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Philosophical Magazine Volume 83, 2003 - Issue 10
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Original Articles

Structure and role of the interfacial layers in VC-rich WC-Co cermets

S. Lay Laboratoire de Thermodynamique et Physico-chimie Métallurgique, Unité Mixte de Recherche 5614 associée au CNRS-Institut National Polytechnique de Grenoble-Université Joseph Fourier, Domaine Universitaire, BP 75, St Martin-d'Hères Cedex, 38402, France
,
J. Thibault Département de Recherche Fondamentale sur la Matière Condensée, Commissariat à l'Energie Atomique, 17 rue des Martyrs, Grenoble Cedex, 38054, France
&
S. Hamar-Thibault Laboratoire de Thermodynamique et Physico-chimie Métallurgique, Unité Mixte de Recherche 5614 associée au CNRS-Institut National Polytechnique de Grenoble-Université Joseph Fourier, Domaine Universitaire, BP 75, St Martin-d'Hères Cedex, 38402, France
Pages 1175-1190 | Published online: 15 Nov 2010

Citations (51)

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Read on this site (3)

Sven A.E. Johansson & Göran Wahnström. (2010) Theory of ultrathin films at metal–ceramic interfaces. Philosophical Magazine Letters 90:8, pages 599-609.
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A.K. Basak, S. Achanta, M. De Bonte, J. P. Celis, M. Vardavoulias & P. Matteazzi. (2007) Effect of Al and Cr addition on tribological behaviour of HVOF and APS nanostructured WC–Co coatings. Transactions of the IMF 85:6, pages 310-315.
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S. Lay & M. Loubradou. (2003) Characteristics and origin of clusters in submicron WC-Co cermets. Philosophical Magazine 83:23, pages 2669-2679.
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Articles from other publishers (48)

Weiyou Chen, Zengbin Yin, Xuelin Li & Juntang Yuan. (2023) Effect of co-doped additives on microstructure and mechanical properties of microwave-sintered WC-10Co cemented carbide tool materials. Journal of Alloys and Compounds 962, pages 171148.
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Xueqi Wang, Jianbo Tu, Wenhao Dai, Pinwen Zhu, Qiang Tao, Fulong Ning & Baochang Liu. (2023) Enhanced mechanical properties of fine-grained polycrystalline diamond compact doping with nano‑vanadium carbide. International Journal of Refractory Metals and Hard Materials 114, pages 106248.
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Xiao-Hui Yang, Kai-Fei Wang, Guo-Hua Zhang & Kuo-Chih Chou. (2022) WC-VC/Cr3C2 composite powders prepared by a carbothermic reduction-carburization process. International Journal of Refractory Metals and Hard Materials 109, pages 105982.
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Congying Xiang, Min Shen, Chongze Hu, Lok Wing Wong, Hongbo Nie, Huasheng Lei, Jian Luo, Jiong Zhao & Zhiyang Yu. (2022) Atomistic observation of in situ fractured surfaces at a V-doped WC Co interface. Journal of Materials Science & Technology 110, pages 103-108.
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Xiaoyuan Ye, Congying Xiang, Hongbo Nie, Huasheng Lei, Yong Du, Wandong Xing, Jian Luo & Zhiyang Yu. (2022) Facet-dependent interfacial segregation behavior of V-doped WC-Co cemented carbides. Ceramics International 48:8, pages 11251-11256.
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A.K. Basak & Alokesh Pramanik. 2022. Machining and Tribology. Machining and Tribology 93 112 .
A.K. Basak, J.-P. Celis, M. Vardavoulias & P. Matteazzi. (2021) Abrasive wear of nanostructured cermet coatings in dry and slurry conditions. International Journal of Refractory Metals and Hard Materials 100, pages 105638.
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Ahmet Bahadir Yildiz, R. Prasath Babu, Manon Bonvalet-Rolland, Sebastian Busch, Vasyl Ryukhtin, Jonathan Weidow, Susanne Norgren & Peter Hedström. (2021) Quantification of nano-scale interface structures to guide mechanistic modelling of WC grain coarsening inhibition in V-doped hard metals. Materials & Design 207, pages 109825.
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Erik Fransson, Martin Gren & Göran Wahnström. (2021) Complexions and grain growth retardation: First-principles modeling of phase boundaries in WC-Co cemented carbides at elevated temperatures. Acta Materialia 216, pages 117128.
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Can Yang, Chongze Hu, Congying XiangHongbo Nie, Xinfu Gu, Lin XieJiaqing HeWenqing Zhang, Zhiyang Yu & Jian Luo. (2021) Interfacial superstructures and chemical bonding transitions at metal-ceramic interfaces. Science Advances 7:11.
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Congying Xiang, Chao Liu, Xiao Wen, Hongbo Nie, Chongze Hu, Zhishan Luo, Yanwen Li, Jian Luo & Zhiyang Yu. (2020) Formation of stacking faults in tungsten carbide during sintering. Ceramics International 46:10, pages 15851-15857.
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Joanna Wachowicz. (2020) Spark Plasma Sintering – new technology for obtaining tool materials. Annals of WULS, Forestry and Wood Technology 109, pages 64-69.
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Boxiang Wang, Zhenhua Wang, Zengbin Yin, Juntang Yuan & Jiheng Jia. (2020) Preparation and properties of the VC/Cr3C2/TaC doped ultrafine WC-Co tool material by spark plasma sintering. Journal of Alloys and Compounds 816, pages 152598.
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Igor L. ShabalinIgor L. Shabalin. 2020. Ultra-High Temperature Materials III. Ultra-High Temperature Materials III 515 707 .
José García, Verónica Collado Ciprés, Andreas Blomqvist & Bartek Kaplan. (2019) Cemented carbide microstructures: a review. International Journal of Refractory Metals and Hard Materials 80, pages 40-68.
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S. Farag, I. Konyashin & B. Ries. (2018) The influence of grain growth inhibitors on the microstructure and properties of submicron, ultrafine and nano-structured hardmetals – A review. International Journal of Refractory Metals and Hard Materials 77, pages 12-30.
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I-Ting Ho, Yung-Ta Chen, An-Chou Yeh, Chih-Peng Chen & Kuo-Kuang Jen. (2018) Microstructure evolution induced by inoculants during the selective laser melting of IN718. Additive Manufacturing 21, pages 465-471.
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Hao Chen, Qiumin Yang, Jiangao Yang, Hailin Yang, Liyong Chen, Jianming Ruan & Qizhong Huang. (2017) Effects of VC/Cr 3 C 2 on WC grain morphologies and mechanical properties of WC-6wt.%Co cemented carbides. Journal of Alloys and Compounds 714, pages 245-250.
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Xiao-Ou Yi, Xiang Huang, Chang-Bin Liu, Dan-Qing Yi, Yong Jiang, Bin Wang, Hui-Qun Liu & Li-Yong Chen. (2016) Effect of Cooling Rate on the Formation and Morphology of (W,V)C x in VC-doped WC–Co Cemented Carbide. Acta Metallurgica Sinica (English Letters) 30:2, pages 146-155.
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K. Okada & A. Osada. (2017) Microstructural study on the grain growth inhibition of VC-doped WC-Co cemented carbides. International Journal of Refractory Metals and Hard Materials 62, pages 149-154.
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Sven A.E. Johansson & G. Wahnström. (2016) First-principles derived complexion diagrams for phase boundaries in doped cemented carbides. Current Opinion in Solid State and Materials Science 20:5, pages 299-307.
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Lukas Lauter, Roman Hochenauer, Christoph Buchegger, Marcel Bohn & Walter Lengauer. (2016) Solid-state solubilities of grain-growth inhibitors in WC-Co and WC-MC-Co hardmetals. Journal of Alloys and Compounds 675, pages 407-415.
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Weiteng Guo, Kai Li, Yong Du, Zhongjian Zhang, Tao Xu, Chao Yin, Zhuo Zhang, Peng Zhou, Xiangzhong Liu & Baiyun Huang. (2016) Microstructure and composition of segregation layers at WC/Co interfaces in ultrafine-grained cemented carbides co-doped with Cr and V. International Journal of Refractory Metals and Hard Materials 58, pages 68-73.
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Hongtao Wang, Tim Webb & Jonathan W. Bitler. (2015) Different effects of Cr3C2 and VC on the sintering behavior of WC–Co materials. International Journal of Refractory Metals and Hard Materials 53, pages 117-122.
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I. Sugiyama, Y. Mizumukai, T. Taniuchi, K. Okada, F. Shirase, T. Tanase, Y. Ikuhara & T. Yamamoto. (2015) Carbon content dependence of grain growth mode in VC-doped WC–Co hardmetals. International Journal of Refractory Metals and Hard Materials 52, pages 245-251.
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Masaru Kawakami & Kozo Kitamura. (2015) Segregation layers of grain growth inhibitors at WC/WC interfaces in VC-doped submicron-grained WC–Co cemented carbides. International Journal of Refractory Metals and Hard Materials 52, pages 229-234.
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Christoph Buchegger, Walter Lengauer, Johannes Bernardi, Jakob Gruber, Theo Ntaflos, Franz Kiraly & Jessica Langlade. (2015) Diffusion parameters of grain-growth inhibitors in WC based hardmetals with Co, Fe/Ni and Fe/Co/Ni binder alloys. International Journal of Refractory Metals and Hard Materials 49, pages 67-74.
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Masaru KawakamiKozo Kitamura. (2015) Segregation of Dopants at WC/Co and WC/WC Interfaces in Solid-State-Sintered WC-VC-Cr<sub>3</sub>C<sub>2</sub>-Co Cemented Carbides. MATERIALS TRANSACTIONS 56:11, pages 1880-1886.
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Hui Wang, Meiqin Zeng, Jiangwen Liu, Zhongcheng Lu, Zhenhua Shi, Liuzhang Ouyang & Min Zhu. (2015) One-step synthesis of ultrafine WC–10Co hardmetals with VC/V2O5 addition by plasma assisted milling. International Journal of Refractory Metals and Hard Materials 48, pages 97-101.
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S. Norgren, J. García, A. Blomqvist & L. Yin. (2015) Trends in the P/M hard metal industry. International Journal of Refractory Metals and Hard Materials 48, pages 31-45.
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I. Sugiyama, Y. Mizumukai, T. Taniuchi, K. Okada, F. Shirase, T. Tanase, Y. Ikuhara & T. Yamamoto. (2013) Three-dimensional morphology of (W,V)C in VC-doped WC–Co hard metals. Scripta Materialia 69:6, pages 473-476.
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Li Zhang, Ming-wei Xie, Xin Cheng, Qing Nan, Zhe Wang & Yu-ping Feng. (2013) Micro characteristics of binder phases in WC–Co cemented carbides with Cr–V and Cr–V–RE additives. International Journal of Refractory Metals and Hard Materials 36, pages 211-219.
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S. A. E. Johansson & G. Wahnström. (2012) First-principles study of an interfacial phase diagram in the V-doped WC-Co system. Physical Review B 86:3.
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S. Lay, M. Loubradou, S. A. E. Johansson & G. Wahnström. (2011) Interface structure in a WC–Co alloy co-doped with VC and Cr3C2. Journal of Materials Science 47:3, pages 1588-1593.
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I. Sugiyama, Y. Mizumukai, T. Taniuchi, K. Okada, F. Shirase, T. Tanase, Y. Ikuhara & T. Yamamoto. (2012) Formation of (W,V)C layers at the WC/Co interfaces in the VC-doped WC–Co cemented carbide. International Journal of Refractory Metals and Hard Materials 30:1, pages 185-187.
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I. Sugiyama, M. Goto, T. Taniuchi, F. Shirase, T. Tanase, K. Okada, Y. Ikuhara & T. Yamamoto. (2011) Blunt corners of WC grains induced by lowering carbon content in WC–12mass%Co cemented carbides. Journal of Materials Science 46:12, pages 4413-4419.
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Jonathan Weidow & Hans-Olof Andrén. (2011) APT analysis of WC–Co based cemented carbides. Ultramicroscopy 111:6, pages 595-599.
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F.J.J. Kellner, M.S. Killian, G. Yang, E. Spiecker & S. Virtanen. (2011) TEM and ToF-SIMS studies on the corrosion behavior of vanadium and chromium containing WC–Co hard metals in alkaline solutions. International Journal of Refractory Metals and Hard Materials 29:3, pages 376-383.
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Takahisa YAMAMOTO. (2011) Nano/sub-nano analysis based on high resolution transmission electron microscopy for ceramic materials. Journal of the Ceramic Society of Japan 119:1385, pages 8-15.
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Jonathan Weidow & Hans-Olof Andrén. (2011) Grain and phase boundary segregation in WC–Co with TiC, ZrC, NbC or TaC additions. International Journal of Refractory Metals and Hard Materials 29:1, pages 38-43.
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Sabine Lay, Patricia Donnadieu & Marc Loubradou. (2010) Polarity of prismatic facets delimiting WC grains in WC–Co alloys. Micron 41:5, pages 472-477.
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A.S. Bolokang. (2009) A comparison of the mechanically alloyed (V,W)C and (V,W)C–Co powders. Journal of Alloys and Compounds 477:1-2, pages 905-908.
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Z. Zak Fang, Xu Wang, Taegong Ryu, Kyu Sup Hwang & H.Y. Sohn. (2009) Synthesis, sintering, and mechanical properties of nanocrystalline cemented tungsten carbide – A review. International Journal of Refractory Metals and Hard Materials 27:2, pages 288-299.
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Y. Yamanaka, T. Taniuchi, F. Shirase, T. Tanase, Y. Ikuhara & T. Yamamoto. (2009) High Resolution Electron Microscopy Study in ZrC-Doped WC-12 mass%Co Alloys. MATERIALS TRANSACTIONS 50:5, pages 1096-1101.
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Teruyoshi Tanase. (2007) Development of High Performance Carbide Tools. Journal of the Japan Society of Powder and Powder Metallurgy 54:4, pages 243-250.
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Mikael Christensen & Göran Wahnström. (2006) Strength and reinforcement of interfaces in cemented carbides. International Journal of Refractory Metals and Hard Materials 24:1-2, pages 80-88.
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Z. Fang, P. Maheshwari, X. Wang, H.Y. Sohn, A. Griffo & R. Riley. (2005) An experimental study of the sintering of nanocrystalline WC–Co powders. International Journal of Refractory Metals and Hard Materials 23:4-6, pages 249-257.
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A. Delanoë, M. Bacia, E. Pauty, S. Lay & C.H. Allibert. (2004) Cr-rich layer at the WC/Co interface in Cr-doped WC–Co cermets: segregation or metastable carbide?. Journal of Crystal Growth 270:1-2, pages 219-227.
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