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Philosophical Magazine Volume 90, 2010 - Issue 1-4: Phase Transformations, Microstructure Evolution and Deformation
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Original Articles

Thermodynamics of polar anisotropy in morphotropic ferroelectric solid solutions

A.A. Heitmann Materials Science and Engineering Program and Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA
&
G.A. Rossetti Jr. Materials Science and Engineering Program and Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USACorrespondence[email protected]
Pages 71-87 | Received 13 Jan 2009, Accepted 14 Mar 2009, Published online: 01 Sep 2009

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Daniel J Franzbach, Yo-Han Seo, Andrew J Studer, Yichi Zhang, Julia Glaum, John E Daniels, Jurij Koruza, Andreja Benčan, Barbara Malič & Kyle G Webber. (2014) Electric-field-induced phase transitions in co-doped Pb(Zr1−xTix)O3 at the morphotropic phase boundary. Science and Technology of Advanced Materials 15:1.
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A.A. Heitmann & G.A. Rossetti$suffix/text()$suffix/text(). (2011) Polar Anisotropy and Inter-Ferroelectric Transitions in Barium Titanate and its Solid Solutions. Integrated Ferroelectrics 126:1, pages 155-165.
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Articles from other publishers (34)

Peter Finkel, Chris Lynch & Ahmed Amin. (2023) Transduction modality near instability in domain engineered relaxor ferroelectric single crystals. Smart Materials and Structures 33:1, pages 013001.
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Soumya Bandyopadhyay, Vaishnavi S. M., Tushar Jogi, Ranjith Ramadurai & Saswata Bhattacharyya. (2023) Role of electrostriction on domain switching near the morphotropic phase region in a ferroelectric solid solution: Thermodynamic analysis and phase-field simulations. Physical Review B 108:13.
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Richard Pérez‐Moyet, Yenny Cardona‐Quintero, Ian M. Doyle & Adam A. Heitmann. (2023) Anisotropy free energy contribution of the ferroelectric domain dynamics in PMN‐PT and PIN‐PMN‐PT relaxor ferroelectrics. Journal of the American Ceramic Society 106:9, pages 5522-5540.
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Saswata Bhattacharyya & Soumya Bandyopadhyay. 2023. Strain Engineering in Functional Materials and Devices. Strain Engineering in Functional Materials and Devices 6-1 6-28 .
M.V. Gorev, V.S. Bondarev, I.N. Flerov, K. Bormanis & E. Birks. (2022) T − E phase diagrams and electrocaloric effect in PNN-PT solid solutions. Journal of Alloys and Compounds 927, pages 167032.
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Oscar A. Torres-Matheus, R. Edwin García & Catherine M. Bishop. (2021) Microstructural phase coexistence kinetics near the polymorphic phase boundary. Acta Materialia 206, pages 116579.
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Haijun Wu, Yang Zhang, Jiagang Wu, John Wang & Stephen J. Pennycook. (2019) Microstructural Origins of High Piezoelectric Performance: A Pathway to Practical Lead‐Free Materials. Advanced Functional Materials 29:33, pages 1902911.
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Dragan Damjanovic & George A. RossettiJr.Jr.. (2018) Strain generation and energy-conversion mechanisms in lead-based and lead-free piezoceramics. MRS Bulletin 43:8, pages 588-594.
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Ling Li, Mankang Zhu, Qiumei Wei, Mupeng Zheng, Yudong Hou & Jigong Hao. (2018) Ferroelectric P4mm to relaxor P4bm transition and temperature-insensitive large strains in Bi(Mg0.5Ti0.5)O3-modified tetragonal 0.875Bi0.5Na0.5TiO3-0.125BaTiO3 lead-free ferroelectric ceramics. Journal of the European Ceramic Society 38:4, pages 1381-1388.
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Ruihao Yuan, Zhen Liu, Prasanna V. Balachandran, Deqing Xue, Yumei Zhou, Xiangdong Ding, Jun Sun, Dezhen Xue & Turab Lookman. (2018) Accelerated Discovery of Large Electrostrains in BaTiO 3 ‐Based Piezoelectrics Using Active Learning . Advanced Materials 30:7, pages 1702884.
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M. Acosta, N. Novak, V. Rojas, S. Patel, R. Vaish, J. Koruza, G. A. RossettiJr.Jr. & J. Rödel. (2017) BaTiO3-based piezoelectrics: Fundamentals, current status, and perspectives. Applied Physics Reviews 4:4.
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Peng Lv, Linghang Wang & Christopher S. Lynch. (2017) A phenomenological thermodynamic energy function for PIN-PMN-PT relaxor ferroelectric single crystals. Acta Materialia 137, pages 93-102.
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Hwang-Pill Kim, Chang Won Ahn, Younghun Hwang, Ho-Yong Lee & Wook Jo. (2017) Strategies of A Potential Importance, Making Lead-Free Piezoceramics Truly Alternative to PZTs. Journal of the Korean Ceramic Society 54:2, pages 86-95.
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Soumya Bandyopadhyay, Tushar Jogi, Kumaraswamy Miriyala, Ranjith Ramadurai & Saswata Bhattacharyya. (2016) A phase-field study of domain dynamics in ferroelectric BCT-BZT system. MRS Advances 1:40, pages 2783-2788.
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Chang-Hyo Hong, Hwang-Pill Kim, Byung-Yul Choi, Hyoung-Su Han, Jae Sung Son, Chang Won Ahn & Wook Jo. (2016) Lead-free piezoceramics – Where to move on?. Journal of Materiomics 2:1, pages 1-24.
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Matias AcostaMatias Acosta. 2016. Strain Mechanisms in Lead-Free Ferroelectrics for Actuators. Strain Mechanisms in Lead-Free Ferroelectrics for Actuators 77 149 .
Matias AcostaMatias Acosta. 2016. Strain Mechanisms in Lead-Free Ferroelectrics for Actuators. Strain Mechanisms in Lead-Free Ferroelectrics for Actuators 7 42 .
Matias Acosta, Nikola Novak, George A. RossettiJr.Jr. & Jürgen Rödel. (2015) Mechanisms of electromechanical response in (1 − x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 ceramics. Applied Physics Letters 107:14.
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P. Finkel, M. Staruch, A. Amin, M. Ahart & S.E. Lofland. (2015) Simultaneous Stress and Field Control of Sustainable Switching of Ferroelectric Phases. Scientific Reports 5:1.
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Xiaoyan Lu, Limei Zheng, Hui Li & Wenwu Cao. (2015) Theoretical study on phase coexistence in ferroelectric solid solutions near the tricritical point. Journal of Applied Physics 117:13.
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Matias Acosta, Nasser Khakpash, Takumi Someya, Nikola Novak, Wook Jo, Hajime Nagata, George A. Rossetti & Jürgen Rödel. (2015) Origin of the large piezoelectric activity in ceramics . Physical Review B 91:10.
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Adam A. Heitmann & George A. RossettiJr.Jr.. (2014) Thermodynamics of Ferroelectric Solid Solutions with Morphotropic Phase Boundaries. Journal of the American Ceramic Society 97:6, pages 1661-1685.
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Yang Zhang, Dezhen Xue, Haijun Wu, Xiangdong Ding, Turab Lookman & Xiaobing Ren. (2014) Adaptive ferroelectric state at morphotropic phase boundary: Coexisting tetragonal and rhombohedral phases. Acta Materialia 71, pages 176-184.
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Guru Subramanyam, M. W. Cole, Nian X. Sun, Thottam S. Kalkur, Nick M. Sbrockey, Gary S. Tompa, Xiaomei Guo, Chonglin Chen, S. P. Alpay, G. A. RossettiJr.Jr., Kaushik Dayal, Long-Qing Chen & Darrell G. Schlom. (2013) Challenges and opportunities for multi-functional oxide thin films for voltage tunable radio frequency/microwave components. Journal of Applied Physics 114:19.
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Yo-Han Seo, Daniel J. Franzbach, Jurij Koruza, Andreja Benčan, Barbara Malič, Marija Kosec, Jacob L. Jones & Kyle G. Webber. (2013) Nonlinear stress-strain behavior and stress-induced phase transitions in soft Pb(Zr Ti )O at the morphotropic phase boundary . Physical Review B 87:9.
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Dezhen Xue, Yumei Zhou, Jinghui Gao, Xiangdong Ding & Xiaobing Ren. (2012) A comparison between tetragonal-rhombohedral and tetragonal-orthorhombic phase boundaries on piezoelectricity enhancement. EPL (Europhysics Letters) 100:1, pages 17010.
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Wen D Dong, David M Pisani & Christopher S Lynch. (2012) A finite element based phase field model for ferroelectric domain evolution. Smart Materials and Structures 21:9, pages 094014.
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Haijun Wu, Dezhen Xue, Duchao Lv, Jinghui Gao, Shengwu Guo, Yumei Zhou, Xiangdong Ding, Chao Zhou, Sen Yang, Yaodong Yang & Xiaobing Ren. (2012) Microstructure at morphotropic phase boundary in Pb(Mg1/3Nb2/3)O3-PbTiO3 ceramic: Coexistence of nano-scaled {110}-type rhombohedral twin and {110}-type tetragonal twin. Journal of Applied Physics 112:5.
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Yong Ni & Armen G. Khachaturyan. (2012) Giant anhysteretic response of ferroelectric solid solutions with morphotropic boundaries: the role of polar anisotropy. Acta Mechanica Solida Sinica 25:4, pages 429-440.
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William S Oates, Hongbo Wang & Robert L Sierakowski. (2012) Unusual field-coupled nonlinear continuum mechanics of smart materials. Journal of Intelligent Material Systems and Structures 23:5, pages 487-504.
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Roland Schierholz & Hartmut Fuess. (2011) Symmetry of domains in morphotropic PbZr Ti O ceramics . Physical Review B 84:6.
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Daisuke Kan, Varatharajan Anbusathaiah & Ichiro Takeuchi. (2011) Chemical Substitution-Induced Ferroelectric Polarization Rotation in BiFeO3. Advanced Materials 23:15, pages 1765-1769.
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Chaoye Wu, Wenhui Duan, Xiao-Wen Zhang & Zhirong Liu. (2010) Effects of hydrostatic pressure on Pb(Zr1−xTix)O3 near the morphotropic phase boundary. Journal of Applied Physics 108:12.
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Peter Finkel, Harold Robinson, Joseph Stace & Ahmed Amin. (2010) Study of phase transitions in ternary lead indium niobate-lead magnesium niobate-lead titanate relaxor ferroelectric morphotropic single crystals. Applied Physics Letters 97:12.
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