The unusual influence of hetaryl groups on the direct conversion of some secondary alcohols into thiols with Lawesson’s reagent: elucidation of the reaction mechanism

Grzegorz MlostońDepartment of Organic and Applied Chemistry, University of Łódź, Łódź, PolandCorrespondence[email protected]
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Róża Hamera-FałdygaDepartment of Organic and Applied Chemistry, University of Łódź, Łódź, PolandView further author information

Małgorzata CeledaDepartment of Organic and Applied Chemistry, University of Łódź, Łódź, PolandView further author information

Anthony LindenDepartment of Chemistry, University of Zurich, Zurich, SwitzerlandView further author information

Heinz HeimgartnerDepartment of Chemistry, University of Zurich, Zurich, SwitzerlandView further author information

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Tarik E. Ali, Mohammed A. Assiri, Hafez M. El-Shaaer, Mohamed M. Hassan, Ahmed M. Fouda & Noha M. Hassanin. (2019) Reaction of 2-imino-2H-chromene-3-carboxamide with some phosphorus esters: Synthesis of some novel chromenes containing phosphorus heterocycles and phosphonate groups and their antioxidant and cytotoxicity properties. Synthetic Communications 49:21, pages 2983-2994.
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Noha M. Hassanin, Tarik E. Ali, Hafez M. El-Shaaer & Mohamed M. Hassan. (2018) Reaction of 2-imino-2H-chromene-3-carboxamide with phosphorus sulfides: Synthesis of novel 2-sulfido-2,3-dihydro-4H-chromeno[2,3-d][1,3,2]diaza-phosphinines. Phosphorus, Sulfur, and Silicon and the Related Elements 193:10, pages 651-655.
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Hena Khatoon & Emilia Abdulmalek. (2021) A Focused Review of Synthetic Applications of Lawesson’s Reagent in Organic Synthesis. Molecules 26:22, pages 6937.
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Wei He, Yong Ding, Jianzhuo Tu, Chuqiang Que, Zhanhui Yang & Jiaxi Xu. (2018) Thermal conversion of primary alcohols to disulfides via xanthate intermediates: an extension to the Chugaev elimination . Organic & Biomolecular Chemistry 16:10, pages 1659-1666.
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Artur Mardyukov, Dominik Niedek & Peter R. Schreiner. (2018) Unravelling Lawesson's reagent: the structure of monomeric (4-methoxyphenyl)phosphine disulfide. Chemical Communications 54:22, pages 2715-2718.
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The unusual influence of hetaryl groups on the direct conversion of some secondary alcohols into thiols with Lawesson’s reagent: elucidation of the reaction mechanism

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The unusual influence of hetaryl groups on the direct conversion of some secondary alcohols into thiols with Lawesson’s reagent: elucidation of the reaction mechanism

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