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Recent Progress in the Vinylic Polymerization and Copolymerization of Norbornene Catalyzed by Transition Metal Catalysts

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Pages 249-287 | Received 07 May 2008, Accepted 28 Feb 2009, Published online: 22 Jul 2009

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Dmitry A. Alentiev & Maxim V. Bermeshev. (2022) Design and Synthesis of Porous Organic Polymeric Materials from Norbornene Derivatives. Polymer Reviews 62:2, pages 400-437.
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Articles from other publishers (46)

Evgeniya V. Bermesheva & Maxim V. Bermeshev. (2023) Single‐Component Catalysts for the Vinyl‐Addition Polymerization of Norbornene and its Derivatives. ChemCatChem.
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Mingyuan Li, Zhengguo Cai & Moris S. Eisen. (2023) Norbornene Copolymerization with Polar Monomers Catalyzed by Palladium Catalysts Containing Imidazolidin-2-imine/Guanidine Ligands. Inorganic Chemistry.
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Mingyuan Li, Zhengguo Cai & Moris S. Eisen. (2023) Rational design of aldimine imidazolidin-2-imine/guanidine nickel catalysts for norbornene (Co)polymerizations with enhanced catalytic performance. Journal of Catalysis 420, pages 58-67.
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Liang Fang, Chun-Yu Zhang, Xue-Quan Zhang, Xian-De Shen, Heng Liu & Toyoji Kakuchi. (2022) Ni(acac)2 Mediated Vinyl Polymerization of Norbornene in the Presence of Bulky Salicylaldiminate Ligands: An Effective Strategy to Access Soluble Polynorbornenes. Chinese Journal of Polymer Science 41:3, pages 356-364.
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Lixin Cao, Mingyuan Li & Zhengguo Cai. (2023) Copolymerization of Norbornene and Methyl Acrylate by Nickel Catalyst Bearing 2-(Diarylphosphino)-N-phenylbenzenamine Ligands. Catalysts 13:2, pages 311.
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Ahmad Soleimannezhad, Seyed Mohammad Mahdi Mortazavi, Saeid Ahmadjo, Samira Mansouri & Reza Rashedi. (2021) Study on polymerization conditions in homo- and copolymer syntheses of norbornene/1-hexene with nickel-based late-transition metal catalyst. Iranian Polymer Journal 31:2, pages 237-245.
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Alyona I. Wozniak, Evgeniya V. Bermesheva, Ilya L. Borisov, Alexey V. Volkov, Dmitrii I. Petukhov, Natalia N. Gavrilova, Victor P. Shantarovich, Andrey F. Asachenko, Maxim A. Topchiy, Eugene Sh Finkelshtein & Maxim V. Bermeshev. (2022) Switching on/switching off solubility controlled permeation of hydrocarbons through glassy polynorbornenes by the length of side alkyl groups. Journal of Membrane Science 641, pages 119848.
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Jie Dong & Baiquan Wang. (2021) Homo- and copolymerization of norbornene using tridentate IzQO palladium catalysts with dimethylaminoethyl as a side arm. Polymer Chemistry 12:32, pages 4736-4747.
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Xing-Wang Han, Olafs Daugulis & Maurice Brookhart. (2021) Synthesis of End-Functionalized Poly(norbornenes) and Poly(ethylidene norbornenes) Using a Pd(II) Catalyst in Combination with Chain Transfer Agents. Organometallics 40:15, pages 2709-2715.
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Gleb O. Karpov, Xiang-Kui Ren, Elizaveta K. Melnikova & Maxim V. Bermeshev. (2021) Activation of Pd-precatalysts by organic compounds for vinyl-addition polymerization of a norbornene derivative. Chemical Communications 57:35, pages 4255-4258.
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Haobo Yuan, Takumitsu Kida, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama & Takeshi Shiono. (2021) Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa -fluorenylamidodimethyltitanium-[Ph 3 C][B(C 6 F 5 ) 4 ] catalyst system . Polymer Chemistry 12:2, pages 189-195.
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E. V. Bermesheva, A. I. Wozniak, M. V. Bermeshev, A. F. Asachenko, M. A. Topchiy, M. S. Nechaev, M. P. Filatova & A. P. Khrychikova. (2020) Polymerization of 5-Ethylidene-2-norbornene in the Presence of Pd–N-Heterocyclic Carbene Complexes with Phosphine and Pyridine Ligands. Polymer Science, Series B 62:4, pages 319-327.
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Jie Dong, Minliang Li & Baiquan Wang. (2019) Synthesis, Structures, and Norbornene Polymerization Behavior of Imidazo[1,5- a ]pyridine-sulfonate-Ligated Palladacycles . Organometallics 38:19, pages 3786-3795.
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Jie Dong & Baiquan Wang. (2019) Synthesis and Catalytic Properties of Cyclopalladated Complexes Bearing a Phosphane‐Sulfonate Ligand. European Journal of Inorganic Chemistry 2019:35, pages 3919-3924.
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D. S. Suslov, M. V. Bykov & O. V. Kravchenko. (2019) Norbornene Addition Polymerization with Catalysts Based on Transition Metal Compounds: 2008–2018. Polymer Science, Series C 61:1, pages 145-173.
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Mingyuan Li, Hu Zhang, Zhengguo Cai & Moris S. Eisen. (2019) Norbornene polymerization and copolymerization with 1-alkenes by neutral palladium complexes bearing aryloxide imidazolin-2-imine ligand. Polymer Chemistry 10:21, pages 2741-2748.
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Xiangyang Song, Lixin Cao, Ryo Tanaka, Takeshi Shiono & Zhengguo Cai. (2019) Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties. ACS Macro Letters 8:3, pages 299-303.
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Sanghamitra Das, Vasudevan Subramaniyan & Ganesan Mani. (2019) Nickel(II) and Palladium(II) Complexes Bearing an Unsymmetrical Pyrrole-Based PNN Pincer and Their Norbornene Polymerization Behaviors versus the Symmetrical NNN and PNP Pincers. Inorganic Chemistry 58:5, pages 3444-3456.
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Jie Gao, Li Zhang, Liu Zhong, Cheng Du, Heng Liao, Haiyang Gao & Qing Wu. (2019) Living isomerization polymerizations of alkenylcyclohexane with camphyl α-diimine nickel catalysts. Polymer 164, pages 26-32.
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Mingyuan Li, Zhengguo Cai & Moris S. Eisen. (2018) Neutral Nickel(II) Complexes Bearing Aryloxide Imidazolin-2-imine Ligands for Efficient Copolymerization of Norbornene and Polar Monomers. Organometallics 37:24, pages 4753-4762.
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M.V. Bermeshev & P.P. Chapala. (2018) Addition polymerization of functionalized norbornenes as a powerful tool for assembling molecular moieties of new polymers with versatile properties. Progress in Polymer Science 84, pages 1-46.
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Jonathan Potier, Basile Commarieu, Armand Soldera & Jerome P. Claverie. (2018) Thermodynamic Control in the Catalytic Insertion Polymerization of Norbornenes as Rationale for the Lack of Reactivity of Endo-Substituted Norbornenes. ACS Catalysis 8:7, pages 6047-6054.
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Oishi Jana & Ganesan Mani. (2018) Enantiomers and Structural Isomers of Sodium and Palladium Complexes Bearing ortho -Bis(3,5-dimethylpyrazolylmethyl)phenolate: Fluxional Property and Highly Active Catalysts for Norbornene Polymerization . Inorganic Chemistry 57:13, pages 7735-7747.
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Beom-Goo Kang, Dong-Gyun Kim & Richard A. Register. (2018) Vinyl Addition Copolymers of Norbornylnorbornene and Hydroxyhexafluoroisopropylnorbornene for Efficient Recovery of n -Butanol from Dilute Aqueous Solution via Pervaporation . Macromolecules 51:10, pages 3702-3710.
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Mingyuan Li, Xin Shu, Zhengguo Cai & Moris S. Eisen. (2018) Synthesis, Structures, and Norbornene Polymerization Behavior of Neutral Nickel(II) and Palladium(II) Complexes Bearing Aryloxide Imidazolidin-2-imine Ligands. Organometallics 37:7, pages 1172-1180.
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Ting Zheng, Heng Liao, Jie Gao, Liu Zhong, Haiyang Gao & Qing Wu. (2018) Synthesis and characterization of α-diamine palladium complexes and insight into hybridization effects of nitrogen donor atoms on norbornene (co)polymerizations. Polymer Chemistry 9:22, pages 3088-3097.
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Dandan Yang, Jie Dong & Baiquan Wang. (2018) Homo- and copolymerization of norbornene with tridentate nickel complexes bearing o -aryloxide-N-heterocyclic carbene ligands . Dalton Transactions 47:1, pages 180-189.
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Lixia Pei, San He, Jie Gao, Heng Liao & Haiyang Gao. (2017) Homo- and Copolymerizations of Ethylene and Norbornene Using Bis(β-ketoamino) Titanium Catalysts Containing Pyrazolone Rings. Polymers 9:12, pages 262.
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Xiangyang Song, Lijun Yu, Takeshi Shiono, Tariqul Hasan & Zhengguo Cai. (2017) Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin Segments. Macromolecular Rapid Communications 38:7, pages 1600815.
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Xiaohui He, Yingjiao Deng, Xiong Jiang, Zijie Wang, Yingping Yang, Zhilong Han & Defu Chen. (2017) Copolymerization of norbornene and butyl methacrylate at elevated temperatures by a single centre nickel catalyst bearing bulky bis(α-diimine) ligand with strong electron-withdrawing groups. Polymer Chemistry 8:15, pages 2390-2396.
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Hongliang Mu, Li Pan, Dongpo Song & Yuesheng Li. (2015) Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties. Chemical Reviews 115:22, pages 12091-12137.
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Basile Commarieu & Jerome P. Claverie. (2015) Bypassing the lack of reactivity of endo-substituted norbornenes with the catalytic rectification–insertion mechanism. Chemical Science 6:4, pages 2172-2181.
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Gao Jie, Bao Feng, Chen Ying, Chen Tao, Ma Rui, Liu Pan, Han Xiaobing, Lan Zhenzhen, Ma Jianlan & Yan Chunjie. (2014) Cobalt complex bearing β-ketoamine ligand: syntheses, structure, catalytic behavior for styrene and methyl methacrylate polymerization. Applied Organometallic Chemistry 28:8, pages 584-588.
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Qian Feng, Dajun Chen, Danyang Feng, Libin Jiao, Zhigang Peng & Lixia Pei. (2014) Synthesis of poly(norbornene-co-styrene) copolymers containing high styrene incorporation using bis(β-ketoamino) copper catalysts. Journal of Polymer Research 21:7.
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Haiyang Gao, Yong Liu, Guiliang Li, Zefan Xiao, Guodong Liang & Qing Wu. (2014) Catalytic synthesis of polyethylene-block-polynorbornene copolymers using a living polymerization nickel catalyst. Polym. Chem. 5:20, pages 6012-6018.
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Qian Feng, Dajun Chen, Danyang Feng, Libin Jiao, Zhigang Peng & Lixia Pei. (2014) Vinyl polymerizations of norbornene catalyzed by nickel complexes with acetoacetamide ligands. Applied Organometallic Chemistry 28:1, pages 32-37.
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Yinghua Yu, Jianxin Chen, Suqin Meng, Chao Li, Meiying Lan & Zhichun Zhang. (2013) Nickel(II) and copper(II) complexes as catalysts for norbornene vinyl polymerization bearing tetradentate β-ketoiminato ligands. Journal of Molecular Catalysis A: Chemical 380, pages 104-111.
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Takeshi Shiono, Mitsunori Sugimoto, Tariqul Hasan & Zhengguol Cai. (2013) Facile Synthesis of Hydroxy‐Functionalized Cycloolefin Copolymer Using ω‐Alkenylaluminium as a Comonomer. Macromolecular Chemistry and Physics 214:19, pages 2239-2244.
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Jun-Kai Zhang, Peng-Chao Wang, Xiao-Wei Wang, Liang Wang, Jun-Cai Chen, Zhi-Wu Zheng & Yong-Ping Niu. (2011) Vinyl addition polymerization of norbornene catalyzed by β-iminoamine Ni(II) complexes/methylaluminoxane systems. Journal of Organometallic Chemistry 696:23, pages 3697-3702.
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V. S. Tkach, D. S. Suslov, N. V. Kurat’eva, M. V. Bykov & M. V. Belova. (2011) Synthesis and structure of (acetylacetonato-κ2-O,O′)(bistriphenylphosphine)palladium tetrafluoroborate as a precursor of catalysts active in the conversion of unsaturated hydrocarbons. Russian Journal of Coordination Chemistry 37:10, pages 752-756.
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Takeshi Shiono. (2011) Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-based catalysts. Polymer Journal 43:4, pages 331-351.
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Liqin Ding, Zeng Chu, Leilei Chen, Xingqiang Lü, Biao Yan, Jirong Song, Daidi Fan & Feng Bao. (2011) Pd-Salen and Pd-Salan complexes: Characterization and application in styrene polymerization. Inorganic Chemistry Communications 14:4, pages 573-577.
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Massimiliano Delferro & Tobin J. Marks. (2011) Multinuclear Olefin Polymerization Catalysts. Chemical Reviews 111:3, pages 2450-2485.
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Lixia Pei & Haiyang Gao. (2011) Bis(β-ketoamino) copper complexes for vinyl polymerization of norbornene: Correlation between precursor structure and catalytic activity. Journal of Molecular Catalysis A: Chemical 336:1-2, pages 94-99.
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Guoqi Xiao, Bing Yan, Rui Ma, Wen Juan Jin, Xing Qiang Lü, Li Qin Ding, Chu Zeng, Lei Lei Chen & Feng Bao. (2011) Bulk ring-opening polymerization (ROP) of L-lactide catalyzed by Ni( ii ) and Ni( ii )-Sm( iii ) complexes based on a salen-type schiff-base ligand . Polym. Chem. 2:3, pages 659-664.
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Zeng Chu, Li Qin Ding, Yong Long, Lei Lei Chen, Xing Qiang Lü, Ji Rong Song, Dai Di Fan, Feng Bao & Rui Ma. (2010) A Chiral Salen-type Schiff Base Cu2+ Complex for the Vinylic-type Polymerization of Norbornene. Journal of Inorganic and Organometallic Polymers and Materials 20:2, pages 235-241.
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