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Solvent Extraction and Ion Exchange Volume 21, 2003 - Issue 5
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Original Articles

Studies on the Parallel Synthesis and Evaluation of New Heterocyclic Extractants for the Partitioning of Minor Actinides

Michael J. Hudson Department of Chemistry, University of Reading, P.O. Box 224, Whiteknights, Reading, GB‐RG6 6AD, UKCorrespondence[email protected]
,
Mark R. St. J. Foreman Department of Chemistry, University of Reading, P.O. Box 224, Whiteknights, Reading, GB‐RG6 6AD, UK
,
Clément Hill Commisariat d'Energie Atomique, CEA‐Valrho (Marcoule), Bagnol‐sur Ceze, France
,
Nathalie Huet Department of Chemistry, University of Reading, P.O. Box 224, Whiteknights, Reading, GB‐RG6 6AD, UK
&
Charles Madic Commisariat d'Energie Atomique, CEA‐Valrho (Marcoule), Bagnol‐sur Ceze, France
Pages 637-652 | Received 10 Jan 2003, Published online: 15 Feb 2007

Citations (28)

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MarkR. St. J. Foreman, Michael J. Hudson, Andreas Geist, Charles Madic & Michael Weigl. (2005) An Investigation into the Extraction of Americium(III), Lanthanides and D‐Block Metals by 6,6′‐Bis‐(5,6‐dipentyl‐[1,2,4]triazin‐3‐yl)‐[2,2′]bipyridinyl (C5‐BTBP). Solvent Extraction and Ion Exchange 23:5, pages 645-662.
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Articles from other publishers (27)

Lei Xu, Xiaofan Yang, Anyun Zhang, Chao Xu & Chengliang Xiao. (2023) Separation and complexation of f-block elements using hard-soft donors combined phenanthroline extractants. Coordination Chemistry Reviews 496, pages 215404.
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Xiaobin Zhang, Sara L. Adelman, Brian T. Arko, Channa R. De Silva, Jing Su, Stosh A. Kozimor, Veronika Mocko, Jenifer C. Shafer, Benjamin W. Stein, Georg Schreckenbach, Enrique R. Batista & Ping Yang. (2022) Advancing the Am Extractant Design through the Interplay among Planarity, Preorganization, and Substitution Effects. Inorganic Chemistry 61:30, pages 11556-11570.
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Tim Pruessmann, Peter Nagel, Laura Simonelli, David Batchelor, Robert Gordon, Bernd Schimmelpfennig, Michael Trumm & Tonya Vitova. (2022) Opportunities and challenges of applying advanced X-ray spectroscopy to actinide and lanthanide N-donor ligand systems. Journal of Synchrotron Radiation 29:1, pages 53-66.
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Grigory Andreev & Nina Budantseva. (2020) Neptunium(V) Complexes with Lipophilic N‐Donor Extractant Ligands. ChemistrySelect 5:44, pages 14217-14222.
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Neil J. Williams, Jérémy Dehaudt, Vyacheslav S. Bryantsev, Huimin Luo, Carter W. Abney & Sheng Dai. (2017) Selective separation of americium from europium using 2,9-bis(triazine)-1,10-phenanthrolines in ionic liquids: a new twist on an old story. Chemical Communications 53:18, pages 2744-2747.
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Arunasis Bhattacharyya, Paul M. Forster, Daniel B. Rego & Kenneth R. Czerwinski. (2016) Lanthanide Complexation of 2,6‐Bis(5,6‐dipyridyl‐1,2,4‐triazinyl)pyr­idine – Solvent‐ and Lanthanide‐Ion‐Controlled Ligand Coordination Mode and Denticity. European Journal of Inorganic Chemistry 2016:6, pages 921-927.
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Yan-Ni Liang, Xia Yang, Songdong Ding, Shoujian Li, Fan Wang, Zhifang Chai & Dongqi Wang. (2015) Computational thermodynamic study on the complexes of Am( iii ) with tridentate N-donor ligands . New Journal of Chemistry 39:10, pages 7716-7729.
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Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, Udo Müllich & Andreas Geist. (2015) Efficient masking of corrosion and fission products such as Ni( ii ) and Pd( ii ) in the presence of the minor actinide Am( iii ) using hydrophilic anionic or cationic bis-triazines . Chemical Communications 51:44, pages 9189-9192.
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A. Afsar, L.M. Harwood & M.J. Hudson. 2015. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.
Antje Bremer, Andreas Geist & Petra J. Panak. (2013) Complexation of Cm(III) and Eu(III) with 2,6-bis(5-(2,2-dimethylpropyl)-1H-pyrazol-3-yl)pyridine and 2-bromohexanoic acid studied by time-resolved laser fluorescence spectroscopy. Radiochimica Acta 101:5, pages 285-292.
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Michael J. HudsonLaurence M. HarwoodDominic M. LaventineFrank W. Lewis. (2012) Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides. Inorganic Chemistry 52:7, pages 3414-3428.
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Petra J. Panak & Andreas Geist. (2013) Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands . Chemical Reviews 113:2, pages 1199-1236.
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Gary L. Guillet, I. F. Dempsey Hyatt, Patrick C. Hillesheim, Khalil A. Abboud & Michael J. Scott. (2013) 1,2,4-Triazine-picolinamide functionalized, nonadentate chelates for the segregation of lanthanides( iii ) and actinides( iii ) in biphasic systems . New J. Chem. 37:1, pages 119-131.
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Antje Bremer, Andreas Geist & Petra J. Panak. (2012) Complexation of Cm(iii) with 6-(5,6-dipentyl-1,2,4-triazin-3-yl)-2,2′-bipyridine studied by time resolved laser fluorescence spectroscopy. Dalton Transactions 41:25, pages 7582.
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Mark D. Ogden, Cortney L. Hoch, Serguei I. Sinkov, G. Patrick Meier, Gregg J. Lumetta & Kenneth L. Nash. (2011) Complexation Studies of Bidentate Heterocyclic N-Donor Ligands with Nd(III) and Am(III). Journal of Solution Chemistry 40:11, pages 1874-1888.
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C. Hill. 2011. Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment. Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment 311 362 .
Kenneth L. Nash, Charles Madic, Jagdish N. Mathur & Jeéroôme Lacquement. 2011. The Chemistry of the Actinide and Transactinide Elements. The Chemistry of the Actinide and Transactinide Elements 2622 2798 .
Yi-Feng Sun, Wei Huang, Chang-Gui Lu & Yi-Ping Cui. (2009) The synthesis, two-photon absorption and blue upconversion fluorescence of novel, nitrogen-containing heterocyclic chromophores. Dyes and Pigments 81:1, pages 10-17.
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Zdenek Kolarik. (2008) Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions. Chemical Reviews 108:10, pages 4208-4252.
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Clement Hill, Jean-F. Desreux, Christian Ekberg, Amparo Glez Espartero, M. Galetta, G. Modolo, Andreas Geist, P. Selucky, Jerzy Narbutt & Charles Madic. (2008) Assessment of ligand extraction properties: an intercomparison campaign amongst EUROPARTners. Radiochimica Acta 96:4-5, pages 259-264.
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Jerzy Narbutt & Jadwiga Krejzler. (2008) Neutral bidentate N -heterocyclic ligands – phase transfer reagents improving the kinetics of solvent extraction of Am(III) and Eu(III) ions with tetradentate 6,6′-bis-(diethyl-1,2,4-triazin-3-yl)-2,2′-bipyridine . Radiochimica Acta 96:4-5, pages 219-223.
Crossref
V. A. Babain, M. Yu. Alyapyshev & R. N. Kiseleva. (2007) Metal extraction by N , N ′-dialkyl- N , N ′-diaryl-dipicolinamides from nitric acid solutions . Radiochimica Acta 95:4, pages 217-223.
Crossref
J. Krejzler, J. Narbutt, M. R. St J. Foreman, M. J. Hudson, B. Casensky & C. Madic. (2006) Solvent extraction of Am(III) and Eu(III) from nitrate solution using synergistic mixtures of N-tridentate heterocycles and chlorinated cobalt dicarbollide. Czechoslovak Journal of Physics 56:S4, pages D459-D467.
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H. Hoshi, Y.-Z. Wei, M. Kumagai, T. Asakura & Y. Morita. (2006) Separation of trivalent actinides from lanthanides by using R-BTP resins and stability of R-BTP resin. Journal of Alloys and Compounds 408-412, pages 1274-1277.
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Michael J. Hudson, Carole E. Boucher, Damien Braekers, Jean F. Desreux, Michael G. B. Drew, Mark R. St J. Foreman, Laurence M. Harwood, Cl?ment Hill, Charles Madic, Frank Marken & Tristan G. A. Youngs. (2006) New bis(triazinyl) pyridines for selective extraction of americium(iii). New Journal of Chemistry 30:8, pages 1171.
Crossref
Mark R. S. Foreman, Michael J. Hudson, Michael G. B. Drew, Clément Hill & Charles Madic. (2006) Complexes formed between the quadridentate, heterocyclic molecules 6,6′-bis-(5,6-dialkyl-1,2,4-triazin-3-yl)-2,2′-bipyridine (BTBP) and lanthanides( iii ): implications for the partitioning of actinides( iii ) and lanthanides( iii ) . Dalton Trans.:13, pages 1645-1653.
Crossref
J. Krejzler, J. Narbutt, M. R.StJ. Foreman, M. J. Hudson, B. Casensky & C. Madic. (2006) Solvent extraction of Am(III) and Eu(III) from nitrate solution using synergistic mixtures of N-tridentate heterocycles and chlorinated cobalt dicarbollide. Czechoslovak Journal of Physics 56:1, pages D459-D467.
Crossref

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