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Original Articles

IONIC THERMOPLASTIC ELASTOMERS: A REVIEW

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Pages 41-77 | Published online: 20 Aug 2006

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (4)

T. Chatterjee, S. Hait, A. B. Bhattacharya, A. Das, S. Wiessner & K. Naskar. (2020) Zinc salts induced ionomeric thermoplastic elastomers based on XNBR and PA12. Polymer-Plastics Technology and Materials 59:2, pages 141-153.
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Yiping Ni, Frédéric Becquart, Mohamed Taha, Jean-Charles Majeste & Jianding Chen. (2014) Poly(butyl methacrylate-co-methacrylic acid) Copolymers with Calcium Carbonate Supramolecular Networks. International Journal of Polymeric Materials and Polymeric Biomaterials 63:8, pages 405-415.
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Hong‐Quan Xie, Wei Zhao, Da‐Ting Tian & Dong Xie. (2008) Synthesis, Characterization and Properties of Novel Amphiphilic Phosphated Ionomers by Ring‐Opening Reaction of Epoxidized Styrene‐Butadiene‐Styrene Triblock Polymer. Journal of Macromolecular Science, Part A 45:2, pages 151-158.
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Articles from other publishers (54)

Mithun Das, Arshad Rahman Parathodika, Purbasha Maji & Kinsuk Naskar. (2023) Dynamic chemistry: The next generation platform for various elastomers and their mechanical properties with self-healing performance. European Polymer Journal 186, pages 111844.
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Uddhab Kalita, Bhavya Parameswaran & Nikhil K. Singha. 2001. Kirk-Othmer Encyclopedia of Chemical Technology. Kirk-Othmer Encyclopedia of Chemical Technology 1 39 .
Georgina L. Gregory, Gregory S. Sulley, Joost Kimpel, Matylda Łagodzińska, Lisa Häfele, Leticia Peña Carrodeguas & Charlotte K. Williams. (2022) Block Poly(carbonate‐ester) Ionomers as High‐Performance and Recyclable Thermoplastic Elastomers. Angewandte Chemie International Edition 61:47.
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Georgina L. Gregory, Gregory S. Sulley, Joost Kimpel, Matylda Łagodzińska, Lisa Häfele, Leticia Peña Carrodeguas & Charlotte K. Williams. (2022) Block Poly(carbonate‐ester) Ionomers as High‐Performance and Recyclable Thermoplastic Elastomers. Angewandte Chemie 134:47.
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Mithun Das, T. K. Sreethu, Sanjay Pal & Kinsuk Naskar. (2022) Biologically Derived Metal–Cysteine Coordination Complexes Crosslink Carboxylated Nitrile Rubber and Enable Room Temperature Self-Healing, Stretchability, and Recyclability. ACS Applied Polymer Materials 4:9, pages 6414-6425.
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Prakash Vislavath, Srikanth Billa, Praveen S, Jitendra Bahadur, Kathi Sudarshan, T. Umasankar Patro, Sangram K. Rath & Debdatta Ratna. (2022) Heterogeneous Coordination Environment and Unusual Self-Assembly of Ionic Aggregates in a Model Ionomeric Elastomer: Effect of Curative Systems. Macromolecules 55:15, pages 6739-6749.
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Bartłomiej Kost, Malgorzata Basko, Melania Bednarek, Marta Socka, Bartosz Kopka, Grzegorz Łapienis, Tadeusz Biela, Przemysław Kubisa & Marek Brzeziński. (2022) The influence of the functional end groups on the properties of polylactide-based materials. Progress in Polymer Science 130, pages 101556.
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Chloé Larrue, Véronique Bounor-Legaré & Philippe Cassagnau. (2021) Enhancement of EPDM Crosslinked Elastic Properties by Association of Both Covalent and Ionic Networks. Polymers 13:18, pages 3161.
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Chenrun Feng, C.P. Hemantha Rajapaksha & Antal Jákli. (2021) Ionic Elastomers for Electric Actuators and Sensors. Engineering 7:5, pages 581-602.
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Debdipta Basu, Shib Shankar Banerjee, Subhas Chandra Debnath, Mikhail Malanin, Lyaysan Amirova, Philippe Dubois, Gert Heinrich & Amit Das. (2021) Unusual low temperature relaxation behavior of crosslinked acrylonitrile-butadiene co-polymer. Polymer 212, pages 123309.
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Ramesh P. Birmod, Vikesh G. Lade & Rakesh D. Shambharkar. 2021. Handbook of Nanomaterials for Wastewater Treatment. Handbook of Nanomaterials for Wastewater Treatment 673 697 .
Sijia Zheng, Yang Chen & Michael A. Brook. (2020) Thermoplastic silicone elastomers based on Gemini ionic crosslinks. Polymer Chemistry 11:46, pages 7382-7392.
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Jihua Zhang, Chao Wang, Weitao Zao, Huadong Feng, Yange Hou & Aijuan Huo. (2020) High-Performance Nitrile Butadiene Rubber Composites with Good Mechanical Properties, Tunable Elasticity, and Robust Shape Memory Behaviors. Industrial & Engineering Chemistry Research 59:36, pages 15936-15947.
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Aizeti Burgoa, Ricardo Hernandez & Jose Luis Vilas. (2020) New ways to improve the damping properties in high‐performance thermoplastic vulcanizates. Polymer International 69:5, pages 467-475.
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Kedafi Belkhir, Jean‐Charles Majesté, Corinne Jegat & Mohamed Taha. (2019) Rheological study of quaternary ammonium‐containing star‐shaped polylactic acid. Journal of Applied Polymer Science 137:5, pages 48337.
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Debdipta Basu, Airit Agasty, Amit Das, Santanu Chattopadhyay, Puspendu Sahu & Gert Heinrich. (2019) Phase changing stearate ions as active fillers in multifunctional carboxylated acrylonitrile–butadiene composite: Exploring the role of zinc stearate. Journal of Applied Polymer Science 137:2, pages 48271.
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Thanh Tung Nguyen, Anh Vy Tran, Hye Jin Lee, Jayeon Baek & Yong Jin Kim. (2019) Palladium-catalyzed reductive carbonylation of nitrobenzene for producing phenyl isocyanate. Tetrahedron Letters 60:50, pages 151310.
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A.R. El Dhaba & M. Shaat. (2019) Modeling deformation of auxetic and non-auxetic polymer gels. Applied Mathematical Modelling 74, pages 320-336.
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Magdalena Rogulska. (2018) Polycarbonate-based thermoplastic polyurethane elastomers modified by DMPA. Polymer Bulletin 76:9, pages 4719-4733.
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Yu. A. Lebedev, R. R. Kinzyabulatov, V. V. Astanin & D. V. Gunderov. (2019) Impact of Ultraviolet Irradiation on Stress–Strain Behavior of Syndiotactic 1,2-Polybutadien: The Role of Oxidation. Technical Physics 64:4, pages 475-479.
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Haibin Sun, Xueying Liu, Bing Yu, Zhanbin Feng, Nanying Ning, Guo-Hua Hu, Ming Tian & Liqun Zhang. (2019) Simultaneously improved dielectric and mechanical properties of silicone elastomer by designing a dual crosslinking network. Polymer Chemistry 10:5, pages 633-645.
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German H. Gómez, Thiago Manha Gasparini & Sebastião V. Canevarolo. (2019) Solid-state Morphology Evolution of Sodium Neutralized Poly(ethylene-ran-methacrylic acid) Ionomer Under Dry and Wet Thermal Annealing. Materials Research 22:4.
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Jing Huang, Lijie Zhang, Zhenghai Tang & Baochun Guo. (2018) Bioinspired engineering of sacrificial bonds into rubber networks towards high-performance and functional elastomers. Composites Communications 8, pages 65-73.
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L. Robert MiddletonKaren I. Winey. (2017) Nanoscale Aggregation in Acid- and Ion-Containing Polymers. Annual Review of Chemical and Biomolecular Engineering 8:1, pages 499-523.
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Lucie Imbernon & Sophie Norvez. (2016) From landfilling to vitrimer chemistry in rubber life cycle. European Polymer Journal 82, pages 347-376.
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John F. Trant, Mahmoud M. Abd Rabo Moustafa, Inderpreet Sran & Elizabeth R. Gillies. (2016) Polyisobutylene-paclitaxel conjugates with pendant carboxylic acids and polystyrene chains: Towards multifunctional stent coatings with slow drug release. Journal of Polymer Science Part A: Polymer Chemistry 54:14, pages 2209-2219.
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Dong Wang, Huan Zhang, Beichen Cheng, Zhenchao Qian, Wenxing Liu, Ning Zhao & Jian Xu. (2016) Dynamic cross-links to facilitate recyclable polybutadiene elastomer with excellent toughness and stretchability. Journal of Polymer Science Part A: Polymer Chemistry 54:10, pages 1357-1366.
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Kwang‐Hwan Ko & Joon‐Seop Kim. 2001. Kirk-Othmer Encyclopedia of Chemical Technology. Kirk-Othmer Encyclopedia of Chemical Technology 1 34 .
Jung-Soo Kim, Jong-Woo Bae, Jin-Hyok Lee, Young-Hee Lee & Han-Do Kim. (2015) Preparation and properties of high-performance recyclable ethylene propylene diene rubber. Journal of Applied Polymer Science 132:44, pages n/a-n/a.
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John F. Trant, Inderpreet Sran, John R. de Bruyn, Mark Ingratta, Aneta Borecki & Elizabeth R. Gillies. (2015) Synthesis and properties of arborescent polyisobutylene derivatives and a paclitaxel conjugate: Towards stent coatings with prolonged drug release. European Polymer Journal 72, pages 148-162.
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Matthew J. McEachran, John F. Trant, Inderpreet Sran, John R. de Bruyn & Elizabeth R. Gillies. (2015) Carboxylic Acid-Functionalized Butyl Rubber: Synthesis, Characterization, and Physical Properties. Industrial & Engineering Chemistry Research 54:17, pages 4763-4772.
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Lin Li, Shuai Zhao, Chunhua Chen & Zhenxiang Xin. (2015) Synthesis and characterization of thermoreversible K-Ionomers based on butyl rubber: a simple one-step crosslinking method and a novel crosslinking system. Journal of Polymer Research 22:5.
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Keren Zhang, Motohiro Aiba, Gregory B. Fahs, Amanda G. Hudson, William D. Chiang, Robert B. Moore, Mitsuru Ueda & Timothy E. Long. (2015) Nucleobase-functionalized acrylic ABA triblock copolymers and supramolecular blends. Polymer Chemistry 6:13, pages 2434-2444.
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Wei Song, Huijing Han, Xiaojuan Liao, Ruyi Sun, Jianhua Wu & Meiran Xie. (2014) Metathesis Cyclopolymerization of Imidazolium-Functionalized 1,6-Heptadiyne toward Polyacetylene Ionomer. Macromolecules 47:18, pages 6181-6188.
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. 2014. Handbook of Thermoplastic Elastomers. Handbook of Thermoplastic Elastomers 347 348 .
Adam Ozvald, J. Scott Parent & Ralph A. Whitney. (2013) Hybrid ionic/covalent polymer networks derived from functional imidazolium ionomers. Journal of Polymer Science Part A: Polymer Chemistry 51:11, pages 2438-2444.
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I. Mora-Barrantes, M. A. Malmierca, J. L. Valentin, A. Rodriguez & L. Ibarra. (2012) Effect of covalent cross-links on the network structure of thermo-reversible ionic elastomers. Soft Matter 8:19, pages 5201.
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J. Scott Parent, Anthony M.J. Porter, Monika R. Kleczek & Ralph A. Whitney. (2011) Imidazolium bromide derivatives of poly(isobutylene-co-isoprene): A new class of elastomeric ionomers. Polymer 52:24, pages 5410-5418.
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J. Scott Parent, Sean M. Malmberg & Ralph A. Whitney. (2011) Auto-catalytic chemistry for the solvent-free synthesis of isobutylene-rich ionomers. Green Chemistry 13:10, pages 2818.
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Joon‐Seop Kim, Mohammad Luqman & Ju‐Myung Song. 2002. Encyclopedia of Polymer Science and Technology. Encyclopedia of Polymer Science and Technology.
Damien Montarnal, François Tournilhac, Manuel Hidalgo & Ludwik Leibler. (2010) Epoxy‐based networks combining chemical and supramolecular hydrogen‐bonding crosslinks. Journal of Polymer Science Part A: Polymer Chemistry 48:5, pages 1133-1141.
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Brian S. Aitken, Minjae Lee, Matthew T. Hunley, Harry W. Gibson & Kenneth B. Wagener. (2010) Synthesis of Precision Ionic Polyolefins Derived from Ionic Liquids. Macromolecules 43:4, pages 1699-1701.
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Mariëlle Wouters, Eric Craenmehr, Karin Tempelaars, Hartmut Fischer, Niki Stroeks & Joyce van Zanten. (2009) Preparation and properties of a novel remendable coating concept. Progress in Organic Coatings 64:2-3, pages 156-162.
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Luís Ibarra, Andrés Rodríguez & Irene Mora-Barrantes. (2009) Crosslinking of carboxylated nitrile rubber (XNBR) induced by coordination with anhydrous copper sulfate. Polymer International 58:2, pages 218-226.
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M. A. J. van der Mee, R. M. A. l’Abee, G. Portale, J. G. P. Goossens & M. van Duin. (2008) Synthesis, Structure, and Properties of Ionic Thermoplastic Elastomers Based on Maleated Ethylene/Propylene Copolymers. Macromolecules 41:14, pages 5493-5501.
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Brian P. Grady. (2008) Review and critical analysis of the morphology of random ionomers across many length scales. Polymer Engineering & Science 48:6, pages 1029-1051.
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Kamlesh P. Nair, Victor Breedveld & Marcus Weck. (2008) Complementary Hydrogen-Bonded Thermoreversible Polymer Networks with Tunable Properties. Macromolecules 41:10, pages 3429-3438.
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Hong‐Quan Xie, Wei Zhao, Wei Yang & Dong Xie. (2007) Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer. Journal of Applied Polymer Science 107:4, pages 2681-2688.
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Suk-kyun Ahn, Rajeswari M. Kasi, Seong-Cheol Kim, Nitin Sharma & Yuxiang Zhou. (2008) Stimuli-responsive polymer gels. Soft Matter 4:6, pages 1151.
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Katsuji Matsunaga, Kazuko Nakagawa, Satoshi Sawai, Osamu Sonoda, Masahiro Tajima & Yasuhiko Yoshida. (2005) Synthesis and characterization of polyurethane anionomers. Journal of Applied Polymer Science 98:5, pages 2144-2148.
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Hong‐Quan Xie, Ji‐Chen Deng & Dong Xie. (2005) Synthesis of amphiphilic graft copolymers of SBS with acrylamide and study of their properties. Journal of Applied Polymer Science 97:3, pages 1248-1253.
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Olivier ColombaniChantal BariozLaurent BouteillerCorinne ChanéacLionel FompérieFrédéric LortieHélène Montès. (2005) Attempt toward 1D Cross-Linked Thermoplastic Elastomers:  Structure and Mechanical Properties of a New System. Macromolecules 38:5, pages 1752-1759.
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J. Scott Parent, Andrea Liskova & Rui Resendes. (2004) Isobutylene-based ionomer composites: siliceous filler reinforcement. Polymer 45:24, pages 8091-8096.
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J. Scott Parent, Anca Penciu, Sergio A. Guillén-Castellanos, Andrea Liskova & Ralph A. Whitney. (2004) Synthesis and Characterization of Isobutylene-Based Ammonium and Phosphonium Bromide Ionomers. Macromolecules 37:20, pages 7477-7483.
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