. Hsu, M. Deutsch, B. M. Ocko & E. B. Sirota. (1998) Rotator Phases and Surface Crystallization in α-Eicosene. The Journal of Physical Chemistry B 102:15, pages 2754-2758.
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Z. Achour, A. Sabour, M. Dirand & M. Hoch. (2014) Thermodynamic Properties of the n-Alkanes C19H40 to C26H54 and Their Binary Phase Diagrams. Journal of Thermal Analysis and Calorimetry 51:2, pages 477-488.
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Paul Mingo Ghogomu, Mohammed Bouroukba, Jacques Dellacherie, Daniel Balesdent & Michel Dirand. (1997) On the ideality of liquid mixtures of long-chain n-alkanes. Thermochimica Acta 306:1-2, pages 69-71.
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P.M. Ghogomu, M. Bouroukba, J. Dellacherie, D. Balesdent & M. Dirand. (1997) Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n-alkanes. Thermochimica Acta 302:1-2, pages 159-164.
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P.M. Ghogomu, M. Bouroukba, J. Dellacherie, D. Balesdent & M. Dirand. (1997) Excess thermodynamic properties of some binary solutions of ethylbenzene + n-alkanes. Thermochimica Acta 302:1-2, pages 151-158.
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H. Nouar, D. Petitjean, J.B. Bourdet & M. Dirand. (1997) Structural evolutions of n-docosane and n-tricosane mixtures at room temperature. Journal of Molecular Structure 415:3, pages 277-284.
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E. B. Sirota. (1997) Remarks Concerning the Relation between Rotator Phases of Bulk n -Alkanes and Those of Langmuir Monolayers of Alkyl-Chain Surfactants on Water . Langmuir 13:14, pages 3849-3859.
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P.M. Ghogomu, L. Schuffenecker, J. Dellacherie, M. Dirand & D. Balesdent. (1997) Dissolution of some normal alkanes in ethylbenzene: deduction of the enthalpy of mixing two n-alkanes in the solid state. Thermochimica Acta 294:2, pages 147-155.
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Hakima Nouar, Dominique Petitjean, Jean-Bernard Bourdet, Mohammed Bouroubka & Michel Dirand. (1997) Diagram of the n-tricosane-n-tetracosane mixtures: Corrections. Thermochimica Acta 293:1-2, pages 87-92.
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B. Jouti, E. Provost, D. Petitjean, M. Bouroukba & M. Dirand. (1996) Phase diagram of n-heneicosane and n-tricosane molecular alloys. Journal of Molecular Structure 382:1, pages 49-56.
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