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Solvent Extraction for the Separation of Zr and Hf from Aqueous Solutions

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Pages 199-215 | Received 04 Dec 2013, Accepted 15 Apr 2014, Published online: 10 Sep 2014

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V. Vermaak, H. M. Krieg, L. De Beer & D. Van der Westhuizen. (2018) Mechanistic study of hafnium and zirconium extraction with organophosphorus extractants. Solvent Extraction and Ion Exchange 36:2, pages 150-161.
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Articles from other publishers (27)

Junlian Wang, Hui Liu, Hongru Zhao & Huajun Wang. (2022) Selective extraction of Hf over Zr by a novel extractant (n-octyl)(2,4,4′-trimethylpentyl)phosphinic acid (INET-1) from sulfuric acid media. Journal of Radioanalytical and Nuclear Chemistry 332:7, pages 2473-2485.
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Antoaneta Ene, Hesham M. H. Zakaly, Amany R. Salem, Ayman A. Gouda, Khalid Althumayri, Khaled F. Alshammari, Hamdi A. Awad, Shams A. M. Issa, Ahmad A. Alluhaybi, Salah A. Zaki, Hala A. Ibrahim, Mohamed A. Gado, Enass M. El-Sheikh & Bahig M. Atia. (2022) A New Partially Phosphorylated Polyvinyl Phosphate-PPVP Composite: Synthesis and Its Potentiality for Zr (IV) Extraction from an Acidic Medium. Separations 9:11, pages 382.
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Ting Li, Shishun Dong, Zhaowen Chen, Qifeng Wei & Xiulian Ren. (2022) Breaking through the Separation Barrier of Zr(IV) and Hf(IV): Magical Effect of the Bisamide Ligand. Inorganic Chemistry 61:35, pages 13915-13923.
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Ming Wu, Panfei Dong, Chenjie Wu, Zhenyue Zhang, Ruan Chi & Zhigao Xu. (2022) Separation of Hf(IV) from Zr(IV) in thiocyanate medium with ionic liquid Aliquat 336. Hydrometallurgy 213, pages 105947.
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Cecilia Eiroa-Lledo, Donald E. Wall & Nathalie A. Wall. (2022) Extraction mechanism of Tc(IV) by Di-(2-ethylhexyl)phosphoric acid (HDEHP). Journal of Radioanalytical and Nuclear Chemistry 331:6, pages 2751-2760.
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James A. Sommers, Lauren Palys, Nicolas P. Martin, Dylan B. Fast, Mehran Amiri & May Nyman. (2022) Oxo-Cluster-Based Zr/Hf IV Separation: Shedding Light on a 70-Year-Old Process . Journal of the American Chemical Society 144:6, pages 2816-2824.
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Hanaa A. Abu Khoziem. (2022) Processing of Abu Dob mineralized pegmatites, Central Eastern Desert, Egypt: a study on the kinetics of dissolution process and extraction of some valuable metals. Journal of Radioanalytical and Nuclear Chemistry 331:2, pages 937-951.
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Ming Wu, Fei Xu, Panfei Dong, Hongzhen Wu, Zhiying Zhao, Chenjie Wu, Ruan Chi & Zhigao Xu. (2022) Process for synergistic extraction of Hf(IV) over Zr(IV) from thiocyanic acid solution with TOPO and N1923. Chemical Engineering and Processing - Process Intensification 170, pages 108673.
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Hongyang He, Fei Xu, Qiaolei Li, Panfei Dong, Jian Zheng, Chenjie Wu, Zhengyan He, Jun Qu, Zhigao Xu, Ruan Chi & Ming Wu. (2021) Separation of hafnium from zirconium in HNO3 solution by solvent extraction with Cyanex572. Hydrometallurgy 202, pages 105600.
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Amrita Das, K.R.S. Chandrakumar, Bhaskar Paul, Suresh M. Chopade, Sanjib Majumdar, Ajoy K. Singh & Vivekanand Kain. (2020) Enhanced adsorption and separation of zirconium and hafnium under mild conditions by phosphoric acid based ligand functionalized silica gels: Insights from experimental and theoretical investigations. Separation and Purification Technology 239, pages 116518.
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Jialin Zhao, Ying Sui, Xiujing Peng, Guoxin Sun & Yu Cui. (2020) A new diphosphonic acid extractant N,N-n-octylamine di(methylene phenylphosphinic acid) for extraction and separation of zirconium and hafnium in hydrochloric acid. Journal of Radioanalytical and Nuclear Chemistry 324:1, pages 339-348.
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Janúbia C.B.S. Amaral & Carlos A. Morais. (2020) Equilibrium of zirconium and hafnium in the process of extraction with TBP in nitric medium – Influence in the Zr/Hf separation. Minerals Engineering 146, pages 106138.
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M. V. S. R. Ravi Kanth, S. Pushpavanam, Shankar Narasimhan & Narasimha Murty B. (2019) Unified Framework for Modeling Reactive Extraction of Metals: Illustration on Plutonium(IV) Extraction with Tri- n -butyl Phosphate . Industrial & Engineering Chemistry Research 58:45, pages 20788-20796.
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Taisya Yu. Ekatova & Andrey G. Kazakov. (2019) Extraction-chromatographic behavior of Zr(IV) and Hf(IV) on TRU and LN resins in mixtures of HNO3 and HF. Journal of Radioanalytical and Nuclear Chemistry 321:2, pages 557-563.
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Jialin Zhao, Tao Yang, Hao Zhang, Guoxin Sun & Yu Cui. (2019) Preferential extraction of hafnium over zirconium with D2EHPA through selective complexation of organic acids. Journal of Radioanalytical and Nuclear Chemistry 321:1, pages 333-339.
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Naoya Morohashi, Yutaka Kato, Sahoko Sumida, Yu Kurusu & Tetsutaro Hattori. (2019) Selective Extraction of Zr(IV) over Hf(IV) from Aqueous Hydrochloric Acid with p - tert -Butylcalix[4]arenediphosphonic Acid . Bulletin of the Chemical Society of Japan 92:5, pages 967-972.
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Ming Wu, Hongyang He, Fei Xu, Zhigao Xu, Wenjie Zhang, Zhengyan He, Jun Qu, Ruan Chi & Lingyun Huang. (2019) High-efficient and selective extraction of Hf over Zr with DIBK-P350 synergistic extraction system. Separation and Purification Technology 212, pages 255-261.
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Mochamad L. Firmansyah, Fukiko Kubota, Wataru Yoshida & Masahiro Goto. (2019) Application of a Novel Phosphonium-Based Ionic Liquid to the Separation of Platinum Group Metals from Automobile Catalyst Leach Liquor. Industrial & Engineering Chemistry Research 58:9, pages 3845-3852.
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Tao Yang, Guo-Xin Sun, Yuan Qian, Ji-Fei Ma & Yu-Lan Li. (2019) Separation of hafnium from zirconium in hydrochloric acid solution with di(2-ethylhexyl)phosphoric acid by solvent extraction. Nuclear Science and Techniques 30:2.
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Defeng Guo, Yadan Zhao, Jingtao Li, Kaifang Li, Guosheng Zhang, Ming Li, Bingning Wei, Qian Zhang, Xiaohong Li & Xiangyi Zhang. (2017) Enhancing fracture toughness of fine-grained Zr via forming nanoscale defect structures. Journal of Alloys and Compounds 729, pages 89-94.
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She Chen, Zhifeng Zhang, Shengting Kuang, Yanling Li, Xiaowen Huang & Wuping Liao. (2017) Separation of zirconium from hafnium in sulfate medium using solvent extraction with a new reagent BEAP. Hydrometallurgy 169, pages 607-611.
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Zhigao Xu, Lijun Wang, Ming Wu, Yuanlai Xu, Ruan Chi, Panhong Li & Jun Zhao. (2016) Separation of zirconium and hafnium by solvent extraction using mixture of DIBK and P204. Hydrometallurgy 165, pages 275-281.
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Zhi-gao Xu, Jun Zhao, Li-jun Wang, Yuan-lai Xu, Ru-an Chi, Pan-hong Li & Xin Jin. (2015) Kinetics for extraction of zirconium and hafnium in DIBK-P350 system. Journal of Radioanalytical and Nuclear Chemistry.
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Mohamed H. Mohamed, Lee D. Wilson, Jaimin R. Shah, Jon Bailey, Kerry M. Peru & John V. Headley. (2015) A novel solid-state fractionation of naphthenic acid fraction components from oil sands process-affected water. Chemosphere 136, pages 252-258.
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Le Minh, Nguyen Long, Pham Duong, Youngmi Jung, Alireza Bahadori & Moonyong Lee. (2015) Design of an Extractive Distillation Column for the Environmentally Benign Separation of Zirconium and Hafnium Tetrachloride for Nuclear Power Reactor Applications. Energies 8:9, pages 10354-10369.
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Ling Yun Wang & Man Seung Lee. (2015) Separation of Zr and Hf from sulfuric acid solutions with amine-based extractants by solvent extraction. Separation and Purification Technology 142, pages 83-89.
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Ting li, Shishun Dong, Zhaowen Chen, Qifeng Wei & Xiulian Ren. (2022) Breaking Through the Separation Barrier of Zr(Ⅳ) and Hf(Ⅳ): The Magical Effect of Bisamide Ligand. SSRN Electronic Journal.
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