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Journal of Macromolecular Science, Part A
Pure and Applied Chemistry
Volume 43, 2006 - Issue 7
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Original Articles

Controlled Free‐Radical Copolymerization Kinetics of Styrene and Divinylbenzene by Bimolecular NMRP using TEMPO and Dibenzoyl Peroxide

Ellen Tuinman Institute for Polymer Research (IPR), Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
,
Neil T. McManus Institute for Polymer Research (IPR), Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
,
Martha Roa‐Luna Departamento de Ingeniería Química, Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Conjunto E, Ciudad Universitaria, México, D.F., México
,
Eduardo Vivaldo‐Lima† Institute for Polymer Research (IPR), Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada; Departamento de Ingeniería Química, Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Conjunto E, Ciudad Universitaria, México, D.F., MéxicoCorrespondence[email protected]
,
Liliane M. F. Lona Universidade Estadual de Campinas, Faculdade de Engenharia Química, Departamento de Processos Químicos, Campinas, São Paulo, Brazil
&
Alexander Penlidis Institute for Polymer Research (IPR), Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, CanadaCorrespondence[email protected]
Pages 995-1011 | Received 01 Jan 2006, Accepted 01 Feb 2006, Published online: 17 Dec 2007

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Martha Roa‐Luna, Afsaneh Nabifar, Martha Patricia Díaz‐Barber, Neil T. Mcmanus, Eduardo Vivaldo‐Lima, LilianeM.F. Lona & Alexander Penlidis. (2007) Another Perspective on the Nitroxide Mediated Radical Polymerization (NMRP) of Styrene Using 2,2,6,6‐Tetramethyl‐1‐piperidinyloxy (TEMPO) and Dibenzoyl Peroxide (BPO). Journal of Macromolecular Science, Part A 44:3, pages 337-349.
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Martha Roa‐Luna, Martha Patricia Díaz‐barber, Eduardo Vivaldo‐Lima, LilianeM.F. Lona, Neil T. McManus & Alexander Penlidis. (2007) Assessing the Importance of Diffusion‐Controlled Effects on Polymerization Rate and Molecular Weight Development in Nitroxide‐Mediated Radical Polymerization of Styrene. Journal of Macromolecular Science, Part A 44:2, pages 193-203.
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Articles from other publishers (25)

Gabriel Jaramillo-Soto, Samuel Alejandro Sarracino-Silva & Eduardo Vivaldo-Lima. (2022) Kinetics of Polymer Network Formation by Nitroxide-Mediated Radical Copolymerization of Styrene/Divinylbenzene in Supercritical Carbon Dioxide. Processes 10:11, pages 2386.
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Sharmaine B. Luk, Lorena A. Azevedo & Milan Maric. (2021) Reversible deactivation radical polymerization of bio-based dienes. Reactive and Functional Polymers 162, pages 104871.
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Milan Marić. (2021) History of nitroxide mediated polymerization in Canada. The Canadian Journal of Chemical Engineering 99:4, pages 832-852.
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R I Komendant, E O Perepelitsina & S A Kurochkin. (2019) Influence of the content of n-butanol on the critical conversion of gel formation during “living” three-dimensional radical co-polymerization of styrene and divinylbenzene. IOP Conference Series: Materials Science and Engineering 525, pages 012025.
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Xiao-Yan Wang, Xiu-Li Sun, Zhi-Hao Chen, Feng Wang, Sunewang R. Wang & Yong Tang. (2018) Highly efficient access to well-defined linear polymers with substantial vinyl pendants via ATRP of divinyl monomers . Polymer Chemistry 9:32, pages 4309-4315.
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Eduardo Vivaldo‐Lima, Gabriel Jaramillo‐Soto & Alexander Penlidis. 2002. Encyclopedia of Polymer Science and Technology. Encyclopedia of Polymer Science and Technology 1 48 .
Xiaohui Li, Wen-Jun Wang, Bo-Geng Li & Shiping Zhu. (2015) Branching in RAFT Miniemulsion Copolymerization of Styrene/Triethylene Glycol Dimethacrylate and Control of Branching Density Distribution. Macromolecular Reaction Engineering 9:2, pages 90-99.
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Graeme Moad. (2015) RAFT (Reversible addition-fragmentation chain transfer) crosslinking (co)polymerization of multi-olefinic monomers to form polymer networks. Polymer International 64:1, pages 15-24.
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Lizeth Espinosa-Pérez, Julio César Hernández-Ortiz, Porfirio López-Domínguez, Gabriel Jaramillo-Soto, Eduardo Vivaldo-Lima, Patricia Pérez-Salinas, Alberto Rosas-Aburto, Angel Licea-Claverie, Humberto Vázquez-Torres & Maria Josefa Bernad-Bernad. (2014) Modeling of the Production of Hydrogels from Hydroxyethyl Methacrylate and (Di)Ethylene Glycol Dimethacrylate in the Presence of RAFT Agents. Macromolecular Reaction Engineering 8:8, pages 564-579.
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Alison J. Scott, Afsaneh Nabifar, Julio C. Hernández-Ortiz, Neil T. McManus, Eduardo Vivaldo-Lima & Alexander Penlidis. (2014) Crosslinking nitroxide-mediated radical copolymerization of styrene with divinylbenzene. European Polymer Journal 51, pages 87-111.
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Miguel A. D. Gonçalves, Virgínia D. Pinto, Rita A. S. Costa, Rolando C. S. Dias, Julio C. Hernándes-Ortiz & Mário Rui P. F. N. Costa. (2013) Stimuli-Responsive Hydrogels Synthesis using Free Radical and RAFT Polymerization. Macromolecular Symposia 333:1, pages 41-54.
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Miguel A. D. Gonçalves, Virgínia D. Pinto, Rolando C. S. Dias, Mário Rui P. F. N. Costa, Leandro G. Aguiar & Reinaldo Giudici. (2013) Gel Formation in Aqueous Suspension Nitroxide-Mediated Radical Co-Polymerization of Styrene/Divinylbenzene. Macromolecular Reaction Engineering 7:3-4, pages 155-175.
Crossref
Afsaneh Nabifar, Julio Hernandez-Ortiz, Eduardo Vivaldo-Lima & Alexander Penlidis. (2013) Cross-Linking Nitroxide-Mediated Radical Copolymerization from a Bayesian Experimental Design Angle. Macromolecular Symposia 324:1, pages 19-32.
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Julien Nicolas, Yohann Guillaneuf, Catherine Lefay, Denis Bertin, Didier Gigmes & Bernadette Charleux. (2013) Nitroxide-mediated polymerization. Progress in Polymer Science 38:1, pages 63-235.
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Julio C. Hernández-Ortiz, Eduardo Vivaldo-Lima & Alexander Penlidis. (2012) Modeling of Network Formation in Nitroxide-Mediated Radical Copolymerization of Vinyl/Divinyl Monomers Using a Multifunctional Polymer Molecule Approach. Macromolecular Theory and Simulations 21:5, pages 302-321.
Crossref
Gabriel Jaramillo-Soto & Eduardo Vivaldo-Lima. (2012) RAFT Copolymerization of Styrene/Divinylbenzene in Supercritical Carbon Dioxide. Australian Journal of Chemistry 65:8, pages 1177.
Crossref
M. Roa-Luna, G. Jaramillo-Soto, P. V. Castañeda-Flores & E. Vivaldo-Lima. (2010) Copolymerization Kinetics of Styrene and Divinylbenzene in the Presence of S-Thiobenzoyl Thioglycolic Acid as RAFT Agent. Chemical Engineering & Technology 33:11, pages 1893-1899.
Crossref
Angel Guillermo Zitlalpopoca-Soriano, Eduardo Vivaldo-Lima & Antonio Flores-Tlacuahuac. (2010) Bifurcation Analysis of a Tubular Reactor for Nitroxide-Mediated Radical Polymerization of Styrene. Macromolecular Reaction Engineering 4:9-10, pages 599-612.
Crossref
Miguel AD. Gonçalves, Ivone MR. Trigo, Rolando CS. Dias & Mário Rui PFN. Costa. (2010) Kinetic Modeling of the Molecular Architecture of Cross-Linked Copolymers Synthesized by Controlled Radical Polymerization Techniques. Macromolecular Symposia 291-292:1, pages 239-250.
Crossref
T. R. Nogueira, L. M. F. Lona, N. T. McManus, E. Vivaldo-Lima & A. Penlidis. (2010) Nitroxide-mediated radical copolymerization of styrene and divinylbenzene: increased polymerization rate by using TBEC as initiator. Journal of Materials Science 45:7, pages 1878-1884.
Crossref
Julio C. Hernández-Ortiz, Eduardo Vivaldo-Lima, Liliane M. F. Lona, Neil T. McManus & Alexander Penlidis. (2009) Modeling of the Nitroxide-Mediated Radical Copolymerization of Styrene and Divinylbenzene. Macromolecular Reaction Engineering 3:5-6, pages 288-311.
Crossref
Pedro R. García-Morán, Gabriel Jaramillo-Soto, Martha E. Albores-Velasco & Eduardo Vivaldo-Lima. (2009) An Experimental Study on the Free-Radical Copolymerization Kinetics with Crosslinking of Styrene and Divinylbenzene in Supercritical Carbon Dioxide. Macromolecular Reaction Engineering 3:1, pages 58-70.
Crossref
Vadim I Irzhak. (2008) Kinetics of formation of hyperbranched polymers. Russian Chemical Reviews 77:12, pages 1079-1104.
Crossref
Martha Roa‐Luna, Afsaneh Nabifar, Neil T. McManus, Eduardo Vivaldo‐Lima, Liliane M. F. Lona & Alexander Penlidis. (2008) Effect of the addition of inert or TEMPO‐capped prepolymer on polymerization rate and molecular weight development in the nitroxide‐mediated radical polymerization of styrene. Journal of Applied Polymer Science 109:6, pages 3665-3678.
Crossref
Rafael S. Dias, Maria C. Gonçalves, Liliane M.F. Lona, Eduardo Vivaldo-Lima, Neil T. McManus & Alexander Penlidis. (2007) Nitroxide-mediated radical polymerization of styrene using mono- and di-functional initiators. Chemical Engineering Science 62:18-20, pages 5240-5244.
Crossref

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