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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 2
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Original Articles

AN EFFICIENT BIOMIMETIC CLEAVAGE OF GEM-DIACETATES TO ALDEHYDES BY β-CYCLODEXTRIN UNDER NEUTRAL CONDITIONS IN AQUEOUS MEDIUM*

M. Arjun Reddy Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
L. Rajender Reddy Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
N. Bhanumathi Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
&
K. Rama Rao Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad, 500 007, IndiaCorrespondence[email protected]
Pages 273-277 | Received 16 Nov 2000, Published online: 16 Aug 2006

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Elahe Saburi, Abolghasem Davoodnia & Niloofar Tavakoli-Hoseini. (2011) A Simple and Fast Method for Protection of Aldehydes as 1,1-Diacetates Using Cerium(IV) Sulfate as an Efficient and Reusable Inorganic Catalyst. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 41:9, pages 1063-1066.
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M. Somi Reddy, M. Narender, Y. V. D. Nageswar & K. Rama Rao. (2007) Simple, One‐Pot Procedure for the Generation of Homoallylic Alcohols from Barbier‐Type Allylation of Gem‐diacetates in the Presence of β‐Cyclodextrin in Water. Synthetic Communications 37:12, pages 1983-1988.
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Yurngdong Jahng & MotiurA. F. M. Rahman. (2006) Simple Synthesis of Geminal Diacetates (Acylals) of Aromatic Aldehydes. Synthetic Communications 36:9, pages 1213-1220.
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Tongshou Jin, Guoliang Feng, Mina Yang & Tongshuang Li. (2004) An Efficient and Practical Procedure for Synthesis of 1,1‐Diacetates from Aldehydes Catalyzed by Zirconium Sulfate Tetrahydrate–Silica Gel. Synthetic Communications 34:9, pages 1645-1651.
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Articles from other publishers (13)

Dominik Koszelewski & Ryszard Ostaszewski. (2019) The studies on chemoselective promiscuous activity of hydrolases on acylals transformations. Bioorganic Chemistry 93, pages 102825.
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E. V. Chernykh & S. B. Brichkin. (2010) Supramolecular complexes based on cyclodextrins. High Energy Chemistry 44:2, pages 83-100.
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Rajnikant, Lovely Sarmal, Kamni, Dinesh & M. B. Deshmukh. (2009) Synthesis and X-ray Structure of Acetoxy-4-methyl Phenyl Methyl Acetate. Journal of Chemical Crystallography 39:11, pages 835-837.
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Enrique L. Larghi & Teodoro S. Kaufman. (2008) A combined RCM-Bischler–Napieralski strategy towards the synthesis of the carbon skeleton of excentricine and related stephaoxocanes. Tetrahedron 64:42, pages 9921-9927.
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Motiur A. F. M. Rahman & Yurngdong Jahng. (2007) Preparation of Geminal Diacylates (Acylals) of Aldehydes – Scope and Reactivity of Aldehydes with Acid Anhydrides. European Journal of Organic Chemistry 2007:2, pages 379-383.
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Shu-Tao Yang. (2019) An Efficient and Practical Procedure for Preparation of Gem -Diacetates from Aldehydes Catalysed by Magnesium Perchlorate . Journal of Chemical Research 2006:3, pages 199-202.
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Tong-Shou Jin, Ying Zhao, Li-Bin Liu & Tong-Shuang Li. (2019) A Rapid and Efficient Procedure for Deprotection of 1,1-diacetates Catalysed by Silica Sulfate. Journal of Chemical Research 2005:7, pages 438-439.
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Zhan-Hui Zhang, Liang Yin, Yi Li & Yong-Mei Wang. (2005) A practical and efficient procedure for the cleavage of acylals to aldehydes catalyzed by indium tribromide in water. Tetrahedron Letters 46:5, pages 889-893.
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Veerababurao Kavala & Bhisma�K. Patel. (2005) Reinvestigation of the Mechanism ofgem-Diacylation: Chemoselective Conversion of Aldehydes to Variousgem-Diacylates and Their Cleavage under Acidic and Basic Conditions. European Journal of Organic Chemistry 2005:2, pages 441-451.
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Zhan-Hui Zhang. (2019) Indium tribromide/[bmim]PF 6 : A novel and recyclable catalytic system for the deprotection of 1,1-diacetates . Journal of Chemical Research 2004:11, pages 753-755.
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G Smitha & Ch.Sanjeeva Reddy. (2003) A facile and efficient ZrCl 4 catalyzed conversion of aldehydes to geminal-diacetates and dipivalates and their cleavage. Tetrahedron 59:48, pages 9571-9576.
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N. Srilakshmi Krishnaveni, K. Surendra, M. Arjun Reddy, Y. V. D. Nageswar & K. Rama Rao. (2003) Highly Efficient Deprotection of Aromatic Acetals under Neutral Conditions Using β-Cyclodextrin in Water. The Journal of Organic Chemistry 68:5, pages 2018-2019.
Crossref
M. Arjun Reddy, L. Rajender Reddy, N. Bhanumathi & K. Rama Rao. (2010) ChemInform Abstract: An Efficient Biomimetic Cleavage of gem‐Diacetates to Aldehydes by β‐Cyclodextrin under Neutral Conditions in Aqueous Medium.. ChemInform 33:22.
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