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Original Article

Reversible H-Atom Abstraction from Alcohols by Thiyl Radicals: Determination of Absolute Rate Constants by Pulse Radiolysis

Pages 393-405 | Received 20 Feb 1989, Published online: 07 Jul 2009

Keep up to date with the latest research on this topic with citation updates for this article.

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Peter O'Neill & Peter Wardman. (2009) Radiation chemistry comes before radiation biology. International Journal of Radiation Biology 85:1, pages 9-25.
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L. Grierson, K. Hildenbrand & E. Bothe. (1992) Intramolecular Transformation Reaction of the Glutathione Thiyl Radical into a Non-sulphur-centred Radical: A Pulse-radiolysis and EPR Study. International Journal of Radiation Biology 62:3, pages 265-277.
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Thomas Nauser & Janusz M. Gebicki. (2020) Antioxidants and radical damage in a hydrophilic environment: chemical reactions and concepts. Essays in Biochemistry 64:1, pages 67-74.
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Christian Schöneich. (2017) Sulfur Radical-Induced Redox Modifications in Proteins: Analysis and Mechanistic Aspects. Antioxidants & Redox Signaling 26:8, pages 388-405.
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Dawid Dębski, Renata Smulik, Jacek Zielonka, Bartosz Michałowski, Małgorzata Jakubowska, Karolina Dębowska, Jan Adamus, Andrzej Marcinek, Balaraman Kalyanaraman & Adam Sikora. (2016) Mechanism of oxidative conversion of Amplex® Red to resorufin: Pulse radiolysis and enzymatic studies. Free Radical Biology and Medicine 95, pages 323-332.
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Lisa Olshansky, Arturo A. Pizano, Yifeng Wei, JoAnne Stubbe & Daniel G. Nocera. (2014) Kinetics of Hydrogen Atom Abstraction from Substrate by an Active Site Thiyl Radical in Ribonucleotide Reductase. Journal of the American Chemical Society 136:46, pages 16210-16216.
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Christian Schöneich, Olivier Mozziconacci, Willem H. Koppenol & Thomas Nauser. (2014) Intramolecular 1,2‐ and 1,3‐Hydrogen Transfer Reactions of Thiyl Radicals. Israel Journal of Chemistry 54:3, pages 265-271.
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Olivier Mozziconacci, Todd D. Williams & Christian Schöneich. (2012) Intramolecular Hydrogen Transfer Reactions of Thiyl Radicals from Glutathione: Formation of Carbon-Centered Radical at Glu, Cys, and Gly. Chemical Research in Toxicology 25:9, pages 1842-1861.
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Dustin Hofstetter, Basil Thalmann, Thomas Nauser & Willem H. Koppenol. (2012) Hydrogen Exchange Equilibria in Thiols. Chemical Research in Toxicology 25:9, pages 1862-1867.
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Juan Raúl Alvarez-Idaboy & Annia Galano. (2012) On the Chemical Repair of DNA Radicals by Glutathione: Hydrogen vs Electron Transfer. The Journal of Physical Chemistry B 116:31, pages 9316-9325.
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Christian Schöneich. 2012. Encyclopedia of Radicals in Chemistry, Biology and Materials. Encyclopedia of Radicals in Chemistry, Biology and Materials.
Olivier Mozziconacci, Bruce A. Kerwin & Christian Schöneich. (2011) Reversible Hydrogen Transfer Reactions of Cysteine Thiyl Radicals in Peptides: the Conversion of Cysteine into Dehydroalanine and Alanine, and of Alanine into Dehydroalanine. The Journal of Physical Chemistry B 115:42, pages 12287-12305.
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Christian Schöneich. (2011) Cysteine residues as catalysts for covalent peptide and protein modification: a role for thiyl radicals?. Biochemical Society Transactions 39:5, pages 1254-1259.
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Olivier Mozziconacci, Bruce A. Kerwin & Christian Schöneich. (2010) Reversible Hydrogen Transfer between Cysteine Thiyl Radical and Glycine and Alanine in Model Peptides: Covalent H/D Exchange, Radical−Radical Reactions, and l - to d -Ala Conversion . The Journal of Physical Chemistry B 114:19, pages 6751-6762.
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Olivier Mozziconacci, Bruce A. Kerwin & Christian Schöneich. (2010) Photolysis of an Intrachain Peptide Disulfide Bond: Primary and Secondary Processes, Formation of H 2 S, and Hydrogen Transfer Reactions . The Journal of Physical Chemistry B 114:10, pages 3668-3688.
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Grazyna Wenska, Piotr Filipiak, Klaus-Dieter Asmus, Krzysztof Bobrowski, Jacek Koput & Bronislaw Marciniak. (2008) Formation of a Sandwich-Structure Assisted, Relatively Long-Lived Sulfur-Centered Three-Electron Bonded Radical Anion in the Reduction of a Bis(1-substituted-uracilyl) Disulfide in Aqueous Solution. The Journal of Physical Chemistry B 112:32, pages 10045-10053.
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Christian Schöneich. (2008) Mechanisms of Protein Damage Induced by Cysteine Thiyl Radical Formation. Chemical Research in Toxicology 21:6, pages 1175-1179.
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Marta Wrona, Kantilal B. Patel & Peter Wardman. (2008) The roles of thiol-derived radicals in the use of 2′,7′-dichlorodihydrofluorescein as a probe for oxidative stress. Free Radical Biology and Medicine 44:1, pages 56-62.
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Edyta Madej & Peter Wardman. (2007) The oxidizing power of the glutathione thiyl radical as measured by its electrode potential at physiological pH. Archives of Biochemistry and Biophysics 462:1, pages 94-102.
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Michael J. Davies. (2005) The oxidative environment and protein damage. Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics 1703:2, pages 93-109.
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Carla Ferreri, Abdelouahid Samadi, Fabio Sassatelli, Laura Landi & Chryssostomos Chatgilialoglu. (2004) Regioselective Cis−Trans Isomerization of Arachidonic Double Bonds by Thiyl Radicals:  The Influence of Phospholipid Supramolecular Organization. Journal of the American Chemical Society 126:4, pages 1063-1072.
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Masaru Tada, Emi Katayama, Naoto Sakurai & Keita Murofushi. (2004) Bis(pentafluorophenyl) disulfide as a hydrogen abstractor and an electron acceptor from the resulting radical intermediate. Tetrahedron Letters 45:1, pages 17-19.
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Thomas Nauser & Christian Schöneich. (2003) Thiyl Radicals Abstract Hydrogen Atoms from the α C−H Bonds in Model Peptides:  Absolute Rate Constants and Effect of Amino Acid Structure . Journal of the American Chemical Society 125:8, pages 2042-2043.
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