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Journal of Nuclear Science and Technology Volume 30, 1993 - Issue 6
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Original Paper

Electrochemical and Spectroelectrochemical Studies on Uranyl Carbonato and Aqua Complexes

Kohji MIZUGUCHI Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152
,
Yoon-Yul PARK Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152
,
Hiroshi TOMIYASU Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152
&
Yasuhisa IKEDA Kashiwa Laboratory, Institute of Research and Innovations, Takada, Kashiwa-shi, Chiba, 277
Pages 542-548 | Received 31 Aug 1992, Published online: 15 Mar 2012

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Takuya NANKAWA, Yoshinori SUZUKI, Takuo OZAKI, ArokiasamyJ. FRANCIS & Toshihiko OHNUKI. (2008) Sorption of U(VI) on the 4-Mercaptopyridine Self-Assembled Monolayer. Journal of Nuclear Science and Technology 45:3, pages 251-256.
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Yoshinori SUZUKI, Takuya NANKAWA, Takuo OZAKI, Toshihiko OHNUKI, ArokiasamyJ. FRANCIS, Youichi ENOKIDA & Ichiro YAMAMOTO. (2007) Electrochemical Studies on Uranium in the Presence of Organic Acids. Journal of Nuclear Science and Technology 44:9, pages 1227-1232.
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Seong-Yun KIM, Hiroshi TOMIYASU & Yasuhisa IKEDA. (2002) Electrochemical Studies on [UO2(DMF)5](CIO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N, N-dimethylformamide, acac=acetylacetonate, salen=N, N′-disalicylideneethylenediaminate) Complexes in DMF. Journal of Nuclear Science and Technology 39:2, pages 160-165.
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Noriko ASANUMA, Masayuki HARADA, Yasuhisa IKEDA & Hiroshi TOMIYASU. (2001) New Approach to the Nuclear Fuel Reprocessing in Non-acidic Aqueous Solutions. Journal of Nuclear Science and Technology 38:10, pages 866-871.
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Seong-Yun KIM, Masayuki HARADA, Hiroshi TOMIYASU, Yoshinobu SHIOKAWA & Yasuhisa IKEDA. (2000) Electrochemical Study on Octakis(dimethyl sulfoxide)uranium(IV) Complex in Dimethyl Sulfoxide. Journal of Nuclear Science and Technology 37:11, pages 999-1002.
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Noriko ASANUMA, Hiroshi TOMIYASU, Masayuki HARADA, Yasuhisa IKEDA & Shinichi HASEGAWA. (2000) Anodic Dissolution of UO2 in Aqueous Alkaline Solutions. Journal of Nuclear Science and Technology 37:5, pages 486-488.
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Seong-Yun KIM, Koh HATAKEYAMA, Hiroshi TOMIYASU & Yasuhisa IKEDA. (1998) Structural and Electrochemical Studies on Uranium(VI) Nitrato Complex with n-Octyl(phenyl)-N,N-Diisobutylcarbamoylmethylphosphine Oxide in Non-aqueous Solvents. Journal of Nuclear Science and Technology 35:6, pages 437-442.
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Sang-Hwan LEE, Kohji MIZUGUCHI, Hiroshi TOMIYASU & Yasuhisa IKEDA. (1996) Electrochemical and Spectroelectrochemical Studies on Bis(acetylacetonato) (dimethyl sulfoxide)dioxouranium(VI) in Dimethyl Sulfoxide. Journal of Nuclear Science and Technology 33:2, pages 190-192.
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Maitrey Travadi, Rajendrasinh N. Jadeja & Ray J. Butcher. (2023) Uranyl(VI) Mixed-ligand complex synthesis and characterization using 4-acylhydrazone-5-pyrazolone and 4-acylpyrazolone: Covalency, crystal assay, DFT study and Hirshfeld analysis. Journal of Molecular Structure 1281, pages 135137.
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Maitrey Travadi, Rajendrasinh N. Jadeja & Ray J. Butcher. (2022) Synthesis, Covalency Sequence, and Crystal Features of Pentagonal Uranyl Acylpyrazolone Complexes along with DFT Calculation and Hirshfeld Analysis. ACS Omega 7:38, pages 34359-34369.
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Maitrey Travadi, R.N. Jadeja & Ray J. Butcher. (2022) Synthesis, covalency parameters, energy calculations and crystal features of acylpyrazolone derived pentavalent Uranyl complex along with DFT and Hirshfeld analysis. Polyhedron 223, pages 115956.
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Yun Xue, Jianzhang Gao, Zhenchao Ma, Jiadong Wang, Meng Cao, Chen Guo, Peng Liu, Fuqiu Ma, Yongde Yan & Min Qiu. (2021) An Efficient System for Uranyl Electrodeposition and Investigation of the Uranyl Electrochemical Behavior. Journal of The Electrochemical Society 168:11, pages 112508.
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Xiangyang Hou, Jeffrey R. McLachlan & Christopher J. Dares. (2021) Electrochemical behaviour of uranium at a tripolyphosphate modified ITO electrode. Chemical Communications 57:83, pages 10891-10894.
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Tomoyuki Takeyama, Satoru Tsushima & Koichiro Takao. (2021) Effects of Substituents on the Molecular Structure and Redox Behavior of Uranyl(V/VI) Complexes with N 3 O 2 -Donating Schiff Base Ligands . Inorganic Chemistry 60:15, pages 11435-11449.
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Rahul Agarwal, Rama Mohana Rao Dumpala, Manoj K. SharmaAshok Kumar Yadav & Tamal Kanti Ghosh. (2021) Stabilization of uranyl( v ) by dipicolinic acid in aqueous medium . Dalton Transactions 50:4, pages 1486-1495.
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Sayandev Chatterjee, James M. Peterson, Amanda J. Casella, Tatiana G. Levitskaia & Samuel A. Bryan. (2020) Mechanisms of Plutonium Redox Reactions in Nitric Acid Solutions. Inorganic Chemistry 59:10, pages 6826-6838.
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Radmila Faizova, Farzaneh Fadaei‐Tirani, Rizlan Bernier‐Latmani & Marinella Mazzanti. (2020) Ligand‐Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media. Angewandte Chemie International Edition 59:17, pages 6756-6759.
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Ruma Gupta, BalGovind Vats, Ashok K. Pandey, Manoj K. Sharma, Pooja Sahu, A. K. Yadav, Sk. Musharaf Ali & Shanmugaperumal Kannan. (2019) Insight into Speciation and Electrochemistry of Uranyl Ions in Deep Eutectic Solvents. The Journal of Physical Chemistry B 124:1, pages 181-189.
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Valery N. Bliznyuk, Kamila Kołacińska, Alexander A. Pud, Nikolay A. Ogurtsov, Yuriy V. Noskov, Brian A. Powell & Timothy A. DeVol. (2019) High effectiveness of pure polydopamine in extraction of uranium and plutonium from groundwater and seawater. RSC Advances 9:52, pages 30052-30063.
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Ashutosh Srivastava, Pranaw Kumar & Bhupendra S. Tomar. (2017) Redox speciation of uranium with phenylphosphonic acid (PPA) in aqueous medium. Radiochimica Acta 105:4, pages 311-320.
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Ashutosh Srivastava, Ashis K. Satpati, Ritu Singh, Pranaw Kumar, Sumit Kumar & Bhupendra S. Tomar. (2017) Redox speciation of uranyl in citrate medium: kinetics and reduction mechanism with in situ spectroelectrochemical investigation . New Journal of Chemistry 41:24, pages 15094-15104.
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Anyuna Dash, Renu Agarwal & S. K. Mukerjee. (2016) Electrochemical behaviour of uranium and thorium aqueous solutions at different temperatures. Journal of Radioanalytical and Nuclear Chemistry 311:1, pages 733-747.
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Satyabrata Mishra, Sini K.Ch. Jagadeeswara Rao, C. Mallika & U. Kamachi Mudali. (2016) Electrochemical studies on the reduction of uranyl ions in nitric acid-hydrazine media. Journal of Electroanalytical Chemistry 776, pages 127-133.
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Daniele Merli, Stefano Protti, Matteo Labò, Maria Pesavento & Antonella Profumo. (2016) A ω-mercaptoundecylphosphonic acid chemically modified gold electrode for uranium determination in waters in presence of organic matter. Talanta 151, pages 119-125.
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Phuong D. Dau, Richard E. Wilson & John K. Gibson. (2015) Elucidating Protactinium Hydrolysis: The Relative Stabilities of PaO 2 (H 2 O) + and PaO(OH) 2 + . Inorganic Chemistry 54:15, pages 7474-7480.
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Saurav K. Guin, Arvind S. Ambolikar & J.V. Kamat. (2015) Reduced Graphene Oxide: Is it a promising catalyst for the electrochemistry of [UO2(CO3)3]4−/[UO2(CO3)3]5−?. Electrochimica Acta 174, pages 1002-1008.
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Yoshinori Suzuki, Takuya Nankawa & Toshihiko Ohnuki. (2013) Redox Behavior of Uranium(VI) Adsorbed onto a Phosphate-modified Indium Tin Oxide Electrode. Chemistry Letters 42:8, pages 888-890.
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Colm Mallon, Aurora Walshe, Robert J. Forster, Tia E. Keyes & Robert J. Baker. (2012) Physical Characterization and Reactivity of the Uranyl Peroxide [UO 2 (η 2 -O 2 )(H 2 O) 2 ]·2H 2 O: Implications for Storage of Spent Nuclear Fuels . Inorganic Chemistry 51:15, pages 8509-8515.
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Raymond Atta-Fynn, Donald F. Johnson, Eric J. Bylaska, Eugene S. Ilton, Gregory K. Schenter & Wibe A. de Jong. (2012) Structure and Hydrolysis of the U(IV), U(V), and U(VI) Aqua Ions from Ab Initio Molecular Simulations. Inorganic Chemistry 51:5, pages 3016-3024.
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Koichiro Takao, Masaru Kato, Shinobu Takao, Akira Nagasawa, Gert Bernhard, Christoph Hennig & Yasuhisa Ikeda. (2010) Molecular Structure and Electrochemical Behavior of Uranyl(VI) Complex with Pentadentate Schiff Base Ligand: Prevention of Uranyl(V) Cation−Cation Interaction by Fully Chelating Equatorial Coordination Sites. Inorganic Chemistry 49:5, pages 2349-2359.
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Grégory Nocton, Pawel Horeglad, Valentina Vetere, Jacques Pécaut, Lionel Dubois, Pascale Maldivi, Norman M. Edelstein & Marinella Mazzanti. (2009) Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl. Journal of the American Chemical Society 132:2, pages 495-508.
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Koichiro Takao, Satoru Tsushima, Shinobu Takao, Andreas C. Scheinost, Gert Bernhard, Yasuhisa Ikeda & Christoph Hennig. (2009) X-ray Absorption Fine Structures of Uranyl(V) Complexes in a Nonaqueous Solution. Inorganic Chemistry 48:20, pages 9602-9604.
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Satoru Tsushima. (2009) Photochemical Reduction of UO 2 2+ in the Presence of Alcohol Studied by Density Functional Theory Calculations . Inorganic Chemistry 48:11, pages 4856-4862.
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Fernando Ruipérez, Cécile Danilo, Florent Réal, Jean-Pierre Flament, Valérie Vallet & Ulf Wahlgren. (2009) An ab Initio Theoretical Study of the Electronic Structure of UO 2 + and [UO 2 (CO 3 ) 3 ] 5− . The Journal of Physical Chemistry A 113:8, pages 1420-1428.
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Christopher R. Graves & Jaqueline L. Kiplinger. (2009) Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state. Chemical Communications:26, pages 3831.
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Atsushi Ikeda, Christoph Hennig, Satoru Tsushima, Koichiro Takao, Yasuhisa Ikeda, Andreas C. Scheinost & Gert Bernhard. (2007) Comparative Study of Uranyl(VI) and -(V) Carbonato Complexes in an Aqueous Solution. Inorganic Chemistry 46:10, pages 4212-4219.
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Matthew C. F. Wander, Sebastien Kerisit, Kevin M. Rosso & Martin A. A. Schoonen. (2006) Kinetics of Triscarbonato Uranyl Reduction by Aqueous Ferrous Iron:  A Theoretical Study. The Journal of Physical Chemistry A 110:31, pages 9691-9701.
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Michael E. Stoll. 2007. Encyclopedia of Electrochemistry. Encyclopedia of Electrochemistry.
Koichiro Mizuoka, Satoru Tsushima, Miki Hasegawa, Toshihiko Hoshi & Yasuhisa Ikeda. (2005) Electronic Spectra of Pure Uranyl(V) Complexes:  Characteristic Absorption Bands Due to a U V O 2 + Core in Visible and Near-Infrared Regions 1 . Inorganic Chemistry 44:18, pages 6211-6218.
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Koichiro Mizuoka, Ingmar Grenthe & Yasuhisa Ikeda. (2005) Structural and Kinetic Studies on Uranyl(V) Carbonate Complex Using 13 C NMR Spectroscopy . Inorganic Chemistry 44:13, pages 4472-4474.
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Colin Boxall, Gwénaëlle Le Gurun, Robin J. Taylor & Shaorong Xiao. 2005. Environmental Photochemistry Part II. Environmental Photochemistry Part II 451 481 .
Koichiro Mizuoka, Seong-Yun Kim, Miki Hasegawa, Toshihiko Hoshi, Gunzo Uchiyama & Yasuhisa Ikeda. (2003) Electrochemical and Spectroelectrochemical Studies on UO 2 (saloph)L (saloph = N,N ‘ -Disalicylidene- o -phenylenediaminate, L = Dimethyl Sulfoxide or N,N -Dimethylformamide) . Inorganic Chemistry 42:4, pages 1031-1038.
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Tomoo Yamamura, Yoshinobu Shiokawa, Hajimu Yamana & Hirotake Moriyama. (2002) Electrochemical investigation of uranium β-diketonates for all-uranium redox flow battery. Electrochimica Acta 48:1, pages 43-50.
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David E. Morris. (2002) Redox Energetics and Kinetics of Uranyl Coordination Complexes in Aqueous Solution. Inorganic Chemistry 41:13, pages 3542-3547.
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Seong-Yun KIM, Hiroshi TOMIYASU & Yasuhisa IKEDA. (2002) Electrochemical Studies on [UO2(DMF)5](ClO4)2, UO2(acac)2DMF, and UO2(salen)DMF (DMF=N, N-dimethylformamide, acac=acetylacetonate, salen=N, N'-disalicylideneethylenediaminate) Complexes in DMF.. Journal of Nuclear Science and Technology 39:2, pages 160-165.
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T. I. Docrat, J. F. W. Mosselmans, J. M. Charnock, M. W. Whiteley, D. Collison, F. R. Livens, C. Jones & M. J. Edmiston. (1999) X-ray Absorption Spectroscopy of Tricarbonatodioxouranate(V), [UO 2 (CO 3 ) 3 ] 5 - , in Aqueous Solution . Inorganic Chemistry 38:8, pages 1879-1882.
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Rajendrasinh N. Jadeja, Maitrey Travadi & Ray J. Butcher. (2022) Synthesis, Covalency Parameters, Energy Calculations and Crystal Features of Acyl Pyrazolone Derived Pentavalent Uranyl Complex Along with Dft and Hirshfeld Analysis. SSRN Electronic Journal.
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