Formation of methyl radicals derived from cumene hydroperoxide in reconstructed human epidermis: an EPR spin trapping confirmation by using ¹³C-substitution

Fatma SahliDermatochemistry Laboratory, University of Strasbourg-CNRS UMR 7177, Strasbourg, France; View further author information

Amélie GodardDermatochemistry Laboratory, University of Strasbourg-CNRS UMR 7177, Strasbourg, France; View further author information

Bertrand VilenoPOMAM Laboratory, University of Strasbourg-CNRS UMR 7177, Strasbourg, France; ;French EPR Federation of Research, REseau NAtional de Rpe InterDisciplinaire (RENARD), FranceView further author information

Jean-Pierre LepoittevinDermatochemistry Laboratory, University of Strasbourg-CNRS UMR 7177, Strasbourg, France; View further author information

Elena Giménez-ArnauDermatochemistry Laboratory, University of Strasbourg-CNRS UMR 7177, Strasbourg, France; Correspondence[email protected]

http://orcid.org/0000-0001-8275-5447 View further author information

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Fatma Sahli, Bertrand Vileno, Christophe Gourlaouen & Elena Giménez-Arnau. (2022) Autoxidized citronellol: Free radicals as potential sparkles to ignite the fragrance induced skin sensitizing pathway. Food and Chemical Toxicology 166, pages 113201.
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Isabel A Ogueta, Johanna Brared Christensson, Elena Giménez‐Arnau, Richard Brans, Mark Wilkinson, Luca Stingeni, Caterina Foti, Olivier Aerts, Cecilia Svedman, Margarida Gonçalo & Ana Giménez‐Arnau. (2022) Limonene and linalool hydroperoxides review: Pros and cons for routine patch testing. Contact Dermatitis 87:1, pages 1-12.
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Bertrand Vileno, Yannick Port‐Lougarre & Elena Giménez‐Arnau. (2022) Electron paramagnetic resonance and spin trapping to detect free radicals from allergenic hydroperoxides in contact with the skin: From the molecule to the tissue. Contact Dermatitis 86:4, pages 241-253.
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J. Lichter, M. Silva e Sousa, N. Peter, F. Sahli, B. Vileno, S. Kuresepi, C. Gourlaouen, E. Giménez‐Arnau & B. Blömeke. (2020) Skin sensitization to fragrance hydroperoxides: interplay between dendritic cells, keratinocytes and free radicals. British Journal of Dermatology.
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Salen Kuresepi, Bertrand Vileno, Jean-Pierre Lepoittevin & Elena Giménez-Arnau. (2020) Mechanistic Insights on Skin Sensitization to Linalool Hydroperoxides: EPR Evidence on Radical Intermediates Formation in Reconstructed Human Epidermis and 13 C NMR Reactivity Studies with Thiol Residues . Chemical Research in Toxicology 33:7, pages 1922-1932.
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Mawadda Alghrably, Dorota Dudek, Abdul-Hamid Emwas, Łukasz Jaremko, Mariusz Jaremko & Magdalena Rowińska-Żyrek. (2020) Copper(II) and Amylin Analogues: A Complicated Relationship. Inorganic Chemistry 59:4, pages 2527-2535.
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Formation of methyl radicals derived from cumene hydroperoxide in reconstructed human epidermis: an EPR spin trapping confirmation by using ¹³C-substitution

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Formation of methyl radicals derived from cumene hydroperoxide in reconstructed human epidermis: an EPR spin trapping confirmation by using 13C-substitution

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Formation of methyl radicals derived from cumene hydroperoxide in reconstructed human epidermis: an EPR spin trapping confirmation by using ¹³C-substitution