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Philosophical Magazine Volume 87, 2007 - Issue 28
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Original Articles

Atomistic model of physical ageing in Se-rich As–Se glasses

R. Golovchak Lviv Scientific Research Institute of Materials of SRC “Carat”, 202, Stryjska Str., Lviv, UA, 79031, Ukraine; Department of Materials Science and Engineering, Lehigh University, 5, East Packer Avenue, Bethlehem, PA, 18015-3195, USACorrespondence[email protected]
,
O. Shpotyuk Lviv Scientific Research Institute of Materials of SRC “Carat”, 202, Stryjska Str., Lviv, UA, 79031, Ukraine; Department of Materials Science and Engineering, Lehigh University, 5, East Packer Avenue, Bethlehem, PA, 18015-3195, USA; Institute of Physics of Jan Dlugosz University, 13/15, al. Armii Krajowej, Czestochowa, 42201, Poland
,
A. Kozdras Faculty of Physics of Opole University of Technology, 75, Ozimska Str., Opole, 45370, Poland
,
B. Bureau Laboratoire des Verres et Ceramiques UMR-CNRS 6512, University of Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France
,
M. Vlček Department of General and Inorganic Chemistry, FCHT, University of Pardubice, Pardubice, 532 10, Czech Republic
,
A. Ganjoo Department of Materials Science and Engineering, Lehigh University, 5, East Packer Avenue, Bethlehem, PA, 18015-3195, USA
&
H. Jain Department of Materials Science and Engineering, Lehigh University, 5, East Packer Avenue, Bethlehem, PA, 18015-3195, USA
 show all
Pages 4323-4334 | Received 05 Jan 2007, Accepted 23 May 2007, Published online: 28 Aug 2007

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J. Grenet, E. Bouthegourd, A. Esposito, A. Saiter & J.M. Saiter. (2013) Is the configurational entropic model able to predict the final equilibrium state reached by Se glasses after very long ageing durations?. Philosophical Magazine 93:22, pages 2932-2946.
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R. Golovchak, A. Ingram, A. Kozdras, M. Vlcek, C. Roiland, B. Bureau & O. Shpotyuk. (2012) Initial stage of physical ageing in network glasses. Philosophical Magazine 92:33, pages 4182-4193.
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Articles from other publishers (56)

S.K. Mohamed, M.M. Abd El-Raheem, M.M. Wakkad, A.M. Abdel Hakeeam & H.F. Mohamed. (2023) Structural, optical, and electrical characteristics of Ge18Bi4Se78 chalcogenide glass for optoelectronic applications. Memories - Materials, Devices, Circuits and Systems 6, pages 100085.
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S.K. Pal, N. Mehta, V.I. Mikla, A.A. Horvat, V.V. Minkovich & A. Dahshan. (2021) Response to “Comment on ‘Insights into the physical aging in chalcogenide glasses: A case study of a first-generation As2Se3 binary glass’” [Coord. Chem. Rev. 442 (2021) 213992]. Coordination Chemistry Reviews 449, pages 214205.
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Shiv Kumar Pal, Neeraj Mehta, V.I. Mikla, A.A. Horvat, V.V. Minkovich & A. Dahshan. (2021) Insights into the physical aging in chalcogenide glasses: A case study of a first-generation As2Se3 binary glass. Coordination Chemistry Reviews 442, pages 213992.
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Hiroyuki Ikemoto & Takafumi Miyanaga. (2021) Structure study of the chalcogens and chalcogenides by X-ray absorption fine structure. Zeitschrift für Physikalische Chemie 235:1-2, pages 117-140.
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S.K. Pal, N. Mehta, V.I. Mikla, A.A. Horvat & V.V. Minkovich. (2021) Addendum to “Some novel results of physical aging studies in glassy Selenium” [Mater. Sci. Eng. 259 (2020) 114598]. Materials Science and Engineering: B 263, pages 114802.
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Adyasha Aparimita, Mukta Behera, C. Sripan, R. Ganesan, Shuvendu Jena & Ramakanta Naik. (2018) Effect of Bi addition on the optical properties of Ge30Se70-xBix thin films. Journal of Alloys and Compounds 739, pages 997-1004.
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P. Knotek, P. Kutálek, M. Vlasová, E. Černošková, P. Janíček, Z. Černošek & L. Tichý. (2017) Ageing of Ge24.9Sb11.6S63.5 thin films under various conditions. Materials Chemistry and Physics 195, pages 236-246.
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R Golovchak, A Kozdras, O Shpotyuk & V Balitska. (2016) Crossover between cooperative and fractal relaxation in complex glass-formers. Journal of Physics: Condensed Matter 28:35, pages 355101.
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Matthieu Micoulaut. (2016) Relaxation and physical aging in network glasses: a review. Reports on Progress in Physics 79:6, pages 066504.
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O. Shpotyuk, M. Hyla & V. Boyko. (2015) Compositionally-dependent structural variations in glassy chalcogenides: The case of binary AsSe system. Computational Materials Science 110, pages 144-151.
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Omar A. Lafi, Mousa M.A. Imran, Hassan K. Juwhari & Ma'rouf K. Abdullah. (2015) Investigation of physical ageing effect in Se 90 In 4 Sn 6 glass. Radiation Physics and Chemistry 112, pages 1-5.
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O. Shpotyuk, A. Ingram, R. Szatanik, M. Shpotyuk & R. Golovchak. (2015) Structural-relaxation phenomena in As–S glasses as probed by combined PAL/DBAR technique. Materials Chemistry and Physics 155, pages 76-82.
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O. Shpotyuk, S. A. Kozyukhin, M. Shpotyuk, A. Ingram & R. Szatanik. (2015) Positronics of radiation-induced effects in chalcogenide glassy semiconductors. Semiconductors 49:3, pages 298-304.
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R. Golovchak, P. Lucas, J. Oelgoetz, A. Kovalskiy, J. York-Winegar, Ch Saiyasombat, O. Shpotyuk, M. Feygenson, J. Neuefeind & H. Jain. (2015) Medium range order and structural relaxation in As–Se network glasses through FSDP analysis. Materials Chemistry and Physics 153, pages 432-442.
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Ramakanta Naik, E M Vinod, Sanjit Parida, R Ganesan & K S Sangunni. (2015) Photo induced effects on the optical properties of As 20 Sb 20 S 60 thin films . IOP Conference Series: Materials Science and Engineering 73, pages 012045.
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O. Shpotyuk, V. Balitska, A. Kozdras, A. S. Hacinliyan, Y. Skarlatos, I. Kusbeyzi Aybar & O. O. Aybar. (2014) Chaotic behavior of light-assisted physical aging in arsenoselenide glasses. Chaos: An Interdisciplinary Journal of Nonlinear Science 24:4.
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O. Shpotyuk, B. Bureau, V. Boyko, A. Ingram, R. Golovchak & C. Roiland. (2014) Long-term natural physical aging in glassy Ge5Se95 as probed by combined NMR and PAL spectroscopy. Journal of Non-Crystalline Solids 392-393, pages 1-5.
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R. Golovchak, J. Oelgoetz, M. Vlcek, A. Esposito, A. Saiter, J.-M. Saiter & H. Jain. (2014) Complex structural rearrangements in As-Se glasses. The Journal of Chemical Physics 140:5.
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V. Balitska, R. Golovchak, A. Kozdras & O. Shpotyuk. (2014) Fine kinetics of natural physical ageing in glassy As10Se90. Physica B: Condensed Matter 434, pages 21-25.
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A.S. Hacinliyan, Y. Skarlatos, I. Kusbeyzi Aybar, O.O. Aybar, O. Shpotyuk, R. Golovchak, V. Balitska & A. Kozdras. (2014) Natural physical aging in glassy As–Se: A comparative study of chaotic behavior with enhanced results analysis. Journal of Non-Crystalline Solids 386, pages 8-13.
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B. Bureau. 2014. Chalcogenide Glasses. Chalcogenide Glasses 36 57 .
O. Shpotyuk, R. Golovchak & A. Kozdras. 2014. Chalcogenide Glasses. Chalcogenide Glasses 209 264 .
A.A.A. Darwish. (2014) Photoinduced effect in nanostructured InSe thin films for Photonic applications. Optics Communications 310, pages 104-108.
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Cz. Górecki & T. Górecki. (2013) The kinetics of phase transitions in vitreous chalcogenide semiconductors As10.2Se89.8 and As9Se90Bi in early stage of physical ageing process. Journal of Thermal Analysis and Calorimetry 114:2, pages 725-729.
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R. Golovchak, A. Ingram, S. Kozyukhin & O. Shpotyuk. (2013) Free volume fragmentation in glassy chalcogenides during natural physical ageing as probed by PAL spectroscopy. Journal of Non-Crystalline Solids 377, pages 49-53.
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R. Golovchak, A. Kovalskiy, O. Shpotyuk & H. Jain. (2013) Structural organization of As-rich selenide glasses. Solid State Communications 165, pages 22-26.
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H.Y. Zhao, Y.P. Koh, M. Pyda, S. Sen & S.L. Simon. (2013) The kinetics of the glass transition and physical aging in germanium selenide glasses. Journal of Non-Crystalline Solids 368, pages 63-70.
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Valentina Balitska, Roman Golovchak & Oleh Shpotyuk. (2013) On the Kinetics Description of Below-T<sub>g</sub> Structural Relaxation in Network Glass Formers. Solid State Phenomena 200, pages 162-167.
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Yun Mui Yiu, Gurinder Kaur, Qunfeng Xiao & Tsun Kong Sham. (2013) Ab-initio calculation of the As and Se L3,2-edge XANES of As2Se3 and Zn-doped As2Se3 and comparison to the experiments. Journal of Non-Crystalline Solids 364, pages 13-19.
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Roman Svoboda & Jiří Málek. (2013) Structural relaxation in Se-rich As–Se glasses. Journal of Non-Crystalline Solids 363, pages 89-95.
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Kateryna Sykina, Guang Yang, Claire Roiland, Laurent Le Pollès, Eric Le Fur, Chris J. Pickard, Bruno Bureau & Eric Furet. (2013) 77Se solid-state NMR of As2Se3, As4Se4 and As4Se3 crystals: a combined experimental and computational study. Physical Chemistry Chemical Physics 15:17, pages 6284.
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R Golovchak, A Kozdras, V Balitska & O Shpotyuk. (2012) Step-wise kinetics of natural physical ageing in arsenic selenide glasses. Journal of Physics: Condensed Matter 24:50, pages 505106.
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V. Balitska, R. Golovchak & O. Shpotyuk. (2012) On the kinetics description of below-T<inf>g</inf> structural relaxation in network glass formers. On the kinetics description of below-T<inf>g</inf> structural relaxation in network glass formers.
Ramakanta Naik, Sanjit K. Parida, C. Kumar, R. Ganesan & K.S. Sangunni. (2012) Optical properties change in Sb40S40Se20 thin films by light-induced effect. Journal of Alloys and Compounds 522, pages 172-177.
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Adam Ingram, Andrzej Kozdras, Oleh Shpotyuk & Roman Golovchak. (2012) PAL signature of physical ageing in chalcogenide glasses. physica status solidi (b) 249:5, pages 1017-1019.
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A.A. Elabbar & A.A. Abu-Sehly. (2011) Structural relaxation and rigidity transition in aged and rejuvenated AsxSe100−x glasses. Physica B: Condensed Matter 406:22, pages 4261-4265.
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Andrzej Kozdras, Roman Golovchak, Oleh Shpotyuk, Stefan Szymura, Allisson Saiter & Jean-Marc Saiter. (2011) Light-assisted physical aging in chalcogenide glasses: Dependence on the wavelength of incident photons. Journal of Materials Research 26:18, pages 2420-2427.
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M. Deschamps, C. Roiland, B. Bureau, G. Yang, L. Le Pollès & D. Massiot. (2011) 77Se solid-state NMR investigations on AsxSe1−x glasses using CPMG acquisition under MAS. Solid State Nuclear Magnetic Resonance 40:2, pages 72-77.
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Roman Golovchak, Andriy Kovalskiy, Oleh Shpotyuk & Himanshu Jain. (2011) In search of energy landscape for network glasses. Applied Physics Letters 98:17.
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G. Delaizir, M. Dussauze, V. Nazabal, P. Lecante, M. Dollé, P. Rozier, E.I. Kamitsos, P. Jovari & B. Bureau. (2011) Structural characterizations of As–Se–Te glasses. Journal of Alloys and Compounds 509:3, pages 831-836.
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R. Golovchak, O. Shpotyuk, A. Kozdras, B. J. Riley, S. K. Sundaram & J. S. McCloy. (2010) Radiation effects in physical aging of binary As–S and As–Se glasses. Journal of Thermal Analysis and Calorimetry 103:1, pages 213-218.
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Guang Yang, Bruno Bureau, Tanguy Rouxel, Yann Gueguen, Ozgur Gulbiten, Claire Roiland, Emmanuel Soignard, Jeffery L. Yarger, Johann Troles, Jean-Christophe Sangleboeuf & Pierre Lucas. (2010) Correlation between structure and physical properties of chalcogenide glasses in the system . Physical Review B 82:19.
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R. Ya. Golovchak, S. A. Kozyukhin, A. Kozdras, O. I. Shpotyuk & V. M. Novotortsev. (2010) Physical aging of chalcogenide glasses. Inorganic Materials 46:8, pages 911-913.
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Sachinkumar Dagurao Pangavhane, Petr Němec, Tomáš Wagner, Jan Janča & Josef Havel. (2010) Laser desorption ionization time-of-flight mass spectrometric study of binary As-Se glasses. Rapid Communications in Mass Spectrometry 24:14, pages 2000-2008.
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M.A. Al-Ewaisi, Mousa M.A. Imran, Omar A. Lafi & Moh'd W. Kloub. (2010) Effect of gamma irradiation on some electrical properties and optical band gap of bulk Se92Sn8 chalcogenide glass. Physica B: Condensed Matter 405:12, pages 2643-2647.
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Mousa M.A. Imran & Ali F. Al-Shawabkeh. (2010) Structural relaxation due to sub-Tg annealing of Se98In1.5Sn0.5 chalcogenide glass. Journal of Alloys and Compounds 500:2, pages 237-240.
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R. Golovchak, A. Kozdras & O. Shpotyuk. (2010) Optical signature of structural relaxation in glassy As10Se90. Journal of Non-Crystalline Solids 356:23-24, pages 1149-1152.
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Omar A. Lafi & Mousa M.A. Imran. (2010) The effect of gamma irradiation on glass transition temperature and thermal stability of Se96Sn4 chalcogenide glass. Radiation Physics and Chemistry 79:1, pages 104-108.
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R. Golovchak, A. Kozdras, S. Kozyukhin & O. Shpotyuk. (2009) High-energy γ-irradiation effect on physical ageing in Ge–Se glasses. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 267:17, pages 2958-2961.
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Roman Golovchak, Andrzej Kozdras, Oleh Shpotyuk, Sergey Kozyukhin & Jean-Marc Saiter. (2009) Long-term ageing behaviour in Ge–Se glasses. Journal of Materials Science 44:15, pages 3962-3967.
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Bryan A. Demko & Roderick E. Wasylishen. (2009) Solid-state selenium-77 NMR. Progress in Nuclear Magnetic Resonance Spectroscopy 54:3-4, pages 208-238.
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A Saiter, J-M Saiter, R Golovchak, M Shpotyuk & O Shpotyuk. (2009) Cooperative rearranging region size and free volume in As–Se glasses. Journal of Physics: Condensed Matter 21:7, pages 075105.
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O. Shpotyuk, M. Hyla, V. Boyko & R. Golovchak. (2008) Reversibility windows in selenide-based chalcogenide glasses. Physica B: Condensed Matter 403:19-20, pages 3830-3837.
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Mousa M.A. Imran, Ibrahim F. Al-Hamarneh, M.I. Awadallah & M.A. Al-Ewaisi. (2008) Physical ageing in Se94Sn6 glass induced by gamma irradiation. Physica B: Condensed Matter 403:17, pages 2639-2642.
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R Golovchak, O Shpotyuk, A Kozdras, M Vlček, B Bureau, A Kovalskiy & H Jain. (2008) Long-term physical ageing in As–Se glasses with short chalcogen chains. Journal of Physics: Condensed Matter 20:24, pages 245101.
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R.Ya. Golovchak, A. Kozdras & O.I. Shpotyuk. (2008) Physical ageing in glassy As–Se induced by above-bandgap photoexposure. Solid State Communications 145:9-10, pages 423-426.
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