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Journal of Nuclear Science and Technology Volume 41, 2004 - Issue 11
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SHORT NOTE

Selective Separation of Am(III) from Ln(III) with a Novel Synergistic Extraction System, N,N, N′, N′-tetrakis(2-methylpyridyl)-ethylenediamine (TPEN) and Carboxylic Acid in 1-Octanol

Rinat MIRVALIEV Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, Ibaraki, 319-1195
,
Masayuki WATANABE Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, Ibaraki, 319-1195
,
Tatsuro MATSUMURA Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, Ibaraki, 319-1195
,
Shoichi TACHIMORI Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, Ibaraki, 319-1195
&
Kenji TAKESHITA Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-850
Pages 1122-1124 | Received 20 Jul 2004, Accepted 09 Sep 2004, Published online: 15 Feb 2012

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GlennA. Fugate∗, Kenji Takeshita & Tatsuro Matsumura. (2008) Separation of Americium (III) and Lanthanide (III) Ions using TPEN Analogs. Separation Science and Technology 43:9-10, pages 2619-2629.
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Sunao MIYASHITA, Makoto YANAGA, Isamu SATOH & Hideo SUGANUMA. (2007) Separation of Americium(III) from Europium(III) by Extraction Based on in situ Formation of Dioctylammonium Dioctyldithiocarbamate Extractant. Journal of Nuclear Science and Technology 44:2, pages 233-237.
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Articles from other publishers (14)

Lianjun Song, Xueyu Wang, Dongqi Wang, Qian Xiao, Haowei Xu, Qiuju Li, Lanlan He & Songdong Ding. (2021) 2-Carboxamido-6-(1H-pyrazol-3-yl)-pyridines as ligands for efficient separation of americium(III) from europium(III). Separation and Purification Technology 276, pages 119262.
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Ke Niu, Feng Yang, Théophile Gaudin, Haibo Ma & Weihai Fang. (2021) Theoretical Study of Effects of Solvents, Ligands, and Anions on Separation of Trivalent Lanthanides and Actinides. Inorganic Chemistry 60:13, pages 9552-9562.
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Yuji Miyazaki, Shinichi Suzuki, Toru Kobayashi, Tsuyoshi Yaita, Yusuke Inaba, Kenji Takeshita & Atsunori Mori. (2015) Synthetic Design of TPEN Derivatives for Selective Extraction of Trivalent Minor Actinides against Lanthanides. Chemistry Letters 44:12, pages 1626-1636.
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Dengfang Pan, Cai Jia, Xihong He, Gang Ye & Jing Chen. (2015) A polyazamacrocycle extractant for the extraction of americium and europium. Science China Chemistry 58:6, pages 986-992.
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A. Afsar, L.M. Harwood & M.J. Hudson. 2015. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.
Michael J. HudsonLaurence M. HarwoodDominic M. LaventineFrank W. Lewis. (2012) Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides. Inorganic Chemistry 52:7, pages 3414-3428.
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Wataru Watanabe, Tetsuya Maekawa, Yuji Miyazaki, Tatsuya Kida, Kenji TakeshitaAtsunori Mori. (2012) Quadruple Click: A Facile Pathway leading to Tetrakis(4‐(1,2,3‐triazolyl)methyl)‐ethylenediamine Derivatives as a New Class of Extracting Agents for Soft Metal Ions. Chemistry – An Asian Journal 7:7, pages 1679-1683.
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Yusuke Inaba, Takayuki Tsumagari, Tatsuya Kida, Wataru Watanabe, Yasutaka Nakajima, Sachio Fukuoka, Atsunori Mori, Tatsuro Matsumura, Yoshio Nakano & Kenji Takeshita. (2011) Thermoresponsive extraction of cadmium(II) ions by poly(TPEN–NIPA) gels. Effect of chain length and branched spacer structure on gel formation and extraction behavior. Polymer Journal 43:7, pages 630-634.
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Tetsuya Maekawa, Tatsuya Kida, Yuji Miyazaki, Wataru Watanabe, Yusuke Inaba, Kenji Takeshita & Atsunori Mori. (2011) Temperature-Dependent Change of Extraction Performance of Soft Cadmium(II) Ion with TPEN–NIPA Gel. Studies on the Effect of the Ethylenediamine Skeleton. Bulletin of the Chemical Society of Japan 84:1, pages 122-124.
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Tatsuya Kida, Yusuke Inaba, Wataru Watanabe, Yasutaka Nakajima, Sachio Fukuoka, Kenji Takeshita & Atsunori Mori. (2010) Extraction of Cd 2+ and Am 3+ Ions into Organic and Fluorous Solvents with a TPEN Chelating Agent bearing a Fluoroalkyl Substituent . Chemistry Letters 39:7, pages 774-776.
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Sachio Fukuoka, Tatsuya Kida, Yasutaka Nakajima, Takayuki Tsumagari, Wataru Watanabe, Yusuke Inaba, Atsunori Mori, Tatsuro Matsumura, Yoshio Nakano & Kenji Takeshita. (2010) Thermo-responsive extraction of cadmium(II) ion with TPEN-NIPA gel. Effect of the number of polymerizable double bond toward gel formation and the extracting behavior. Tetrahedron 66:9, pages 1721-1727.
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Marie Heitzmann, Christelle Gateau, Laurence Chareyre, Manuel Miguirditchian, Marie-Christine Charbonnel & Pascale Delangle. (2010) Water-soluble tetrapodal N,O ligands incorporating soft N-heterocycles for the selective complexation of Am(iii) over Ln(iii). New J. Chem. 34:1, pages 108-116.
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Marie Heitzmann, Florence Bravard, Christelle Gateau, Nathalie Boubals, Claude Berthon, Jacques Pécaut, Marie-Christine Charbonnel & Pascale Delangle. (2008) Comparison of Two Tetrapodal N,O Ligands: Impact of the Softness of the Heterocyclic N-Donors Pyridine and Pyrazine on the Selectivity for Am(III) over Eu(III). Inorganic Chemistry 48:1, pages 246-256.
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Sunao Miyashita, Isamu Satoh, Makoto Yanaga, Kenji Okuno & Hideo Suganuma. (2008) Separation of Am(III) from Eu(III) by extraction based on in situ extractant formation of dithiocarbamate derivatives. Progress in Nuclear Energy 50:2-6, pages 499-503.
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