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Original Articles

Selective Extraction of Americium(III) over Macroscopic Concentration of Lanthanides(III) by Synergistic System of TPEN and D2EHPA in 1‐Octanol

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Pages 377-390 | Received 07 Jul 2003, Published online: 24 Aug 2007

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Gregg J. Lumetta, Artem V. Gelis, Jennifer C. Carter, Cynthia M. Niver & Margaret R. Smoot. (2014) The Actinide-Lanthanide Separation Concept. Solvent Extraction and Ion Exchange 32:4, pages 333-347.
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Gregg J. Lumetta, Artem V. Gelis & George F. Vandegrift. (2010) Review: Solvent Systems Combining Neutral and Acidic Extractants for Separating Trivalent Lanthanides from the Transuranic Elements. Solvent Extraction and Ion Exchange 28:3, pages 287-312.
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GlennA. Fugate∗, Kenji Takeshita & Tatsuro Matsumura. (2008) Separation of Americium (III) and Lanthanide (III) Ions using TPEN Analogs. Separation Science and Technology 43:9-10, pages 2619-2629.
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Andreas Geist, Clément Hill, Giuseppe Modolo, MarkR. St. J. Foreman, Michael Weigl, Klaus Gompper & Michael J. Hudson. (2006) 6,6′‐Bis(5,5,8,8‐tetramethyl‐5,6,7,8‐tetrahydro‐benzo[1,2,4]triazin‐3‐yl) [2,2′]bipyridine, an Effective Extracting Agent for the Separation of Americium(III) and Curium(III) from the Lanthanides. Solvent Extraction and Ion Exchange 24:4, pages 463-483.
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Tatsuro MATSUMURA & Kenji TAKESHITA. (2006) Extraction Behavior of Am(III) from Eu(III) with Hydrophobic Derivatives of N,N,N',N'-tetrakis(2-methylpyridyl)ethylenediamine (TPEN) . Journal of Nuclear Science and Technology 43:7, pages 824-827.
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Rinat MIRVALIEV, Masayuki WATANABE, Tatsuro MATSUMURA, Shoichi TACHIMORI & Kenji TAKESHITA. (2004) Selective Separation of Am(III) from Ln(III) with a Novel Synergistic Extraction System, N,N, N′, N′-tetrakis(2-methylpyridyl)-ethylenediamine (TPEN) and Carboxylic Acid in 1-Octanol. Journal of Nuclear Science and Technology 41:11, pages 1122-1124.
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Ke Niu, Feng Yang, Théophile Gaudin, Haibo Ma & Weihai Fang. (2021) Theoretical Study of Effects of Solvents, Ligands, and Anions on Separation of Trivalent Lanthanides and Actinides. Inorganic Chemistry 60:13, pages 9552-9562.
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Arunasis Bhattacharyya, Seraj A. Ansari, Petr I. Matveev, Gladis G. Zakirova, Nataliya E. Borisova, Vladimir G. Petrov, Tsagana Sumyanova, Parveen Kumar Verma, Stepan N. Kalmykov & Prasanta Kumar Mohapatra. (2019) Unfolding the complexation and extraction of Am 3+ and Eu 3+ using N-heterocyclic aromatic diphosphonic acids: a combined experimental and DFT study . Dalton Transactions 48:43, pages 16279-16288.
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Sk. Musharaf Ali. (2018) Role of Ligand Straining in Complexation of Eu 3+ –Am 3+ Ions by TPEN and PPDEN, Scalar Relativistic DFT Exploration in Conjunction with COSMO-RS . ACS Omega 3:10, pages 13104-13116.
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Pin-Wen Huang, Cong-Zhi Wang, Qun-Yan Wu, Jian-Hui Lan, Gang Song, Zhi-Fang Chai & Wei-Qun Shi. (2018) Uncovering the impact of ‘capsule’ shaped amine-type ligands on Am( iii )/Eu( iii ) separation . Physical Chemistry Chemical Physics 20:2, pages 1030-1038.
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Dengfang Pan, Cai Jia, Xihong He, Gang Ye & Jing Chen. (2015) A polyazamacrocycle extractant for the extraction of americium and europium. Science China Chemistry 58:6, pages 986-992.
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Joseph A. Macor, Jessie L. Brown, Justin N. Cross, Scott R. Daly, Andrew J. Gaunt, Gregory S. Girolami, Michael T. Janicke, Stosh A. Kozimor, Mary P. Neu, Angela C. Olson, Sean D. Reilly & Brian L. Scott. (2015) Coordination chemistry of 2,2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu. Dalton Transactions 44:43, pages 18923-18936.
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Kevin S. Boland, David E. Hobart, Stosh A. Kozimor, Molly M. MacInnes & Brian L. Scott. (2014) The coordination chemistry of trivalent lanthanides (Ce, Nd, Sm, Eu, Gd, Dy, Yb) with diphenyldithiophosphinate anions. Polyhedron 67, pages 540-548.
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Scott R. Daly, Jason M. Keith, Enrique R. Batista, Kevin S. Boland, David L. Clark, Stosh A. Kozimor & Richard L. Martin. (2012) Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations. Journal of the American Chemical Society 134:35, pages 14408-14422.
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Hajime Katano, Kohei Uematsu & Toshihide Tsukatani. (2011) Enhancement of the Luminescence Efficiency of Europium(III) Tris(β-diketonato) Complex in Organic Media by Quaternary Ammonium Salts with Anionic Ligands. Analytical Sciences 27:12, pages 1249-1252.
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Mark D. Ogden, Cortney L. Hoch, Serguei I. Sinkov, G. Patrick Meier, Gregg J. Lumetta & Kenneth L. Nash. (2011) Complexation Studies of Bidentate Heterocyclic N-Donor Ligands with Nd(III) and Am(III). Journal of Solution Chemistry 40:11, pages 1874-1888.
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Marie Heitzmann, Christelle Gateau, Laurence Chareyre, Manuel Miguirditchian, Marie-Christine Charbonnel & Pascale Delangle. (2010) Water-soluble tetrapodal N,O ligands incorporating soft N-heterocycles for the selective complexation of Am(iii) over Ln(iii). New J. Chem. 34:1, pages 108-116.
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Gregg J. Lumetta, Jennifer C. Carter, Artem V. Gelis & George F. Vandegrift. 2010. Nuclear Energy and the Environment. Nuclear Energy and the Environment 107 118 .
Qiong Jia, Zhiying Li, Weihong Zhou & Hongfei Li. (2009) Studies on the solvent extraction of rare earths from nitrate media with a combination of di-(2-ethylhexyl)phosphoric acid and sec -octylphenoxyacetic acid . Journal of Chemical Technology & Biotechnology 84:4, pages 565-569.
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Marie Heitzmann, Florence Bravard, Christelle Gateau, Nathalie Boubals, Claude Berthon, Jacques Pécaut, Marie-Christine Charbonnel & Pascale Delangle. (2008) Comparison of Two Tetrapodal N,O Ligands: Impact of the Softness of the Heterocyclic N-Donors Pyridine and Pyrazine on the Selectivity for Am(III) over Eu(III). Inorganic Chemistry 48:1, pages 246-256.
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Zdenek Kolarik. (2008) Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions. Chemical Reviews 108:10, pages 4208-4252.
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Tatsuro Matsumura & Kenji Takeshita. (2008) Extraction separation of trivalent minor actinides from lanthanides with hydrophobic derivatives of TPEN. Progress in Nuclear Energy 50:2-6, pages 470-475.
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Henk H. Dam, David N. Reinhoudt & Willem Verboom. (2007) Multicoordinate ligands for actinide/lanthanide separations. Chem. Soc. Rev. 36:2, pages 367-377.
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