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Focus Topical Reviews

Tetrathiapentalene-based organic conductors

Article: 024301 | Received 14 Jan 2009, Accepted 17 Mar 2009, Published online: 06 Jul 2009

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Meriam Boumedjout, Amel Bendjeddou, Tahar Abbaz, Lakhmici Kaboub, Abdelkrim Gouasmia & Didier Villemin. (2016) New materials derivatives of tetrathiapentalene functionalized by amide groups: Synthesis, characterization, and electrical study. Phosphorus, Sulfur, and Silicon and the Related Elements 191:6, pages 891-897.
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Anna Pintus & Massimiliano Arca. (2022) 1,2-Diselenolene ligands and related metal complexes: Design, synthesis and applications. Coordination Chemistry Reviews 464, pages 214444.
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Takashi Shirahata, Shuhei Kohno, Keisuke Furuta, Shogo Katayama, Kento Suzuki, Tadashi Kawamoto, Takehiko Mori & Yohji Misaki. (2022) Organic Molecular Conductors Based on Tetramethyl-TTP: Structural and Electrical Properties Modulated by the Anion Size and Shape. Inorganic Chemistry 61:20, pages 7754-7764.
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Aya Yoshimura & Yohji Misaki. (2021) Periphery Modification of Tetrathiafulvalenes: Recent Development and Applications. The Chemical Record 21:12, pages 3520-3531.
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V. A. Lykah, E. S. Syrkin & E. N. Trotskii. (2021) Heavy doped organic crystals ordering. Low Temperature Physics 47:5, pages 406-411.
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Yohji Misaki, Kohei Kagawa, Takayuki Higashi & Aya Yoshimura. (2021) Synthesis and Properties of Fused Triad Donors Composed of Two 1,3-Dithiole[5]radialenes and Extended Tetrathiafulvalene. HETEROCYCLES 102:5, pages 961.
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Aya Yoshimura, Keisuke Henmi, Hitoshi Kimura, Ryo Sakakibara, Rika Ochi, Takashi Shirahata, Hideki Yorimitsu & Yohji Misaki. (2020) Synthesis of Peripherally Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C–H Arylation and Construction of a Double-Helical Cobalt-Based Metal-Organic Framework. Synthesis 53:02, pages 326-331.
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Aya Yoshimura, Hitoshi Kimura, Kohei Kagawa, Mayuka Yoshioka, Toshiki Itou, Dhananjayan Vasu, Takashi Shirahata, Hideki Yorimitsu & Yohji Misaki. (2020) Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes. Beilstein Journal of Organic Chemistry 16, pages 974-981.
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Yohji Misaki, Shigenobu Noda, Minami Kato, Tomokazu Yamauchi, Toko Oshima, Aya Yoshimura, Takashi Shirahata & Masaru Yao. (2020) Fused Tetrathiafulvalene and Benzoquinone Triads: Organic Positive‐Electrode Materials Based on a Dual Redox System. ChemSusChem 13:9, pages 2312-2320.
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Masafumi Ueda & Yohji Misaki. (2019) Synthesis and Redox Properties of 1,3-Dithiole[<i>n</i>]radialenes1,3-ジチオール[<i>n</i>]ラジアレン類の合成と酸化還元特性. Journal of Synthetic Organic Chemistry, Japan 77:12, pages 1234-1246.
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Daisuke Ogi, Yusuke Fujita, Minami Kato, Tomokazu Yamauchi, Takashi Shirahata, Masaru Yao & Yohji Misaki. (2019) Tris‐Fused Tetrathiafulvalenes Extended with an Anthraquinoid Spacer as New Positive Electrode Materials for Rechargeable Batteries. European Journal of Organic Chemistry 2019:16, pages 2725-2728.
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Constantinos G. Neochoritis, Ting Zhao & Alexander Dömling. (2019) Tetrazoles via Multicomponent Reactions. Chemical Reviews 119:3, pages 1970-2042.
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Minami Kato, Yusuke Fujita, Tomokazu Yamauchi, Shigeki Mori, Takashi Shirahata & Yohji Misaki. (2018) Redox-Switchable Bis-fused Tetrathiafulvalene Analogue: Observation and Control of Two Different Reduction Processes from Dication to Neutral State. Organic Letters 20:17, pages 5121-5125.
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Katsuya Sako, Tomoya Hasegawa, Hiroyuki Onda, Michito Shiotsuka, Motonori Watanabe, Teruo Shinmyozu, Sachiko Tojo, Mamoru Fujitsuka, Tetsuro Majima, Yasukazu Hirao, Takashi Kubo, Tetsuo Iwanaga, Shinji Toyota & Hiroyuki Takemura. (2018) Donor–Donor′–Acceptor Triads Based on [3.3]Paracyclophane with a 1,4‐Dithiafulvene Donor and a Cyanomethylene Acceptor: Synthesis, Structure, and Electrochemical and Photophysical Properties. Chemistry – A European Journal 24:44, pages 11407-11416.
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Ke Zhou, Hongfeng Chen, Huanli Dong, Qi Fang & Wenping Hu. (2017) Comparable charge transport property based on S???S interactions with that of ?-? stacking in a bis-fused tetrathiafulvalene compound. Science China Chemistry 60:4, pages 510-515.
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Minami Kato, Shigenobu Noda, Tetsu Kiyobayashi, Masaru Yao & Yohji Misaki. (2017) Fused Donor–Donor–Acceptor Triads Composed of Tetrathiafulvalene and Benzoquinone Derivatives as the Positive Electrode Materials for Rechargeable Lithium and Sodium Batteries. Chemistry Letters 46:3, pages 368-370.
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Yuka Kobayashi, Takeshi Terauchi, Satoshi Sumi & Yoshitaka Matsushita. (2016) Carrier generation and electronic properties of a single-component pure organic metal. Nature Materials 16:1, pages 109-114.
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Daisuke Ogi, Yusuke Fujita, Shigeki Mori, Takashi Shirahata & Yohji Misaki. (2016) Bis- and Tris-fused Tetrathiafulvalenes Extended with Anthracene-9,10-diylidene. Organic Letters 18:22, pages 5868-5871.
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Masashi Hasegawa & Yohji Misaki. 2016. Cross Conjugation. Cross Conjugation 301 336 .
Andrey A. Bardin, Hiroki Akutsu & Jun-ichi Yamada. (2016) New Family of Six Stable Metals with a Nearly Isotropic Triangular Lattice of Organic Radical Cations and Diluted Paramagnetic System of Anions: κ(κ ⊥ )-(BDH-TTP) 4 MX 4 ·Solv, where M = Co II , Mn II ; X = Cl, Br, and Solv = (H 2 O) 5 , (CH 2 X 2 ) . Crystal Growth & Design 16:3, pages 1228-1246.
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Takehiko MoriTakehiko Mori. 2016. Electronic Properties of Organic Conductors. Electronic Properties of Organic Conductors 253 310 .
Takashi Shirahata, Shuhei Kohno, Keisuke Furuta, Yusuke Oka & Yohji Misaki. (2015) Synthesis of New Electron Donor ClMe 3 -TTP: Structures and Properties of (ClMe 3 -TTP) 3 X (X = PF 6 and AsF 6 ) . Bulletin of the Chemical Society of Japan 88:8, pages 1086-1092.
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Shintaro Iwamoto, Yuu Inatomi, Daisuke Ogi, Satoshi Shibayama, Yukiko Murakami, Minami Kato, Kazuyuki Takahashi, Kazuyoshi Tanaka, Nobuhiko Hojo & Yohji Misaki. (2015) New tris- and pentakis-fused donors containing extended tetrathiafulvalenes: New positive electrode materials for rechargeable batteries. Beilstein Journal of Organic Chemistry 11, pages 1136-1147.
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Takashi Matsuda, Masafumi Ueda, Rina Kondo, Mizuka Suwaki & Yohji Misaki. (2015) Synthesis and Properties of Fused π-Electron Donors Possessing Vinylogous 1,3-Dithiole[5]radialene Units. Bulletin of the Chemical Society of Japan 88:6, pages 850-856.
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Daisuke Ogi, Shuka Yoshimoto, Takashi Shirahata & Yohji Misaki. (2015) Synthesis, Structures, and Electrochemical Properties of New Extensively Conjugated TTF. Chemistry Letters 44:4, pages 554-556.
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Pedro Fuertes, María García-Valverde, Ricardo Pascual, Teresa Rodríguez, Josefa Rojo, José García-Calvo, Patricia Calvo, José V. Cuevas, Gabriel García-Herbosa & Tomás Torroba. (2014) Structural Conformers of (1,3-Dithiol-2-ylidene)ethanethioamides: The Balance between Thioamide Rotation and Preservation of Classical Sulfur–Sulfur Hypervalent Bonds. The Journal of Organic Chemistry 80:1, pages 30-39.
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Keisuke Furuta, Shuhei Kohno, Takashi Shirahata & Yohji Misaki. (2014) Molecular Conductors with Effectively Half‐Filled Electronic States Based on Tetrathiafulvalene Derivatives Condensed with a 2‐Isopropylidene‐1,3‐dithiole Ring. European Journal of Inorganic Chemistry 2014:24, pages 3982-3988.
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Ken-ichi Nakamura, Yuuki Okada, Takashi Shirahata & Yohji Misaki. (2014) Cyclic TTF Tetramer Linked by Methylenedithio Spacers. Chemistry Letters 43:5, pages 708-710.
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Pedro Fuertes, María García-Valverde, José V. Cuevas, Borja Díaz de Greñu, Teresa Rodríguez, Josefa Rojo & Tomás Torroba. (2014) Synthesis of Pyrrolidine-Fused 1,3-Dithiolane Oligomers by the Cycloaddition of Polycyclic Dithiolethiones to Maleimides and Evaluation as Mercury(II) Indicators. The Journal of Organic Chemistry 79:5, pages 2213-2225.
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Takeshi Terauchi, Satoshi Sumi, Yuka Kobayashi, Yoshitaka Matsushita & Akira Sato. (2014) Two-Dimensional Brickblock Arrangement in Bis-Fused Tetrathiafulvalene Semiconductors. Crystal Growth & Design 14:3, pages 1412-1418.
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Takeshi Terauchi, Satoshi Sumi, Yuka Kobayashi, Toshikazu Nakamura, Ko Furukawa & Yohji Misaki. (2014) A stable metallic state of (TTPCOO)2NH4 with a mobile dopant. Chemical Communications 50:54, pages 7111.
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Minami Kato, Ken-ichiro Senoo, Masaru Yao & Yohji Misaki. (2014) A pentakis-fused tetrathiafulvalene system extended by cyclohexene-1,4-diylidenes: a new positive electrode material for rechargeable batteries utilizing ten electron redox. Journal of Materials Chemistry A 2:19, pages 6747.
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Tetsuro Kusamoto, Hiroshi Nishihara & Reizo Kato. (2013) Substituent-Dependent Spin-Density Distribution and Coexistence of Fe 3d and π Spins on Ferrocene–Tetrathiafulvalene Hybrids. Inorganic Chemistry 52:24, pages 13809-13811.
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Minami Kato, Daisuke Ogi, Masaru YaoYohji Misaki. (2013) A Tris-fused Tetrathiafulvalene Extended with Cyclohexene-1,4-diylidene: A New Positive Electrode Material for Organic Rechargeable Batteries. Chemistry Letters 42:12, pages 1556-1558.
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Minami Kato, Takashi Shirahata & Yohji Misaki. (2013) A New Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and 2-(Xanthen-9-ylidene)-1,3-dithiole. Chemistry Letters 42:12, pages 1548-1550.
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Masafumi Ueda & Yohji Misaki. (2013) [5]Radialene-Fused Tetrathiafulvalenes Exhibiting a Simultaneous Four- or Eight-Electron Transfer. Organic Letters 15:15, pages 3824-3827.
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Tetsuro Kusamoto, Kenji Takada, Ryota Sakamoto, Shoko Kume & Hiroshi Nishihara. (2012) Ferrocene–Dithiolene Hybrids: Control of Strong Donor–Acceptor Electronic Communication to Reverse the Charge Transfer Direction. Inorganic Chemistry 51:22, pages 12102-12113.
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Yuu Inatomi, Nobuhiko Hojo, Taisuke Yamamoto, Sho‐ichiro Watanabe & Yohji Misaki. (2012) Construction of Rechargeable Batteries Using Multifused Tetrathiafulvalene Systems as Cathode Materials. ChemPlusChem 77:11, pages 973-976.
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Yoshihiro Kajiwara, Shojun Hino & Yohji Misaki. (2012) Synthesis and Properties of Tris-Fused Tetrathiafulvalene Analogues Possessing [3]Dendralene Moieties. Bulletin of the Chemical Society of Japan 85:7, pages 830-835.
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Jun-ichi Yamada & Hiroki Akutsu. (2012) Chemical Modifications of BDH-TTP [2,5-Bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene]: Control of Electron Correlation. Crystals 2:3, pages 812-844.
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Takeshi Terauchi, Yuka Kobayashi & Yohji Misaki. (2012) Synthesis of bis-fused tetrathiafulvalene with mono- and dicarboxylic acids. Tetrahedron Letters 53:26, pages 3277-3280.
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Keisuke Furuta, Shuhei Kohno, Takashi Shirahata, Koya Yamasaki, Shojun Hino & Yohji Misaki. (2012) Synthesis and Properties of 2-Alkylidene-1,3-dithiolo[4,5-d]-4,5-ethylenediselenotetrathiafulvalene Derivatives and Crystal Structures of Their Cation Radical Salts. Crystals 2:2, pages 393-412.
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Takashi Shirahata, Tetsuya Ito, Shinya Toki & Yohji Misaki. (2012) Synthesis of a new donor, MOET‐TTP, and the crystal structure, electrical, and magnetic properties of (MOET‐TTP) 2 M Cl 4 ( M  = Fe and Ga) . physica status solidi (b) 249:5, pages 929-932.
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Hideki Yamochi, Tsuyoshi Haneda, Adam Tracz & Gunzi Saito. (2012) Humidity dependent properties of a transparent conducting film doped with BEDO‐TTF complex. physica status solidi (b) 249:5, pages 1012-1016.
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Sudipta Kanungo & T. Saha-Dasgupta. (2011) First-principles study of organic-inorganic hybrid framework compound Mn(C H O ) . Physical Review B 84:13.
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Masataka Nishiwaki, Ken-ichi Nakamura, Takashi Shirahata & Yohji Misaki. (2011) Novel Molecular Conductors Based on Cyclopenteno-TTP Showing Strong Self-aggregation. Chemistry Letters 40:5, pages 452-454.
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Misaki Yasuda, Emiko Fujiwara, Shuji Aonuma, Hideki Fujiwara, Toyonari Sugimoto, Takashi Nakayashiki, Kazuyoshi Tanaka, Kazuyuki Takahashi, Hayao Kobayashi & Yohji Misaki. (2011) Structures and Electrical Properties of (BTM-TS-TTP) 4 PF 6 . Bulletin of the Chemical Society of Japan 84:1, pages 79-81.
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Tetsuya Ito, Ken-ichi Nakamura, Takashi Shirahata, Tadashi Kawamoto, Takehiko Mori & Yohji Misaki. (2011) New Molecular Metals Based on a Tetrathiapentalene Donor with Peripheral Methoxy Groups. Chemistry Letters 40:1, pages 81-83.
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Minoru Ashizawa, Ken-ichi Ishidzu, Masaki Watanabe, Tetsuhiko Tanahashi, Takashi Shirahata, Tadashi Kawamoto, Takehiko Mori & Yohji Misaki. (2010) Novel Bis-fused ?-Electron Donor Composed of Tetrathiafulvalene and Tetraselenafulvalene. Chemistry Letters 39:10, pages 1093-1095.
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Yoshiaki Nakano, Yohji Misaki, Mikio Uruichi, Kyuya Yakushi & Hideki Yamochi. (2010) Charge disproportionation in a semiconducting θ-type salt of BTM-TTP. Physica B: Condensed Matter 405:11, pages S198-S201.
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Yoshiaki Nakano, Toshiaki Nishi, Mikio Uruichi, Kyuya Yakushi & Hideki Yamochi. (2010) Synthesis, crystal structure, and physical property of radical cation salt of 2-(thiopyran-4-ylidene)-4,5-ethylenedithio-1,3-dithiole (TP-EDTT): (TP-EDTT)2SbF6. Physica B: Condensed Matter 405:11, pages S49-S54.
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Katsuyuki Shizu, Tohru Sato & Kazuyoshi Tanaka. (2010) Reduced vibronic coupling density and its application to bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF). Chemical Physics Letters 491:1-3, pages 65-71.
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