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Original Articles

Magnetic Materials Containing the Dicyanamide Anion, {N(Cn)2}

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Pages 693-702 | Published online: 24 Sep 2006

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (3)

Dasarath Mal, Rupam Sen, Chandan Adhikary, Yoshitaro Miyashita, Ken-Ichi Okamoto, Ashis Bhattacharjee, Philipp Gütlich & Subratanath Koner. (2008) Synthesis, X-ray crystal structure and magnetic study of a μ 1,5-dca bridged ferromagnetic dimeric copper(II) complex. Journal of Coordination Chemistry 61:21, pages 3486-3492.
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Mohamedally Kurmoo. (2000) Rutile and Layered Magnets Based on Transition Metal Complexes Containing Dicyanamide and Tricyanomethanide. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 342:1, pages 167-176.
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ChristopherJ. Nuttall, Taishi Takenobu, Yoshihiro Iwasa & Mohamedally Kurmoo. (2000) Pressure Dependence of the Magnetization of MII (N(CN)2)2: Mechanism for the Long Range Magnetic Ordering. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 343:1, pages 227-234.
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Articles from other publishers (45)

Yuh-Shan Ho & Hui-Zhen Fu. (2016) Mapping of metal-organic frameworks publications: A bibliometric analysis. Inorganic Chemistry Communications 73, pages 174-182.
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Yusuke Yoshida, Katsuya Inoue, Koichi Kikuchi & Mohamedally Kurmoo. (2016) Biomimetic Transformation by a Crystal of a Chiral Mn II –Cr III Ferrimagnetic Prussian Blue Analogue . Chemistry of Materials 28:19, pages 7029-7038.
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P. A. Quintero, D. Rajan, M. K. Peprah, T. V. Brinzari, R. S. Fishman, D. R. Talham & M. W. Meisel. (2015) Pressure-induced enhancement of the magnetic anisotropy in . Physical Review B 91:1.
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Jamie L. Manson, Craig M. Brown, Qing Huang, John A. Schlueter, Tom Lancaster, Stephen J. Blundell, John Singleton, Jeffrey W. Lynn & Francis L. Pratt. (2013) Mn(dca)2(o-phen) {dca=dicyanamide; o-phen=1,10-phenanthroline}: Long-range magnetic order in a low-dimensional Mn-dca polymer. Polyhedron 52, pages 679-688.
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Helena Prima-Garcia, Eugenio Coronado, Juan P Prieto-Ruiz & Francisco M Romero. (2012) Tailoring magnetic properties of electrodeposited thin films of the molecule-based magnet Cr5.5(CN)12 11.5H2O. Nanoscale Research Letters 7:1.
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Dasarath Mal, Rupam Sen, Eva Rentschler, Ken-ichi Okamoto, Yoshitaro Miyashita & Subratanath Koner. (2012) Fully interlocked three-dimensional molecular scaffolding: Synthesis, X-ray structure, magnetic and nitrogen sorption study. Inorganica Chimica Acta 385, pages 27-30.
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Eugenio Coronado, Magdalena Makarewicz, Juan P. Prieto-Ruiz, Helena Prima-García & Francisco M. Romero. (2011) Magneto-Optical Properties of Electrodeposited Thin Films of the Molecule-Based Magnet Cr5.5(CN)12·11.5H2O. Advanced Materials 23:37, pages 4323-4326.
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Dasarath Mal, Rupam Sen, Georgina M. Rosair & Subratanath Koner. (2011) Synthesis, X-ray Crystal Structure and Magnetic Study of a ?1,5-dca Bridged Dimeric Copper(II) Complex. Journal of Chemical Crystallography 41:7, pages 1018-1022.
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Mario Wriedt & Christian Näther. (2011) Directed synthesis of μ-1,3,5 bridged dicyanamides by thermal decomposition of μ-1,5 bridged precursor compounds. Dalton Trans. 40:4, pages 886-898.
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Qi-Ji Zhou, Xue-Jun Yao, Lan-Fang Hao, Yan Ouyang, Jing-Yuan Xu, Cheng-Zhi Xie & Jian-Shi Lou. (2010) Synthesis, Crystal Structure, and Magnetic Properties of a New 2D Copper(II) Polymer Constructed by μ1,5-Dicyanamide and Sulfonate Anion Bridges. Zeitschrift für anorganische und allgemeine Chemie 636:13-14, pages 2487-2491.
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Rupam Sen, Ashis Bhattacharjee, Philipp Gütlich, Yoshitaro Miyashita, Ken-Ichi Okamoto & Subratanath Koner. (2009) Structural and magnetic diversity in metal-dicyanamido polymer moieties: Paramagnetic and antiferromagnetic 1D chain compound and weakly ferromagnetic 2D motif. Inorganica Chimica Acta 362:13, pages 4663-4670.
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C. Yuste, D. Armentano, N. Marino, L. Cañadillas-Delgado, F. S. Delgado, C. Ruiz-Pérez, D. P. Rillema, F. Lloret & M. Julve. (2008) Synthesis, crystal structures and magnetic properties of tricyanomethanide-containing copper(II) complexes. Dalton Transactions:12, pages 1583.
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Dasarath Mal, Rupam Sen, Chandan Adhikary, Ashis Bhattacharjee, Philipp Gütlich, Yoshitaro Miyashita, Ken-Ichi Okamoto & Subratanath Koner. (2008) Synthesis, X-ray crystal structure and magnetic study of a dicyanamido bridged 1D chain nickel(II) complex. Inorganica Chimica Acta 361:1, pages 183-187.
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Dasarath Mal, Subratanath Koner, Jean-Pierre Tuchagues & Georgina M. Rosair. (2007) Encapsulation of [Mn(bpy)3]2+ cations in 2D [Mn(dca)3]? sheet: Synthesis, X-ray structure and EPR study. Inorganica Chimica Acta 360:11, pages 3575-3580.
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John A. Schlueter, Jamie L. Manson, Kylee A. Hyzer & Urs Geiser. (2007) Novel anionic dicyanamidocuprate(II) structural motifs through cation templation. Polyhedron 26:9-11, pages 2264-2272.
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Jamie L. Manson, John A. Schlueter & Cara L. Nygren. (2007) Mn(dca)2(pym)2 and Mn(dca)2(pym)(H2O) {dca = dicyanamide; pym = pyrimidine}: New coordination polymers exhibiting 1- and 2-D topologies. Dalton Transactions:6, pages 646.
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L. Zhu, K.L. Yao & Z.L. Liu. (2006) First-principle calculation on the electronic structure of the molecule-based ferromagnet Co[P(CN)2]2 and M[N(CN)2]2 (M=Co, Ni). Chemical Physics Letters 424:1-3, pages 209-213.
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F.X. Zu & S.Z. Xia. (2006) Ab initio study of the electronic structure of the molecule-based ferromagnet Co[N(CN)2]2. Physics Letters A 349:5, pages 384-387.
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F. Thétiot, S. Triki, J. Sala Pala & C.J. Gómez-García. (2005) Polynitrile anions as ligands: synthesis, structure and magnetic properties of a new three-dimensional coordination polymer with the 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide (tcpd2−) bridging ligand. Synthetic Metals 153:1-3, pages 481-484.
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John A. Schlueter, Jamie L. Manson & Urs Geiser. (2005) Structural and Magnetic Diversity in Tetraalkylammonium Salts of Anionic M [N(CN) 2 ] 3 - ( M = Mn and Ni) Three-Dimensional Coordination Polymers . Inorganic Chemistry 44:9, pages 3194-3202.
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Jamie L. Manson. 2004. Magnetism: Molecules to Materials. Magnetism: Molecules to Materials 71 104 .
Jamie L. Manson & John A. Schlueter. (2004) Crystal structure and linear chain antiferromagnetism in Mn(tricyanomethanide)2(4,4′-bipyridine)2. Inorganica Chimica Acta 357:13, pages 3975-3979.
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José Carranza, Jorunn Sletten, Francesc Lloret & Miguel Julve. (2004) Structural analysis and magnetic properties of the copper(II) dicyanamide complexes [Cu2(dmphen)2(dca)4], [Cu(dmphen)(dca)(NO3)] and [Cu(4,4′-dmbpy)(H2O)(dca)2] (dca=dicyanamide; dmphen=2,9-dimethyl-1,10-phenanthroline; 4,4′-dmbpy=4,4′-dimethyl-2,2′-bipyridine). Inorganica Chimica Acta 357:11, pages 3304-3316.
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S J Blundell & F L Pratt. (2004) Organic and molecular magnets. Journal of Physics: Condensed Matter 16:24, pages R771-R828.
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Mohammad Sayaduzzaman, Mao Katsuhara, Hirotada Hoshino, Tadashi Kawamoto & Takehiko Mori. (2004) Alloyed transition‐metal complexes of tricyanomethide (tcm), [Mn 1− x Co x (tcm) 2 ] . Applied Organometallic Chemistry 18:4, pages 176-180.
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Enrique Colacio, Ikram Ben Maimoun, Raikko Kivekäs, Reijo Sillanpää & José Suárez-Varela. (2004) Two polymorphs Ni(II) complexes containing the dicyanamide ligand: syntheses, structures and magnetic properties of {[Ni(meso-CTH)(μ1,5-dca)]ClO4}n and [Ni(meso-CTH)][Ni(meso-CTH)(dca)2](ClO4)2 (dca=dicyanamide; CTH=meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraaza cyclotetradecane). Inorganica Chimica Acta 357:5, pages 1465-1470.
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Stuart R Batten & Keith S Murray. (2003) Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide. Coordination Chemistry Reviews 246:1-2, pages 103-130.
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Franck Thétiot, Smaı̈l Triki & Jean Sala Pala. (2003) Polynitriles as ligands: new coordination polymers with the 1,1,3,3-tetracyano-2-ethoxypropenide (tcnp − ) bridging ligand. Polyhedron 22:14-17, pages 1837-1843.
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Franck Thétiot, Smaı̈l Triki, Jean Sala Pala & Stéphane Golhen. (2003) Molecular assemblies based on tricyanomethanide units and copper(II) ions. Inorganica Chimica Acta 350, pages 314-320.
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Jamie L. Manson, Jiyeong Gu, John A. Schlueter & H.-Hau Wang. (2003) Structures and Magnetic Behavior of 1-, 2-, and 3D Coordination Polymers in the Cu(II)−Dicyanamide−Pyrimidine Family. Inorganic Chemistry 42:12, pages 3950-3955.
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Alexandros Lappas, Andrew S. Wills, Mark A. Green, Kosmas Prassides & Mohamedally Kurmoo. (2003) Magnetic ordering in the rutile molecular magnets Co, Fe, Mn, and . Physical Review B 67:14.
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Enrique ColacioFrancesc LloretIkram Ben MaimounRaikko KivekäsReijo SillanpääJosé Suárez-Varela. (2003) A New Type of Anionic Metal Dicyanamide Extended Networks through [Cu(N 4 -macrocycle)] 2+ Cation Templation. Structure and Magnetic Properties . Inorganic Chemistry 42:8, pages 2720-2724.
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M. R. Pederson, A. Y. Liu, Tunna Baruah, E. Z. Kurmaev, A. Moewes, S. Chiuzbăian, M. Neumann, C. R. Kmety, K. L. Stevenson & D. Ederer. (2002) Electronic structure of the molecule-based magnet from theory and experiment . Physical Review B 66:1.
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Carmen R Kmety, Jamie L Manson, S McCall, J.E Crow, Kenneth L Stevenson & Arthur J Epstein. (2002) Low-temperature specific heat of the molecule-based magnet M[N(CN)2]2 (M=Co, Ni, Cu, Zn) series. Journal of Magnetism and Magnetic Materials 248:1, pages 52-61.
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Hitoshi Kumagai, Katsuya Inoue & Mohamedally Kurmoo. (2002) Self-Organized Metallo-Helicates and -Ladder with 2,2′-Biphenyldicarboxylate (C 14 H 8 O 4 ) 2- : Synthesis, Crystal Structures, and Magnetic Properties . Bulletin of the Chemical Society of Japan 75:6, pages 1283-1289.
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Eugenio Coronado, José R Galán-Mascarós, Carlos J Gómez-Garcı́a & José M Martı́nez-Agudo. (2001) Tuning the magnetic properties in the layered molecular based magnets A[FeIIRuxIIIM1−xIII(ox)3] (MIII=Cr or Fe; ox=oxalate; A=organic or organometallic cation). Synthetic Metals 122:3, pages 501-507.
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Paul Jensen, Stuart R. Batten, Boujemaa Moubaraki & Keith S. Murray. (2001) Synthesis, Structural Isomerism, and Magnetism of the Coordination Polymers [M(dca)2pyz], M=Mn, Fe, Co, Ni and Zn, dca=Dicyanamide (N(CN) −2), and pyz=Pyrazine. Journal of Solid State Chemistry 159:2, pages 352-361.
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Mohamedally Kurmoo, Hitoshi Kumagai, Mark A. Green, Brendon W. Lovett, Stephen J. Blundell, Arzhang Ardavan & John Singleton. (2001) Two Modifications of Layered Cobaltous Terephthalate: Crystal Structures and Magnetic Properties. Journal of Solid State Chemistry 159:2, pages 343-351.
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Jamie L. Manson, John A. Schlueter, Urs Geiser, Matthew B. Stone & Daniel H. Reich. (2001) Crystal structures and magnetic properties of Mn[N(CN)2]2L {L=2,5-dimethylpyrazine and aminopyrazine}. Polyhedron 20:11-14, pages 1423-1429.
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Th Jestädt, M Kurmoo, S J Blundell, F L Pratt, C J Kepert, K Prassides, B W Lovett, I M Marshall, A Husmann, K H Chow, R M Valladares, C M Brown & A Lappas. (2001) Muon-spin-rotation and magnetization study of metal-organic magnets based on the dicyanamide anion. Journal of Physics: Condensed Matter 13:10, pages 2263-2270.
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Jamie L. Manson, Carmen R. Kmety, Fernando Palacio, Arthur J. Epstein & Joel S. Miller. (2001) Low-Field Remanent Magnetization in the Weak Ferromagnet Mn[N(CN) 2 ] 2 . Evidence for Spin-Flop Behavior . Chemistry of Materials 13:3, pages 1068-1073.
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Carlos Kremer, Cecilia Melián, Julia Torres, Marı́a P Juanicó, Claudia Lamas, Horacio Pezaroglo, Eduardo Manta, Herbert Schumann, Joachim Pickardt, Frank Girgsdies, Oscar N Ventura & Francesc Lloret. (2001) Synthesis, structure and magnetic properties of Mn(II) and Cu(II) complexes with the dicyano-acetic acid methyl ester anion. Inorganica Chimica Acta 314:1-2, pages 83-90.
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Jamie L. MansonQing-zhen HuangJeffrey W. LynnHyun-Joo KooMyung-Hwan WhangboRodney BatemanTakeo OtsukaNobuo WadaDimitri N. ArgyriouJoel S. Miller. (2000) Long-Range Magnetic Order in Mn[N(CN) 2 ] 2 (pyz) {pyz = pyrazine}. Susceptibility, Magnetization, Specific Heat, and Neutron Diffraction Measurements and Electronic Structure Calculations . Journal of the American Chemical Society 123:1, pages 162-172.
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Carmen R. Kmety, Qingzhen Huang, Jeffrey W. Lynn, Ross W. Erwin, Jamie L. Manson, S. McCall, J. E. Crow, Kenneth L. Stevenson, Joel S. Miller & Arthur J. Epstein. (2000) Noncollinear antiferromagnetic structure of the molecule-based magnet . Physical Review B 62:9, pages 5576-5588.
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Mohamedally Kurmoo. (1999) Hard Magnets Based on Layered Cobalt Hydroxide:  The Importance of Dipolar Interaction for Long-Range Magnetic Ordering. Chemistry of Materials 11:11, pages 3370-3378.
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