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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 4
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Original Articles

Mo(CO)6 Mediated Selective Reduction of Azides and Nitro Compounds to Amines Under Neutral Conditions

Dr. Suresh Iyer Organic Chemistry Synthesis Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411 008, IndiaCorrespondence[email protected]
&
Girish M. Kulkarni Organic Chemistry Synthesis Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411 008, India
Pages 721-725 | Received 21 May 2003, Published online: 16 Aug 2006

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Byung Woo Yoo & Jung Youn Kim. (2020) Selective and efficient desulfurization of thiiranes with Mo(CO)6. Journal of Sulfur Chemistry 41:1, pages 13-18.
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Majid Hashemi, Mohammad Mehdi Khodaei, Mohammad Teymouri, Alimorad Rashidi & Hadi Mohammadi. (2016) Preparation of NiO Nanocatalyst Supported on MWCNTs and Its Application in Reduction of Nitrobenzene to Aniline in Liquid Phase. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 46:7, pages 959-967.
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K. Rajendran, S. Akash, M. Roshni, N. Pandurangan & D. Jagadeesan. (2022) CuO/CaO as a solid reducing reagent for nitroarenes: combined effect of oxygen vacancies and surface basicity. Proceedings of the Indian National Science Academy 88:3, pages 369-378.
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Stacey N. Anderson, Michael T. Larson & Lisa M. Berreau. (2016) Solution or solid – it doesn't matter: visible light-induced CO release reactivity of zinc flavonolato complexes. Dalton Transactions 45:37, pages 14570-14580.
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Praveen Kumar Verma, Manju Bala, Kavita Thakur, Upendra Sharma, Neeraj Kumar & Bikram Singh. (2014) Iron and Palladium(II) Phthalocyanines as Recyclable Catalysts for Reduction of Nitroarenes. Catalysis Letters 144:7, pages 1258-1267.
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Dandu Damodara, Racha Arundhathi, T. Venkata Ramesh Babu, Margaret K. Legan, Hephzibah J. Kumpaty & Pravin R. Likhar. (2014) Polymethylhydrosiloxane derived palladium nanoparticles for chemo- and regioselective hydrogenation of aliphatic and aromatic nitro compounds in water. RSC Adv. 4:43, pages 22567-22574.
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Lin He, Muhammad Sharif, Helfried Neumann, Matthias Beller & Xiao-Feng Wu. (2014) A convenient palladium-catalyzed carbonylative synthesis of 4(3H)-quinazolinones from 2-bromoformanilides and organo nitros with Mo(CO) 6 as a multiple promoter . Green Chem. 16:8, pages 3763-3767.
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Poongavanam Baburajan & Kuppanagounder P. Elango. (2014) Co2(CO)8 as a convenient in situ CO source for the direct synthesis of benzamides from aryl halides (Br/I) via aminocarbonylation. Tetrahedron Letters 55:5, pages 1006-1010.
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Patrik Nordeman, Luke R. Odell & Mats Larhed. (2012) Aminocarbonylations Employing Mo(CO) 6 and a Bridged Two-Vial System: Allowing the Use of Nitro Group Substituted Aryl Iodides and Aryl Bromides . The Journal of Organic Chemistry 77:24, pages 11393-11398.
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K. Joseph Antony RAJ, M.G. PRAKASH, R. MAHALAKSHMY, T. ELANGOVAN & B. VISWANATHAN. (2012) Liquid Phase Hydrogenation of Nitrobenzene over Nickel Supported on Titania. Chinese Journal of Catalysis 33:7-8, pages 1299-1305.
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John Spencer. (2010) Research Spotlight: Microwave chemistry enabling the synthesis of biologically relevant amines. Future Medicinal Chemistry 2:2, pages 161-168.
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Lin He, Lu‐Cun Wang, Hao Sun, Ji Ni, Yong Cao, He‐Yong He & Kang‐Nian Fan. (2009) Efficient and Selective Room‐Temperature Gold‐Catalyzed Reduction of Nitro Compounds with CO and H 2 O as the Hydrogen Source . Angewandte Chemie International Edition 48:50, pages 9538-9541.
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Lin He, Lu‐Cun Wang, Hao Sun, Ji Ni, Yong Cao, He‐Yong He & Kang‐Nian Fan. (2009) Efficient and Selective Room‐Temperature Gold‐Catalyzed Reduction of Nitro Compounds with CO and H 2 O as the Hydrogen Source . Angewandte Chemie 121:50, pages 9702-9705.
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M. Lakshmi Kantam, Rajashree Chakravarti, Ujjwal Pal, B. Sreedhar & Suresh Bhargava. (2008) Nanocrystalline Magnesium Oxide‐Stabilized Palladium(0): An Efficient and Reusable Catalyst for Selective Reduction of Nitro Compounds. Advanced Synthesis & Catalysis 350:6, pages 822-827.
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Ivan Pogorelić, Mirela Filipan-Litvić, Sonja Merkaš, Goranka Ljubić, Ivica Cepanec & Mladen Litvić. (2007) Rapid, efficient and selective reduction of aromatic nitro compounds with sodium borohydride and Raney nickel. Journal of Molecular Catalysis A: Chemical 274:1-2, pages 202-207.
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Shinya Hanashima, Shino Manabe & Yukishige Ito. (2005) Divergent Synthesis of Sialylated Glycan Chains: Combined Use of Polymer Support, Resin Capture-Release, and Chemoenzymatic Strategies. Angewandte Chemie 117:27, pages 4290-4296.
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Suresh Iyer & Girish M. Kulkarni. (2004) Mo(CO) 6 Mediated Selective Reduction of Azides and Nitro Compounds to Amines Under Neutral Conditions. . ChemInform 35:30.
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