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Original Articles

Peierls instabilities in covalent structures I. Electronic structure, cohesion and the Z = 8 – N rule

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Pages 727-744 | Received 20 Feb 1997, Accepted 16 May 1997, Published online: 13 Aug 2009

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M Mayo, E Yahel, Y Greenberg & G Makov. (2013) Short range order in liquid pnictides. Journal of Physics: Condensed Matter 25:50, pages 505102.
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QING-HAI HAO, Y. D. LI, XIANG-SHAN KONG & C. S. LIU. (2013) AB INITIO MOLECULAR DYNAMICS SIMULATIONS ON LOCAL STRUCTURE AND ELECTRONIC PROPERTIES IN LIQUID Sb FROM 913 K TO 1193 K . International Journal of Modern Physics B 27:05, pages 1350012.
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Y.B. Wang, W.S. Dong, G. Zhao, J.X. Ding, S.H. Li & Y.J. Ge. (2012) Chain structure of liquid Se at high temperature and pressure investigated by ab initio molecular dynamics simulations. Journal of Non-Crystalline Solids 358:5, pages 873-879.
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Salah Eddine Boulfelfel, Gotthard Seifert, Yuri Grin & Stefano Leoni. (2012) Squeezing lone pairs: The 17 to 7 pressure-induced phase transition in black phosphorus . Physical Review B 85:1.
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Alexander V. Kolobov & Junji TominagaAlexander V. Kolobov & Junji Tominaga. 2012. Chalcogenides. Chalcogenides 149 179 .
T. Matsunaga, P. Fons, A. V. Kolobov, J. Tominaga & N. Yamada. (2011) The order-disorder transition in GeTe: Views from different length-scales. Applied Physics Letters 99:23.
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Dominic Lencer, Martin Salinga & Matthias Wuttig. (2011) Design Rules for Phase-Change Materials in Data Storage Applications. Advanced Materials 23:18, pages 2030-2058.
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A.V. Kolobov, M. Krbal, P. Fons, J. Tominaga & T. Uruga. (2011) Distortion-triggered loss of long-range order in solids with bonding energy hierarchy. Nature Chemistry 3:4, pages 311-316.
Crossref
P. Zalden, C. Bichara, J. v. Eijk, R. P. Hermann, I. Sergueev, G. Bruns, S. Buller, W. Bensch, T. Matsunaga, N. Yamada & M. Wuttig. (2011) Thermal and elastic properties of Ge-Sb-Te based phase-change materials. MRS Proceedings 1338.
Crossref
Kameshwar Kumar, Nagesh Thakur, S.C. Katyal & Pankaj Sharma. (2010) A Study of the Physical Properties of Te<sub>15</sub>(Se<sub>100-x</sub>Bi<sub>x</sub>)<sub>85</sub> Glassy Alloys. Defect and Diffusion Forum 305-306, pages 61-69.
Crossref
Paul Fons, Alexander V. Kolobov, Milos Krbal, Junji Tominaga, K. S. Andrikopoulos, S. N. Yannopoulos, G. A. Voyiatzis & T. Uruga. (2010) Phase transition in crystalline GeTe: Pitfalls of averaging effects. Physical Review B 82:15.
Crossref
Gang Zhao, Yu'e Zhao, Yubing Wang & Changjian Ji. (2010) Ab initio molecular dynamics study of liquid Se 30 Te 70 : structural, electronic and dynamical properties . Physica Scripta 82:3, pages 035603.
Crossref
Céline Otjacques, Jean-Yves Raty, Françoise Hippert, Helmut Schober, Mark Johnson, René Céolin & Jean-Pierre Gaspard. (2010) Structural and vibrational study of the negative thermal expansion in liquid . Physical Review B 82:5.
Crossref
Gang Zhao, Yue Zhao, Yubing Wang & Haifeng Mu. (2010) Ab initio molecular dynamics simulations of structural change in liquid Se30Te70 from low- to high-density phases. Physica B: Condensed Matter 405:16, pages 3342-3349.
Crossref
M. H. Müser. (2010) Elementary considerations on the local symmetry in optoelectronic materials and their phase change behavior. The European Physical Journal B 74:3, pages 291-302.
Crossref
Jean-Yves Raty, Céline Otjacques, Jean-Pierre Gaspard & Christophe Bichara. (2010) Amorphous structure and electronic properties of the Ge1Sb2Te4 phase change material. Solid State Sciences 12:2, pages 193-198.
Crossref
Andriy Zhugayevych & Vassiliy Lubchenko. (2010) An intrinsic formation mechanism for midgap electronic states in semiconductor glasses. The Journal of Chemical Physics 132:4.
Crossref
S. J. Park, M. H. Jang, Sung-Jin Park, M.-H. Cho, J. K. Kim, D.-H. Ko & H. C. Sohn. (2010) Effect of Bonding Characteristics on the Instability of Ge[sub x]Sb[sub 1−x] Films. Journal of The Electrochemical Society 157:12, pages H1078.
Crossref
Ayano Chiba, Masatoshi Tomomasa, Takazumi Hayakawa, Stephen M. Bennington, Alex C. Hannon & Kazuhiko Tsuji. (2009) Pressure-induced suppression of the Peierls distortion of liquid As and . Physical Review B 80:6.
Crossref
G. Zhao & Y. N. Wu. (2009) Negative thermal expansion coefficient in supercooled liquid Te. Physical Review B 79:18.
Crossref
Paul Fons. 2009. Phase Change Materials. Phase Change Materials 149 174 .
Christoph Steimer, Vanessa Coulet, Wojciech Welnic, Henning Dieker, Ralf Detemple, Christophe Bichara, Brigitte Beuneu, Jean‐Pierre Gaspard & Matthias Wuttig. (2008) Characteristic Ordering in Liquid Phase‐Change Materials. Advanced Materials 20:23, pages 4535-4540.
Crossref
Pankaj Sharma & S.C. Katyal. (2008) Effect of tellurium addition on the physical properties of germanium selenide glassy semiconductors. Physica B: Condensed Matter 403:19-20, pages 3667-3671.
Crossref
G. Zhao, C.S. Liu & Z.G. Zhu. (2008) Local atomic structure and chemical bonding in liquid Te: An ab initio molecular-dynamics simulation. Chemical Physics Letters 458:1-3, pages 101-107.
Crossref
Wojciech Wełnic & Matthias Wuttig. (2008) Reversible switching in phase-change materials. Materials Today 11:6, pages 20-27.
Crossref
Matthias Wuttig & Noboru Yamada. (2007) Phase-change materials for rewriteable data storage. Nature Materials 6:11, pages 824-832.
Crossref
Wojciech Wełnic, Johannes A. Kalb, Daniel Wamwangi, Christoph Steimer & Matthias Wuttig. (2011) Phase change materials: From structures to kinetics. Journal of Materials Research 22:9, pages 2368-2375.
Crossref
Jean-Yves Raty, Eric Schwegler & Stanimir A. Bonev. (2007) Electronic and structural transitions in dense liquid sodium. Nature 449:7161, pages 448-451.
Crossref
Françoise Leclercq-Hugeux, Marie-Vanessa Coulet, Jean-Pierre Gaspard, Stéphanie Pouget & Jean-Marc Zanotti. (2007) Neutrons probing the structure and dynamics of liquids. Comptes Rendus Physique 8:7-8, pages 884-908.
Crossref
Christophe Bichara, Mark Johnson & Jean Pierre Gaspard. (2007) Octahedral structure of liquid alloy: First-principles molecular dynamics study . Physical Review B 75:6.
Crossref
Matthias Wuttig, Daniel Lüsebrink, Daniel Wamwangi, Wojciech Wełnic, Michael Gilleßen & Richard Dronskowski. (2006) The role of vacancies and local distortions in the design of new phase-change materials. Nature Materials 6:2, pages 122-128.
Crossref
Y. Tsuchiya. (2006) Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table. International Journal of Materials Research 97:4, pages 371-376.
Crossref
Marie-Vanessa Coulet, Denis Testemale, Jean-Louis Hazemann, Jean-Pierre Gaspard & Christophe Bichara. (2005) Reverse Monte Carlo analysis of the local order in liquid alloys combining neutron scattering and x-ray absorption spectroscopy . Physical Review B 72:17.
Crossref
M Delheusy, J.Y Raty, R Detemple, W Welnic, M Wuttig & J.-P Gaspard. (2004) Structure of liquid Te-based alloys used in rewritable DVDs. Physica B: Condensed Matter 350:1-3, pages E1055-E1057.
Crossref
G. Ferlat, A. San Miguel, H. Xu, A. Aouizerat, X. Blase, J. Zuñiga & V. Muñoz-Sanjosé. (2004) Semiconductor-metal transitions in liquid alloys: A concentration-induced transition . Physical Review B 69:15.
Crossref
Claire Bergman, Christophe Bichara, Jean Pierre Gaspard & Yoshimi Tsuchiya. (2003) Experimental investigation of the waterlike density anomaly in the liquid eutectic alloy . Physical Review B 67:10.
Crossref
J.-Y Raty, J.-P Gaspard, C Bichara, C Bergman, R Bellissent & R Ceolin. (2000) Re-entrant peierls distortion in IV–VI compounds. Physica B: Condensed Matter 276-278, pages 473-474.
Crossref
Dong-Kyun Seo & Roald Hoffmann. (1999) What Determines the Structures of the Group 15 Elements?. Journal of Solid State Chemistry 147:1, pages 26-37.
Crossref
D. Molina, E. Lomba & G. Kahl. (1999) Tight-binding model of selenium disordered phases. Physical Review B 60:9, pages 6372-6382.
Crossref
C Bichara, J.-Y Raty & J.-P Gaspard. (1999) Structure of high temperature fluid selenium. Journal of Non-Crystalline Solids 250-252, pages 419-422.
Crossref
J. Y. Raty, A. Saùl, J. P. Gaspard & C. Bichara. (1999) Structure of high-temperature fluid selenium. Physical Review B 60:4, pages 2441-2448.
Crossref

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