75
Views
40
CrossRef citations to date
0
Altmetric
Original Articles

Toward the Development of a General Framework for Modeling Molecular Weight and Compositional Changes in Free-Radical Copolymerization Reactions

&
Pages 183-234 | Published online: 23 Sep 2006

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (3)

J. Gao & A. Penlidis. (1998) A Comprehensive Simulator/Database Package for Reviewing Free-Radical Copolymerizations. Journal of Macromolecular Science, Part C 38:4, pages 651-780.
Read now
E. Vivaldo-Lima, A.E. Hamielec & P.E. Wood. (1994) Auto-Acceleration Effect in Free Radical Polymerization. A Comparison of the CCS and MH Models. Polymer Reaction Engineering 2:1-2, pages 17-85.
Read now
Costas Kiparissides, George Verros & JohnF. Macgregor. (1993) Mathematical Modeling, Optimization, and Quality Control of High-Pressure Ethylene Polymerization Reactors. Journal of Macromolecular Science, Part C 33:4, pages 437-527.
Read now

Articles from other publishers (37)

Dhiraj K. Garg, Christophe A. Serra, Yannick Hoarau, Dambarudhar Parida, Michel Bouquey & Rene Muller. (2020) Numerical Investigations of Perfectly Mixed Condition at the Inlet of Free Radical Polymerization Tubular Microreactors of Different Geometries. Macromolecular Theory and Simulations 29:6.
Crossref
Ioannis Tsagkalias, Afrodite Vlachou, George Verros & Dimitris Achilias. (2019) Effect of Graphene oxide or Functionalized Graphene Oxide on the Copolymerization Kinetics of Styrene/n-butyl Methacrylate. Polymers 11:6, pages 999.
Crossref
Marios Michailidis, George D. Verros, Eleni A. Deliyanni, Eleftherios G. Andriotis & Dimitris S. Achilias. (2017) An experimental and theoretical study of butyl methacrylate in situ radical polymerization kinetics in the presence of graphene oxide nanoadditive . Journal of Polymer Science Part A: Polymer Chemistry 55:8, pages 1433-1441.
Crossref
Costas Kiparissides. 2018. Polymer Reaction Engineering of Dispersed Systems. Polymer Reaction Engineering of Dispersed Systems 121 193 .
George D. Verros & Dimitris S. Achilias. (2016) Toward the development of a mathematical model for the bulk in situ radical polymerization of methyl methacrylate in the presence of nano-additives. The Canadian Journal of Chemical Engineering 94:9, pages 1783-1791.
Crossref
Dhiraj K. Garg, Christophe A. Serra, Yannick Hoarau, Dambarudhar Parida, Michel Bouquey & René Muller. (2014) New transformation proposed for improving CFD simulation of free radical polymerization reactions in microreactors. Microfluidics and Nanofluidics 18:5-6, pages 1287-1297.
Crossref
Prokopios Pladis, Konstantina Karidi, Theofanis Mantourlias & Costas Kiparissides. (2014) An Experimental and Theoretical Investigation of the Ring-Opening Polymerization of L , L -Lactide . Macromolecular Reaction Engineering 8:12, pages 813-825.
Crossref
Mohammad Anwar Hosen, Abbas Khosravi, Douglas Creighton & Saeid Nahavandi. (2014) Prediction interval-based modelling of polymerization reactor: A new modelling strategy for chemical reactors. Journal of the Taiwan Institute of Chemical Engineers 45:5, pages 2246-2257.
Crossref
R.A. Hutchinson. 2013. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.
Erich D. Bain, Salomon Turgman‐Cohen & Jan Genzer. (2012) Progress in Computer Simulation of Bulk, Confined, and Surface‐initiated Polymerizations. Macromolecular Theory and Simulations 22:1, pages 8-30.
Crossref
Kiyumars Jalili, Farhang Abbasi & Morteza Nasiri. (2011) Copolymerization of styrene and methyl methacrylate. Part I: Experimental kinetics and mathematical modeling. Polymer 52:19, pages 4362-4376.
Crossref
C. Kiparissides, A. Krallis, D. Meimaroglou, P. Pladis & A. Baltsas. (2010) From Molecular to Plant‐Scale Modeling of Polymerization Processes: A Digital High‐Pressure Low‐Density Polyethylene Production Paradigm. Chemical Engineering & Technology 33:11, pages 1754-1766.
Crossref
Dimitrios Meimaroglou & Costas Kiparissides. (2010) A Novel Stochastic Approach for the Prediction of the Exact Topological Characteristics and Rheological Properties of Highly-Branched Polymer Chains. Macromolecules 43:13, pages 5820-5832.
Crossref
Jurgen Lange, Natalia Davidenko & Roberto Sastre. (2009) Kinetic Study of the Thermopolymerization of Furfuryl Methacrylate in Bulk by Mathematical Modeling. Part A: Simulation of Experimental Data and Sensitivity Analysis of Kinetic Parameters. Macromolecular Theory and Simulations 18:9, pages 511-527.
Crossref
George D. Verros & Dimitris S. Achilias. (2008) Modeling gel effect in branched polymer systems: Free‐radical solution homopolymerization of vinyl acetate. Journal of Applied Polymer Science 111:5, pages 2171-2185.
Crossref
Apostolos Krallis, Dimitrios Meimaroglou & Costas Kiparissides. (2008) Dynamic prediction of the bivariate molecular weight–copolymer composition distribution using sectional-grid and stochastic numerical methods. Chemical Engineering Science 63:17, pages 4342-4360.
Crossref
Dimitrios Meimaroglou, Apostolos Krallis, Vassilis Saliakas & Costas Kiparissides. (2007) Prediction of the Bivariate Molecular Weight - Long Chain Branching Distribution in Highly Branched Polymerization Systems Using Monte Carlo and Sectional Grid Methods. Macromolecules 40:6, pages 2224-2234.
Crossref
Robin A. Hutchinson & Alexander Penlidis. 2007. Polymer Reaction Engineering. Polymer Reaction Engineering 118 178 .
Victor M. Zavala & Lorenz T. Biegler. (2006) Large-Scale Parameter Estimation in Low-Density Polyethylene Tubular Reactors. Industrial & Engineering Chemistry Research 45:23, pages 7867-7881.
Crossref
Costas Kiparissides. (2006) Challenges in particulate polymerization reactor modeling and optimization: A population balance perspective. Journal of Process Control 16:3, pages 205-224.
Crossref
Robin A. Hutchinson. 2005. Handbook of Polymer Reaction Engineering. Handbook of Polymer Reaction Engineering 153 212 .
G.D. Verros, T. Latsos & D.S. Achilias. (2005) Development of a unified framework for calculating molecular weight distribution in diffusion controlled free radical bulk homo-polymerization. Polymer 46:2, pages 539-552.
Crossref
Mário Rui P.F.N. Costa & Rolando C.S. Dias. (2005) An improved general kinetic analysis of non-linear irreversible polymerisations. Chemical Engineering Science 60:2, pages 423-446.
Crossref
Costas Kiparissides. (2004) Challenges in Polymerization Reactor Modeling and Optimization: A Population Balance Perspective. IFAC Proceedings Volumes 37:9, pages 137-154.
Crossref
Anastasios Keramopoulos & Costas Kiparissides. (2003) Mathematical modeling of diffusion‐controlled free‐radical terpolymerization reactions. Journal of Applied Polymer Science 88:1, pages 161-176.
Crossref
A. Keramopoulos & C. Kiparissides. (2002) Development of a Comprehensive Model for Diffusion-Controlled Free-Radical Copolymerization Reactions. Macromolecules 35:10, pages 4155-4166.
Crossref
H. Hatzantonis, H. Yiannoulakis, A. Yiagopoulos & C. Kiparissides. (2000) Recent developments in modeling gas-phase catalyzed olefin polymerization fluidized-bed reactors: The effect of bubble size variation on the reactor's performance. Chemical Engineering Science 55:16, pages 3237-3259.
Crossref
Yao Zhen, Li Bo-geng, Cao Kun, Huang Yuan & Pan Zu-ren. (2000) Modeling for the diffusion limitation of free radical polymerization. Journal of Zhejiang University-SCIENCE A 1:2, pages 148-156.
Crossref
A. Baltsas, E. Papadopoulos & C. Kiparissides. (1998) Application and validation of the pseudo-kinetic rate constant method to high pressure LDPE tubular reactors. Computers & Chemical Engineering 22, pages S95-S102.
Crossref
C. Kiparissides. (1996) Polymerization reactor modeling: A review of recent developments and future directions. Chemical Engineering Science 51:10, pages 1637-1659.
Crossref
Apostolis Baltsas, Dimitris S. Achilias & Costas Kiparissides. (2003) A theoretical investigation of the production of branched copolymers in continuous stirred tank reactors. Macromolecular Theory and Simulations 5:3, pages 477-497.
Crossref
C. Kiparissides, G. Verros, A. Pertsinidis & I. Goossens. (1996) On-line parameter estimation in a high-pressure low-density polyethylene tubular reactor. AIChE Journal 42:2, pages 440-454.
Crossref
C. Kiparissides & J. Morris. (1996) Intelligent manufacturing of polymers. Computers & Chemical Engineering 20, pages S1113-S1118.
Crossref
Klaus‐Dieter Hungenberg & Paul Wittmer. (2003) Application of Markov chains to copolymerizations. Macromolecular Theory and Simulations 4:4, pages 773-800.
Crossref
C. Kiparissides, E. Papadopoulos & J. Morris. 1995. Methods of Model Based Process Control. Methods of Model Based Process Control 495 530 .
D.S. Achilias & C. Kiparissides. (1994) On the validity of the steady-state approximations in high conversion diffusion-controlled free-radical copolymerization reactions. Polymer 35:8, pages 1714-1721.
Crossref
Tuyu Xie & Archie E. Hamielec. (2003) Modelling free‐radical copolymerization kinetics, 3. Molecular weight calculations for copolymers with crosslinking. Macromolecular Theory and Simulations 2:5, pages 777-803.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.