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Philosophical Magazine B Volume 80, 2000 - Issue 10
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Original Articles

The structural origin of broken chemical order in GeSe2 glass

P. Boolchand Department of Electrical and Computer Engineering and Computer Science, University of Cincinnati, Cincinnati, Ohio, 45221-0030, USA
&
W. J. Bresser Department of Electrical and Computer Engineering and Computer Science, University of Cincinnati, Cincinnati, Ohio, 45221-0030, USA
Pages 1757-1772 | Received 26 Apr 2000, Accepted 03 May 2000, Published online: 24 Aug 2009

Citations (91)

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A. Ganjoo, H. Jain, S. Khalid & C. G. Pantano. (2005) Structural modification of Ge–Se amorphous films with the addition of Sb. Philosophical Magazine Letters 85:10, pages 503-512.
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J. C. Phillips. (2003) Nanoscopic filters as the origin of d-wave energy gaps . Philosophical Magazine 83:28, pages 3255-3265.
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Liuchun Cai & P. Boolchand. (2002) Nanoscale phase separation of GeS2 glass. Philosophical Magazine B 82:15, pages 1649-1657.
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Articles from other publishers (88)

A. Ahmed Simon, B. Badamchi, H. Subbaraman, Y. Sakaguchi, L. Jones, H. Kunold, I. J. van Rooyen & M. Mitkova. (2021) Introduction of Chalcogenide Glasses to Additive Manufacturing: Nanoparticle Ink Formulation, Inkjet Printing, and Phase Change Devices Fabrication. Scientific Reports 11:1.
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A. Piarristeguy, M. Micoulaut, R. Escalier, G. Silly, M.-V. Coulet & A. Pradel. (2021) Obtaining glasses in the extremely crystallizing Ge–Sb–Te phase change material. Journal of Non-Crystalline Solids 562, pages 120730.
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Matthieu Micoulaut, Hugo Flores-Ruiz, Annie Pradel & Andrea Piarristeguy. (2020) Tetrahedral Complexity in Amorphous Networks: A Possible Clue for the Unique Properties of Phase‐Change Materials. physica status solidi (RRL) – Rapid Research Letters 15:3, pages 2000490.
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Jonas Keukelier, Karl Opsomer, Thomas Nuytten, Stefanie Sergeant, Wouter Devulder, Sergiu Clima, Ludovic Goux, Gouri Sankar Kar & Christophe Detavernier. (2021) Impact of changes in bond structure on ovonic threshold switching behaviour in GeSe 2 . Journal of Materials Chemistry C 9:1, pages 117-126.
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Pankaj K. Mishra, K. Singh, A.N. Upadhyay & H. Kumar. (2019) Compositional dependence of thermal transport and optical properties of Se85 Ge15-x Pbx (0≤ x ≤10) chalcogenide glassy alloys. Optical Materials 97, pages 109395.
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Yue Liu, Junming Wu, Guang Yang, Tianlu Zhao & Siqi Shi. (2019) Predicting the onset temperature (Tg) of Ge Se1− glass transition: a feature selection based two-stage support vector regression method. Science Bulletin 64:16, pages 1195-1203.
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Ralph Chbeir, Mathieu Bauchy, Matthieu Micoulaut & Punit Boolchand. (2019) Evidence for a Correlation of Melt Fragility Index With Topological Phases of Multicomponent Glasses. Frontiers in Materials 6.
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Muhammad R. Latif, Dmitri A. Tenne & Maria Mitkova. (2018) Nanotube structures: material characterization and structural analysis of Ge–Se thin films. Journal of Materials Science: Materials in Electronics 30:3, pages 2470-2478.
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Anita Zeidler, Philip S. Salmon, Dean A. J. Whittaker, Keiron J. Pizzey & Alex C. Hannon. (2017) Topological Ordering and Viscosity in the Glass-Forming Ge–Se System: The Search for a Structural or Dynamical Signature of the Intermediate Phase. Frontiers in Materials 4.
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S. Dash, P. Chen & P. Boolchand. (2017) Molecular origin of aging of pure Se glass: Growth of inter-chain structural correlations, network compaction, and partial ordering. The Journal of Chemical Physics 146:22.
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Kiran Prasai, Gang Chen & D. A. Drabold. (2017) Amorphous to amorphous insulator-metal transition in :Ag glasses . Physical Review Materials 1:1.
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Pengfei Li, Yaqi Zhang, Zeming Chen, Peng Gao, Tao Wu & Li-Min Wang. (2017) Relaxation dynamics in the strong chalcogenide glass-former of Ge22Se78. Scientific Reports 7:1.
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Philip S Salmon & Anita Zeidler. (2015) Networks under pressure: the development of in situ high-pressure neutron diffraction for glassy and liquid materials . Journal of Physics: Condensed Matter 27:13, pages 133201.
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Philip S. Salmon & Anita Zeidler. 2015. Molecular Dynamics Simulations of Disordered Materials. Molecular Dynamics Simulations of Disordered Materials 1 31 .
R.T. Ananth Kumar, P. Chithra Lekha, C. Sanjeeviraja & D. Pathinettam Padiyan. (2014) Evolution of structural disorder using Raman spectra and Urbach energy in GeSe 0.5 S 1.5 thin films. Journal of Non-Crystalline Solids 405, pages 21-26.
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A.W. Mao, S.C. Currie, B.G. Aitken & S. Sen. (2014) Synthesis and characterization of ternary glasses in the system Na2Se-Ga2Se3-GeSe2. Journal of Non-Crystalline Solids 404, pages 91-97.
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Kamil Wezka, Assil Bouzid, Keiron J. Pizzey, Philip S. Salmon, Anita Zeidler, Stefan Klotz, Henry E. Fischer, Craig L. Bull, Matthew G. Tucker, Mauro Boero, Sébastien Le Roux, Christine Tugène & Carlo Massobrio. (2014) Density-driven defect-mediated network collapse of glass . Physical Review B 90:5.
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Shibalik Chakraborty & P. Boolchand. (2014) Topological Origin of Fragility, Network Adaptation, and Rigidity and Stress Transitions in Especially Homogenized Nonstoichiometric Binary Ge x S 100– x Glasses . The Journal of Physical Chemistry B 118:8, pages 2249-2263.
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Guang Yang, Yann Gueguen, Jean-Christophe Sangleboeuf, Tanguy Rouxel, Catherine Boussard-Plédel, Johann Troles, Pierre Lucas & Bruno Bureau. (2013) Physical properties of the GexSe1−x glasses in the 0<x<0.42 range in correlation with their structure. Journal of Non-Crystalline Solids 377, pages 54-59.
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A.W. Mao, D.C. Kaseman, R.E. Youngman, B.G. Aitken & S. Sen. (2013) Structure and bonding characteristics of chalcogenide glasses in the system BaSeGa2Se3GeSe2. Journal of Non-Crystalline Solids 375, pages 40-46.
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R. Holomb, V. Mitsa, E. Akalin, S. Akyuz & M. Sichka. (2013) Ab initio and Raman study of medium range ordering in GeSe2 glass. Journal of Non-Crystalline Solids 373-374, pages 51-56.
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A.W. Mao, B.G. Aitken & S. Sen. (2013) Synthesis and physical properties of chalcogenide glasses in the system BaSe–Ga2Se3–GeSe2. Journal of Non-Crystalline Solids 369, pages 38-43.
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Pyotr Rabochiy & Vassiliy Lubchenko. (2013) Microscopic calculation of the free energy cost for activated transport in glass-forming liquids. The Journal of Chemical Physics 138:12.
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Philip S. Salmon & Anita Zeidler. (2013) Identifying and characterising the different structural length scales in liquids and glasses: an experimental approach. Physical Chemistry Chemical Physics 15:37, pages 15286.
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Sheikh Ziaur Rahaman, Siddheswar Maikap, Atanu Das, Amit Prakash, Ya Hsuan Wu, Chao-Sung Lai, Ta-Chang Tien, Wei-Su Chen, Heng-Yuan Lee, Frederick T Chen, Ming-Jinn Tsai & Liann-Be Chang. (2012) Enhanced nanoscale resistive switching memory characteristics and switching mechanism using high-Ge-content Ge0.5Se0.5 solid electrolyte. Nanoscale Research Letters 7:1.
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P. Boolchand, K. Gunasekera & S. Bhosle. (2012) Midgap states, Raman scattering, glass homogeneity, percolative rigidity and stress transitions in chalcogenides. physica status solidi (b) 249:10, pages 2013-2018.
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Siddhesh Bhosle, Kapila Gunasekera, Punit Boolchand & Matthieu Micoulaut. (2012) Melt Homogenization and Self-Organization in Chalcogenides-Part II. International Journal of Applied Glass Science 3:3, pages 205-220.
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Trenton G. Edwards, Sabyasachi Sen & Erica L. Gjersing. (2012) A combined 77Se NMR and Raman spectroscopic study of the structure of GexSe1-x glasses: Towards a self consistent structural model. Journal of Non-Crystalline Solids 358:3, pages 609-614.
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S. Bhosle, K. Gunasekera, Ping Chen, P. Boolchand, M. Micoulaut & C. Massobrio. (2011) Meeting experimental challenges to physics of network glasses: Assessing the role of sample homogeneity. Solid State Communications 151:24, pages 1851-1855.
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J.C. Phillips. (2011) Microscopic aspects of Stretched Exponential Relaxation (SER) in homogeneous molecular and network glasses and polymers. Journal of Non-Crystalline Solids 357:22-23, pages 3853-3865.
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M. Bauchy, M. Micoulaut, M. Celino, S. Le Roux, M. Boero & C. Massobrio. (2011) Angular rigidity in tetrahedral network glasses with changing composition. Physical Review B 84:5.
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T. G. Edwards & S. Sen. (2011) Structure and Relaxation in Germanium Selenide Glasses and Supercooled Liquids: A Raman Spectroscopic Study. The Journal of Physical Chemistry B 115:15, pages 4307-4314.
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Changgui Lin, Laurent Calvez, Haizheng Tao, Mathieu Allix, Alain Moréac, Xianghua Zhang & Xiujian Zhao. (2011) Evidence of network demixing in GeS2–Ga2S3 chalcogenide glasses: A phase transformation study. Journal of Solid State Chemistry 184:3, pages 584-588.
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Tomas Kohoutek, Shintaro Mizuno, Takenobu Suzuki, Yasutake Ohishi, Morio Matsumoto & Takashi Misumi. (2011) Third-harmonic generation measurement of nonlinear optical susceptibility χ^(3) of Ge-Ga-Sb-S chalcogenide glasses proposed for highly nonlinear photonic fibers. Journal of the Optical Society of America B 28:2, pages 298.
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I. D. Tolmachov. (2010) Optical properties and structure of As-Ge-Se thin films. Semiconductor physics, quantum electronics and optoelectronics 13:3, pages 276-279.
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E. L. Gjersing, S. Sen & B. G. Aitken. (2010) Structure, Connectivity, and Configurational Entropy of Ge x Se 100− x Glasses: Results from 77 Se MAS NMR Spectroscopy . The Journal of Physical Chemistry C 114:18, pages 8601-8608.
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M. Erazú, J. Rocca, M. Fontana, A. Ureña, B. Arcondo & A. Pradel. (2010) Raman spectroscopy of chalcogenide thin films prepared by PLD. Journal of Alloys and Compounds 495:2, pages 642-645.
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V Petkov & D Le Messurier. (2010) Atomic-scale structure of GeSe 2 glass revisited: a continuous or broken network of Ge–(Se 1/2 ) 4 tetrahedra? . Journal of Physics: Condensed Matter 22:11, pages 115402.
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Ping Chen, P Boolchand & D G Georgiev. (2010) Long term aging of selenide glasses: evidence of sub- T g endotherms and pre- T g exotherms . Journal of Physics: Condensed Matter 22:6, pages 065104.
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Carlo Massobrio, Matthieu Micoulaut & Philip S. Salmon. (2010) Impact of the exchange-correlation functional on the structure of glassy GeSe2. Solid State Sciences 12:2, pages 199-203.
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C. Massobrio. 2010. Advances in the Atomic-Scale Modeling of Nanosystems and Nanostructured Materials. Advances in the Atomic-Scale Modeling of Nanosystems and Nanostructured Materials 343 374 .
P. Boolchand, Ping Chen & U. Vempati. (2009) Intermediate Phases, structural variance and network demixing in chalcogenides: The unusual case of group V sulfides. Journal of Non-Crystalline Solids 355:37-42, pages 1773-1785.
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Yi-Fan Niu, Jean-Pierre Guin, Tanguy Rouxel, Abdesselam Abdelouas, Johann Troles & Frederic Smektala. (2009) Aqueous Corrosion of the GeSe 4 Chalcogenide Glass: Surface Properties and Corrosion Mechanism . Journal of the American Ceramic Society 92:8, pages 1779-1787.
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Matthieu Micoulaut, Rodolphe Vuilleumier & Carlo Massobrio. (2009) Improved modeling of liquid : Impact of the exchange-correlation functional . Physical Review B 79:21.
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Punit Boolchand, Matthieu Micoulaut & Ping Chen. 2009. Phase Change Materials. Phase Change Materials 39 62 .
Carlo Massobrio & Alfredo Pasquarello. (2008) Short and intermediate range order in amorphous . Physical Review B 77:14.
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Nor Aiyyuhal Jemali, Hasan Abu Kassim, V. Radhika Devi & Keshav N. Shrivastava. (2008) Ab initio calculation of vibrational frequencies of GexSe1−x glass. Journal of Non-Crystalline Solids 354:15-16, pages 1744-1750.
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Bibiana Arcondo, María Andrea Ureña, Maximiliano Erazú, Javier Rocca & Marcelo Fontana. (2008) The effect of adding a bit of Fe to Ag–Ge–Se system. Hyperfine Interactions 182:1-3, pages 137-147.
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Bibiana Arcondo, María Andrea Ureña, Maximiliano Erazú, Javier Rocca & Marcelo Fontana. 2009. ICAME 2007. ICAME 2007 137 147 .
Carlo Massobrio & Alfredo Pasquarello. (2007) Structural properties of amorphous GeSe 2 . Journal of Physics: Condensed Matter 19:41, pages 415111.
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Philip S. Salmon. (2007) Structure of liquids and glasses in the Ge–Se binary system. Journal of Non-Crystalline Solids 353:32-40, pages 2959-2974.
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B. Arcondo, M.A. Ureña, A. Piarristeguy, A. Pradel & M. Fontana. (2007) Homogeneous–inhomogeneous models of Agx(Ge0.25Se0.75)100−x bulk glasses. Physica B: Condensed Matter 389:1, pages 77-82.
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P. Boolchand, P. Chen, M. Jin, B. Goodman & W.J. Bresser. (2007) 129I and 119Sn Mössbauer spectroscopy, reversibility window and nanoscale phase separation in binary GexSe1−x glasses. Physica B: Condensed Matter 389:1, pages 18-28.
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Eungho Ahn, G. A. Williams & P. C. Taylor. (2006) Nuclear quadrupole resonance study of local bonding in glassy . Physical Review B 74:17.
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R. Singh, S.K. Tripathi & S. Kumar. (2006) Space charge limited conduction in a-(Ge20Se80)1−xSnx thin films. Journal of Non-Crystalline Solids 352:30-31, pages 3230-3235.
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Michael N. Kozicki & Maria Mitkova. (2006) Mass transport in chalcogenide electrolyte films – materials and applications. Journal of Non-Crystalline Solids 352:6-7, pages 567-577.
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Valeri Petkov. (2005) Atomic‐Scale Structure of Glasses Using High‐Energy X‐Ray Diffraction. Journal of the American Ceramic Society 88:9, pages 2528-2531.
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Fei Wang, S. Mamedov, P. Boolchand, B. Goodman & Meera Chandrasekhar. (2005) Pressure Raman effects and internal stress in network glasses. Physical Review B 71:17.
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Carlo Massobrio, Massimo Celino & Alfredo Pasquarello. (2004) Charge fluctuations and concentration fluctuations at intermediate-range distances in the disordered network-forming materials , , and . Physical Review B 70:17.
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Maria I. Mitkova, Michael N. Kozicki & Janmichael P. Aberouette. (2003) Morphology of electrochemically grown silver deposits on silver-saturated Ge–Se thin films. Journal of Non-Crystalline Solids 326-327, pages 425-429.
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R. Ston, Mir. Vlček & H. Jain. (2003) Structure and photoinduced changes in bulk and films of As–Ge–S system. Journal of Non-Crystalline Solids 326-327, pages 220-225.
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Y Wang, M Mitkova, D G Georgiev, S Mamedov & P Boolchand. (2003) Macroscopic phase separation of Se-rich ( x < 1/3) ternary Ag y (Ge x Se 1  x ) 1  y glasses . Journal of Physics: Condensed Matter 15:16, pages S1573-S1584.
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Carlo Massobrio, Massimo Celino & Alfredo Pasquarello. (2003) Evidence of concentration fluctuations in disordered network-forming systems: the case of GeSe 4 and SiSe 2 . Journal of Physics: Condensed Matter 15:16, pages S1537-S1546.
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Philip S Salmon & Ingrid Petri. (2003) Structure of glassy and liquid GeSe 2 . Journal of Physics: Condensed Matter 15:16, pages S1509-S1528.
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Massimo Celino & Carlo Massobrio. (2003) Origin of Network Connectivity and Structural Units in Amorphous . Physical Review Letters 90:12.
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M.A.P Silva, V Briois, M Poulain, Y Messaddeq & S.J.L Ribeiro. (2003) SiO2–PbF2–CdF2 glasses and glass ceramics. Journal of Physics and Chemistry of Solids 64:1, pages 95-105.
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Matthieu Micoulaut. (2002) Network entropy and connectivity: the underlying factors determining compositional trends in the glass-transition temperature. Comptes Rendus Chimie 5:12, pages 825-830.
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Punit Boolchand, Daniel G. Georgiev, Tao Qu, Fei Wang, Liuchun Cai & Swapnajit Chakravarty. (2002) Nanoscale phase separation effects near and 2.67, and rigidity transitions in chalcogenide glasses. Comptes Rendus Chimie 5:11, pages 713-724.
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RICHARD KERNER. (2012) STOCHASTIC DESCRIPTION OF AGGLOMERATION AND GROWTH PROCESSES IN GLASSES. International Journal of Modern Physics B 16:14n15, pages 1987-1994.
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Koblar Jackson, Sudha Srinivas, Jens Kortus & Mark Pederson. (2002) Modeling the Mössbauer spectra of chalcogenide glasses using density-functional theory calculations . Physical Review B 65:21.
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Massimo Celino & Carlo Massobrio. (2002) Beyond short-range order length scales in disordered materials: first principles modeling of SiSe2. Computational Materials Science 24:1-2, pages 28-32.
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Yong Wang, Kouhei Tanaka, Toshiyuki Nakaoka & Kazuo Murase. (2002) Effect of nanophase separation on crystallization process in Ge–Se glasses studied by Raman scattering. Physica B: Condensed Matter 316-317, pages 568-571.
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Eungho Ahn, G.A Williams, P.C Taylor, D.G Georgiev, P Boolchand, B.E Schwickert & R.L Cappelletti. (2002) Nuclear quadrupole resonance study of the glassy AsxSe1−x system. Journal of Non-Crystalline Solids 299-302, pages 958-962.
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M Mitkova & M.N Kozicki. (2002) Silver incorporation in Ge–Se glasses used in programmable metallization cell devices. Journal of Non-Crystalline Solids 299-302, pages 1023-1027.
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Yong Wang, Kouhei Tanaka, Toshiyuki Nakaoka & Kazuo Murase. (2002) Evidence of nanophase separation in Ge–Se glasses. Journal of Non-Crystalline Solids 299-302, pages 963-967.
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Y. Wang, T. Nakaoka & K. Murase. 2002. Phase Transitions and Self-Organization in Electronic and Molecular Networks. Phase Transitions and Self-Organization in Electronic and Molecular Networks 85 100 .
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Koblar Jackson & Shau Grossman. (2001) Chain formation and the origin of structure in the Raman spectrum of . Physical Review B 65:1.
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P. Boolchand, X. Feng & W.J. Bresser. (2001) Rigidity transitions in binary Ge–Se glasses and the intermediate phase. Journal of Non-Crystalline Solids 293-295, pages 348-356.
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I. Petri & P.S. Salmon. (2001) A neutron diffraction study of glassy GeS2. Journal of Non-Crystalline Solids 293-295, pages 169-174.
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P. Boolchand & W. J. Bresser. (2001) Mobile silver ions and glass formation in solid electrolytes. Nature 410:6832, pages 1070-1073.
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P. Boolchand, D. Selvanathan, Y. Wang, D. G. Georgiev & W. J. Bresser. 2001. Properties and Applications of Amorphous Materials. Properties and Applications of Amorphous Materials 97 132 .
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